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Keywords = advanced fuel cladding

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13 pages, 10001 KB  
Article
High-Temperature Tensile Properties and Serrated Flow Behavior of FeCrAl Alloy for Accident-Tolerant Fuel Cladding
by Mengyu Chai, Zelin Han, Hao Su, Hao Li, Pan Liu and Yan Song
Appl. Sci. 2024, 14(24), 11748; https://doi.org/10.3390/app142411748 - 16 Dec 2024
Viewed by 1198
Abstract
The development of FeCrAl alloys has commenced for use as nuclear fuel cladding material, intended to serve as an enhanced accident-tolerant alternative to Zr-based alloys. In this study, the Fe-13Cr-4Al alloy, specifically designed for advanced accident-tolerant fuel (ATF) cladding, was carefully prepared through [...] Read more.
The development of FeCrAl alloys has commenced for use as nuclear fuel cladding material, intended to serve as an enhanced accident-tolerant alternative to Zr-based alloys. In this study, the Fe-13Cr-4Al alloy, specifically designed for advanced accident-tolerant fuel (ATF) cladding, was carefully prepared through vacuum induction melting and hot-working processes. Mechanical properties and serrated flow behavior of this alloy were investigated through tensile tests at temperatures ranging from 200 to 800 °C. Intriguingly, serrations emerged within a specific temperature range, accompanied by unique mechanical behavior characteristics indicative of dynamic strain aging (DSA). Additionally, the alloy’s fracture modes showed a transition from a mix of ductile and cleavage fracture features to fully ductile fracture as the temperature increased. This study offers insights into the mechanical properties and serration behaviors of FeCrAl alloys, highlighting their potential for use in nuclear fuel cladding. Full article
(This article belongs to the Section Materials Science and Engineering)
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16 pages, 8562 KB  
Article
A Study on Enhancing Axial Flux Motor Efficiency Using Cladding Core Technology
by Seung-Woo Park, Ju-Hyeong Moon, Dong-Woo Kang and Khac-Huan Su
Mathematics 2024, 12(19), 2981; https://doi.org/10.3390/math12192981 - 25 Sep 2024
Cited by 1 | Viewed by 3772
Abstract
With the rise of eco-friendly policies, advanced motor technologies are being developed to replace fossil fuel-based engines in the mobility industry. Axial flux motors, known for their ability to reduce size and increase output torque compared to radial flux motors, require different materials [...] Read more.
With the rise of eco-friendly policies, advanced motor technologies are being developed to replace fossil fuel-based engines in the mobility industry. Axial flux motors, known for their ability to reduce size and increase output torque compared to radial flux motors, require different materials and manufacturing techniques. Specifically, the production of complex stator cores and segmented magnets presents significant challenges, often leading to higher costs. To address this issue, soft magnetic composite (SMC) materials, which offer greater design flexibility, are being explored for use in stator cores. However, soft magnetic composite materials exhibit lower permeability and saturation flux density compared to laminated silicon steel, resulting in reduced output torque and efficiency. This paper investigates the effects of stator geometry on axial flux motor performance and explores cladding core technology, which combines soft magnetic composite materials with silicon steel. By conducting finite element method (FEM) analysis to evaluate the output torque and efficiency based on the shape of the silicon steel within the cladding core, this study proposes an optimized cladding core design to enhance the efficiency and output torque of axial flux motors. Full article
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15 pages, 30937 KB  
Article
Multi-Scale Characterization of Porosity and Cracks in Silicon Carbide Cladding after Transient Reactor Test Facility Irradiation
by Fei Xu, Tiankai Yao, Peng Xu, Jason L. Schulthess, Mario D. Matos, Sean Gonderman, Jack Gazza, Joshua J. Kane and Nikolaus L. Cordes
Energies 2024, 17(1), 197; https://doi.org/10.3390/en17010197 - 29 Dec 2023
Cited by 2 | Viewed by 1920
Abstract
Silicon carbide (SiC) ceramic matrix composite (CMC) cladding is currently being pursued as one of the leading candidates for accident-tolerant fuel (ATF) cladding for light water reactor applications. The morphology of fabrication defects, including the size and shape of voids, is one of [...] Read more.
Silicon carbide (SiC) ceramic matrix composite (CMC) cladding is currently being pursued as one of the leading candidates for accident-tolerant fuel (ATF) cladding for light water reactor applications. The morphology of fabrication defects, including the size and shape of voids, is one of the key challenges that impacts cladding performance and guarantees reactor safety. Therefore, quantification of defects’ size, location, distribution, and leak paths is critical to determining SiC CMC in-core performance. This research aims to provide quantitative insight into the defect’s distribution under multi-scale characterization at different length scales before and after different Transient Reactor Test Facility (TREAT) irradiation tests. A non-destructive multi-scale evaluation of irradiated SiC will help to assess critical microstructural defects from production and/or experimental testing to better understand and predict overall cladding performance. X-ray computed tomography (XCT), a non-destructive, data-rich characterization technique, is combined with lower length scale electronic microscopic characterization, which provides microscale morphology and structural characterization. This paper discusses a fully automatic workflow to detect and analyze SiC-SiC defects using image processing techniques on 3D X-ray images. Following the XCT data analysis, advanced characterizations from focused ion beam (FIB) and transmission electron microscopy (TEM) were conducted to verify the findings from the XCT data, especially quantitative results from local nano-scale TEM 3D tomography data, which were utilized to complement the 3D XCT results. In this work, three SiC samples (two irradiated and one unirradiated) provided by General Atomics are investigated. The irradiated samples were irradiated in a way that was expected to induce cracking, and indeed, the automated workflow developed in this work was able to successfully identify and characterize the defects formation in the irradiated samples while detecting no observed cracking in the unirradiated sample. These results demonstrate the value of automated XCT tools to better understand the damage and damage propagation in SiC-SiC structures for nuclear applications. Full article
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11 pages, 2459 KB  
Article
Density Functional Theory Insight into Chemical Vapor Infiltration
by Eric A. Walker, Joseph J. Marziale and James Chen
Methane 2023, 2(4), 415-425; https://doi.org/10.3390/methane2040028 - 9 Nov 2023
Cited by 1 | Viewed by 2583
Abstract
Chemical Vapor Infiltration (CVI) has proven remarkably successful in producing strong and lightweight ceramic matrix composite materials. This technology has matured to regular industrial use. However, two fundamental problems remain, and those are the formation of pores and depositing of weaker material than [...] Read more.
Chemical Vapor Infiltration (CVI) has proven remarkably successful in producing strong and lightweight ceramic matrix composite materials. This technology has matured to regular industrial use. However, two fundamental problems remain, and those are the formation of pores and depositing of weaker material than silicon carbide (SiC), namely, Si. Definitive knowledge of the molecular mechanism would catalyze an advance in the chemical precursors used in CVI. In this work, the CVI reaction is modeled using density functional theory (DFT) calculations. The DFT calculations here use the Bayesian Error Estimation Functional with van der Waals correction (BEEF-vdW). The main findings begin with C deposition determining the rate of solid SiC growth due to Si being far more reactive. Therefore, increasing the C content of the precursor is a logical CVI strategy. Methane (CH4) is more reactive than ethane (C2H6) and ethylene (C2H2) and would be effective as an additive to the chemical precursor. Increasing the deposition rate of C has the benefit of decreasing pure Si deposits. Si melts at 1410 °C and CMCs are used in high-temperature settings beyond this melting point, including in aeroengines and nuclear fuel cladding. Full article
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24 pages, 5419 KB  
Review
Cladding Failure Modelling for Lead-Based Fast Reactors: A Review and Prospects
by Guan Wang, Zhaohao Wang and Di Yun
Metals 2023, 13(9), 1524; https://doi.org/10.3390/met13091524 - 28 Aug 2023
Cited by 11 | Viewed by 3958
Abstract
Lead-cooled fast reactors (LFRs) are considered one of the most promising technologies to meet the requirements introduced for advanced nuclear systems. LFRs have higher neutron doses, higher temperatures, higher burnup and an extremely corrosive environment. The failure studies of claddings play a vital [...] Read more.
Lead-cooled fast reactors (LFRs) are considered one of the most promising technologies to meet the requirements introduced for advanced nuclear systems. LFRs have higher neutron doses, higher temperatures, higher burnup and an extremely corrosive environment. The failure studies of claddings play a vital role in improving the safety criteria of nuclear reactors and promoting research on advanced nuclear materials. This paper presented a comprehensive review of the extreme environment in LFRs based on the fuel performance analyses and transient analyses of reference LFRs. It provided a clear image of cladding failure, focusing on the underlying mechanisms, such as creep, rupture, fatigue, swelling, corrosion, etc., which are resulted from the motions of defects, the development of microcracks and accumulation of fission products to some extent. Some fundamental parameters and behavior models of Ferritic/Martensitic (F/M) steels and Austenitic stainless (AuS) steels were summarized in this paper. A guideline for cladding failure modelling was also provided to bridge the gap between fundamental material research and realistic demands for the application of LFRs. Full article
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18 pages, 7322 KB  
Article
Developing a Reactivity-Equivalent Physical Transformation to Simulate an Axially Heterogeneous Boiling Water Reactor
by Robert Mossop, Bruno Merk, Maulik Patel, Tetsushi Hino and Aiden Peakman
Energies 2023, 16(8), 3359; https://doi.org/10.3390/en16083359 - 11 Apr 2023
Viewed by 1849
Abstract
Hitachi is advancing their designs for a conceptual reactor called the resource-renewable boiling water reactor (RBWR), a concept reactor similar to the advanced boiling water reactor with a harder neutron spectrum. This design aims to minimise construction costs and waste production as well [...] Read more.
Hitachi is advancing their designs for a conceptual reactor called the resource-renewable boiling water reactor (RBWR), a concept reactor similar to the advanced boiling water reactor with a harder neutron spectrum. This design aims to minimise construction costs and waste production as well as to utilise separated plutonium and minor actinide fuel. However, the axial heterogeneity of the design poses calculation difficulties. The aim of this work is to use a known method, reactivity-equivalent physical transformation (RPT), for calculating fuel with double heterogeneity and apply it to a BWR-type fuel pin. This could reduce the calculation time needed for optimisation of the design of the RBWR. The objective of the study is to use SCALE 6.2 to produce an equivalent axial pin model by comparison with the burnup and neutron spectra of a radial model of the fuel. This model can then be used for 2D burnup calculations, and in future work will be used for the generation of two-group and multigroup cross-sections for further deterministic calculations as part of a two-step approach for analysis of the RBWR. The RPT method has been extensively tested on spherical fuel, and SCALE is a standard industry code. The initial radial model is a hexagonal assembly with 20% enriched UO2 fuel in a zircaloy cladding, surrounded by light water moderator. The derived axial model has a water density distribution taken from Hitachi’s RBWR designs. Criticality over 70 GWd/tU burnup is estimated using the model. The application of the RPT to the BWR pin was shown to be possible, but to have limitations with the introduction of additional radial complexity. For a single pin, excellent agreement between the radial and axial models could be found across a range of water densities, but in the case of an assembly level calculation distinct equivalence models were required for each water density. In addition, the produced RPT model is validated using SCALE’s 3D Monte Carlo module, KENO. Full article
(This article belongs to the Special Issue Nuclear and New Energy Technology)
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17 pages, 4567 KB  
Review
Steam Oxidation of Silicon Carbide at High Temperatures for the Application as Accident Tolerant Fuel Cladding, an Overview
by Hai V. Pham, Masaki Kurata and Martin Steinbrueck
Thermo 2021, 1(2), 151-167; https://doi.org/10.3390/thermo1020011 - 27 Jul 2021
Cited by 26 | Viewed by 9466
Abstract
Since the nuclear accident at Fukushima Daiichi Nuclear Power Station in 2011, a considerable number of studies have been conducted to develop accident tolerant fuel (ATF) claddings for safety enhancement of light water reactors. Among many potential ATF claddings, silicon carbide is one [...] Read more.
Since the nuclear accident at Fukushima Daiichi Nuclear Power Station in 2011, a considerable number of studies have been conducted to develop accident tolerant fuel (ATF) claddings for safety enhancement of light water reactors. Among many potential ATF claddings, silicon carbide is one of the most promising candidates with many superior features suitable for nuclear applications. In spite of many potential benefits of SiC cladding, there are some concerns over the oxidation/corrosion resistance of the cladding, especially at extreme temperatures (up to 2000 °C) in severe accidents. However, the study of SiC steam oxidation in conventional test facilities in water vapor atmospheres at temperatures above 1600 °C is very challenging. In recent years, several efforts have been made to modify existing or to develop new advanced test facilities to perform material oxidation tests in steam environments typical of severe accident conditions. In this article, the authors outline the features of SiC oxidation/corrosion at high temperatures, as well as the developments of advanced test facilities in their laboratories, and, finally, give some of the current advances in understanding based on recent data obtained from those advanced test facilities. Full article
(This article belongs to the Special Issue Thermodynamics and Nuclear Materials)
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16 pages, 13573 KB  
Article
On the Use of Chromium Coating for Inner-Side Fuel Cladding Protection: Thickness Identification Based on Fission Fragments Implantation and Damage Profile
by Rofida Hamad Khlifa, Nicolay N. Nikitenkov and Viktor N. Kudiiarov
Coatings 2021, 11(6), 710; https://doi.org/10.3390/coatings11060710 - 12 Jun 2021
Cited by 8 | Viewed by 3032
Abstract
Inner-side coatings have been proposed as a complementary solution within the accident tolerant fuel (ATF) framework, to provide enhanced protection for the nuclear fuel cladding. Unlike external surface, the degradation of irradiated internal cladding surface has not been studied extensively. Fission fragments produced [...] Read more.
Inner-side coatings have been proposed as a complementary solution within the accident tolerant fuel (ATF) framework, to provide enhanced protection for the nuclear fuel cladding. Unlike external surface, the degradation of irradiated internal cladding surface has not been studied extensively. Fission fragments produced during the fission of nuclear fuel is one of the key players in this degradation. This study aimed to estimate the minimum thickness of the thin chromium film, required to protect the inner side of the nuclear fuel cladding. The approach used is based on a set of calculations, of Ion ranges and damage profiles, for a group fission fragments, using the TRIM code. The calculation results were verified by comparison with the experimental data associated with the phenomena of the inner cladding degradation of thermo-releasing elements. The recommended minimum thickness for such a film was found to be 9 microns. Calculations also showed that chromium metal has a greater stopping power compared to the zirconium-based alloy E110, which indicates an increased ability of chromium to withstand exposure to energetic fission fragments during reactor operation. Full article
(This article belongs to the Special Issue Advanced Coatings for Accident Tolerant Fuel Claddings)
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32 pages, 11036 KB  
Review
Recent Advances in Protective Coatings for Accident Tolerant Zr-Based Fuel Claddings
by Egor Kashkarov, Bright Afornu, Dmitrii Sidelev, Maksim Krinitcyn, Veronica Gouws and Andrey Lider
Coatings 2021, 11(5), 557; https://doi.org/10.3390/coatings11050557 - 9 May 2021
Cited by 106 | Viewed by 9289
Abstract
Zirconium-based alloys have served the nuclear industry for several decades due to their acceptable properties for nuclear cores of light water reactors (LWRs). However, severe accidents in LWRs have directed research and development of accident tolerant fuel (ATF) concepts that aim to improve [...] Read more.
Zirconium-based alloys have served the nuclear industry for several decades due to their acceptable properties for nuclear cores of light water reactors (LWRs). However, severe accidents in LWRs have directed research and development of accident tolerant fuel (ATF) concepts that aim to improve nuclear fuel safety during normal operation, operational transients and possible accident scenarios. This review introduces the latest results in the development of protective coatings for ATF claddings based on Zr alloys, involving their behavior under normal and accident conditions in LWRs. Great attention has been paid to the protection and oxidation mechanisms of coated claddings, as well as to the mutual interdiffusion between coatings and zirconium alloys. An overview of recent developments in barrier coatings is introduced, and possible barrier layers and structure designs for suppressing mutual diffusion are proposed. Full article
(This article belongs to the Special Issue Advanced Coatings for Accident Tolerant Fuel Claddings)
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23 pages, 4149 KB  
Review
Advanced Structural Materials for Gas-Cooled Fast Reactors—A Review
by Jakub Čížek, Jana Kalivodová, Miloš Janeček, Josef Stráský, Ondřej Srba and Anna Macková
Metals 2021, 11(1), 76; https://doi.org/10.3390/met11010076 - 1 Jan 2021
Cited by 36 | Viewed by 6563
Abstract
This review summarizes the development of the Gas-Cooled Fast Reactor (GFR) concept from the early 1970s until now, focusing specifically on structural materials and advanced fuel cladding materials. Materials for future nuclear energy systems must operate under more extreme conditions than those in [...] Read more.
This review summarizes the development of the Gas-Cooled Fast Reactor (GFR) concept from the early 1970s until now, focusing specifically on structural materials and advanced fuel cladding materials. Materials for future nuclear energy systems must operate under more extreme conditions than those in the current Gen II or Gen III systems. These conditions include higher temperatures, a higher displacement per atom, and more corrosive environments. This paper reviews previous GFR concepts in light of several promising candidate materials for the GFR system. It also reviews the recent development of nuclear power and its use in the peaceful exploration of space. The final section focuses on the development and testing of new advanced materials such as SiCf/SiC composites and high entropy alloys (HEA) for the construction and development of GFRs. Full article
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24 pages, 19567 KB  
Review
An Overview on Corrosion-Resistant Coating Technologies in Biomass/Waste-to-Energy Plants in Recent Decades
by Yuuzou Kawahara
Coatings 2016, 6(3), 34; https://doi.org/10.3390/coatings6030034 - 5 Aug 2016
Cited by 50 | Viewed by 12375
Abstract
Highly efficient electric power generation from biomass/waste fuels becomes an important worldwide issue to prevent global warming. In these plants, severe high-temperature corrosion and erosion-corrosion damage occur in boiler tubes influenced by HCl, SOx gases, and chlorides as contaminants in fuels. Coating [...] Read more.
Highly efficient electric power generation from biomass/waste fuels becomes an important worldwide issue to prevent global warming. In these plants, severe high-temperature corrosion and erosion-corrosion damage occur in boiler tubes influenced by HCl, SOx gases, and chlorides as contaminants in fuels. Coating technologies become important as a countermeasure for such damage, because of the easy maintenance, cost performance, and ease of application on various materials. In severe corrosive conditions of boilers, formation of dense, homogenous, and tough coating layers, as well as protective oxide layers of corrosion-resistant materials, are important. In the last 30 years, materials and coating processes applied in shop and on site have progressed based on many field observations and the consideration of deterioration mechanisms in order to maintain long lifetimes in the plants. Furthermore, new innovative coatings are now being developed by using advanced precise control, nanotechnologies, etc. This paper introduces recent trends of advanced coating developments and applications, such as weld-overlay, cladding, thermal spray coating, and slurry coating for biomass/waste boilers. Furthermore, the evaluation results of deterioration mechanisms and lifetime of coatings, and the future issue for innovative coatings, are presented. Full article
(This article belongs to the Special Issue High Temperature Coatings)
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