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Keywords = TSL furnace

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34 pages, 16142 KiB  
Review
A Review of Top-Submerged Lance (TSL) Processing—Part I: Plant and Reactor Engineering
by Avinash Kandalam, Markus A. Reuter, Michael Stelter, Markus Reinmöller, Martin Gräbner, Andreas Richter and Alexandros Charitos
Metals 2023, 13(10), 1728; https://doi.org/10.3390/met13101728 - 12 Oct 2023
Cited by 9 | Viewed by 7519
Abstract
Part I of this series of papers focuses on plant and reactor engineering aspects of the TSL reactor technology. A general flowsheet is presented, while emphasis is given to the definition of different reactor zones in terms of fluid dynamics and occurring reactions. [...] Read more.
Part I of this series of papers focuses on plant and reactor engineering aspects of the TSL reactor technology. A general flowsheet is presented, while emphasis is given to the definition of different reactor zones in terms of fluid dynamics and occurring reactions. Then, the technical advantages of TSL processing, such as feed flexibility and high conversion rates (due to induced turbulence), low dust generation, and low fugitive emissions, are explained. In addition, the reactor is analyzed part by part, also taking into account patent literature, focusing on furnace design, settling furnaces for molten phase disengagement, feeding systems regarding input material streams such as concentrates and fuels, vessel cooling arrangements, off-gas system, and aspects associated with the refractory lining. Furthermore, specific focus is given to the centerpiece of the TSL reactor, i.e., the reactor lance. Associated developments have focused on establishing a slag coating to hinder lance wear, i.e., the development of cooling mechanisms (e.g., use of fluid-cooled lance and shroud arrangements), the increment of O2 enrichment within the incoming air stream, and influencing of fluid dynamics (e.g., O2 conversion at the lance tip, bubble formation, and bath splashing). Finally, comprehensive tables concerning process developments and commissioned TSL plants are provided thus concluding Part I of the review. Full article
(This article belongs to the Special Issue Metal Extraction/Refining and Product Development)
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35 pages, 10654 KiB  
Article
Numerical Simulation Study on the Flow and Heat Transfer Characteristics of Subcooled N-Heptane Flow Boiling in a Vertical Pipe under External Radiation
by Jinhu Lin, Xiaohui Zhang, Xiaoyan Huang and Luyang Chen
Energies 2022, 15(10), 3777; https://doi.org/10.3390/en15103777 - 20 May 2022
Cited by 1 | Viewed by 2470
Abstract
In the top submerged lance (TSL) smelting process, flow boiling may occur in the lance’s inner pipe due to the heat coming from the furnace when liquid fuel is adopted. In the current study, a numerical simulation was carried out by coupling the [...] Read more.
In the top submerged lance (TSL) smelting process, flow boiling may occur in the lance’s inner pipe due to the heat coming from the furnace when liquid fuel is adopted. In the current study, a numerical simulation was carried out by coupling the Eulerian two-fluid model with the improved RPI wall boiling model to investigate the subcooled n-heptane flow boiling in the inner pipe. The effects of inlet velocity and pipe wall emissivity on two-phase flow and heat transfer are elucidated. The results show that, for pipes with inlet velocity ranging from 0.3 m·s−1 to 1.0 m·s−1, an increase in inlet velocity leads to a lower void fraction near the outlet, as well as a lower average velocity and a lower average temperature of each phase. Meanwhile, the Onset of Nucleate Boiling (ONB) position approaches to the outlet, and the total pressure drop of the entire pipe reduces when the inlet velocity increases. However, the opposite trends appear when increasing the pipe wall emissivity. The maximum wall temperature corresponding to the critical heat flux (CHF) point is slightly affected by inlet velocity but significantly affected by pipe wall emissivity. The non-equilibrium effect and the specific components of pressure drop are also further investigated. Full article
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20 pages, 8504 KiB  
Article
Numerical Simulation on the Influence of Submerged Combustion on Splashing and Heat Transfer in TSL Furnace
by Chen Song, Yuhua Pan, Ping Ma, Ming Zhao and Tiancai Liu
Metals 2022, 12(2), 328; https://doi.org/10.3390/met12020328 - 13 Feb 2022
Cited by 5 | Viewed by 2890
Abstract
Bath smelting technologies based on top submerged lance (TSL) injection have been widely used for pyrometallurgical metal production and solid waste treatment. In this work, a two-dimensional CFD simulation model of a pilot-scale 300 kg TSL furnace was established and applied to investigate [...] Read more.
Bath smelting technologies based on top submerged lance (TSL) injection have been widely used for pyrometallurgical metal production and solid waste treatment. In this work, a two-dimensional CFD simulation model of a pilot-scale 300 kg TSL furnace was established and applied to investigate the slag splashing phenomenon caused by submerged gas injection and combustion, with a special focus on the effect of submerged combustion on bubble formation, splash generation, splash distribution and heat transfer in the top space of the TSL furnace. The slag splash amount and distribution, and the temperature distribution characteristics inside the TSL furnace, especially under the influence of submerged combustion, were predicted, and influences of lance immersion depth and total injection gas flowrate on the splash behavior and heat transfer were investigated. As the lance immersion depth increases, more splashes are generated that distribute more evenly in the furnace top space and consequently heat transfer is enhanced. A larger injection gas flowrate generally increases the splash amount but the effect becomes weak when the injection gas flowrate exceeds a certain level, and there exists an appropriate range in injection gas flowrate for achieving the best heat transfer efficiency in TSL furnace. Full article
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8 pages, 2079 KiB  
Article
Optimization on Temperature Strategy of BOF Vanadium Extraction to Enhance Vanadium Yield with Minimum Carbon Loss
by Zhen-Yu Zhou and Ping Tang
Metals 2021, 11(6), 906; https://doi.org/10.3390/met11060906 - 2 Jun 2021
Cited by 8 | Viewed by 2372
Abstract
During the vanadium extraction process in basic oxygen furnace (BOF), unduly high temperature is unfavorable to achieve efficient vanadium yield with minimum carbon loss. A new temperature strategy was developed based on industrial experiments. The new strategy applies the selective oxidation temperature between [...] Read more.
During the vanadium extraction process in basic oxygen furnace (BOF), unduly high temperature is unfavorable to achieve efficient vanadium yield with minimum carbon loss. A new temperature strategy was developed based on industrial experiments. The new strategy applies the selective oxidation temperature between carbon and vanadium (Tsl) and the equilibrium temperature of vanadium oxidation and reduction (Teq) for the earlier and middle-late smelting, respectively. Industrial experiments showed 56.9 wt% of V was removed together with carbon loss for 5.6 wt% only in the earlier smelting. Additionally, 30 wt% of vanadium was removed together with carbon loss by 13.4 wt% in middle-late smelting. Applicability analyses confirmed Teq as the high-limit temperature, vanadium removal remains low and carbon loss increased sharply when the molten bath temperature exceeded Teq. With the optimized temperature strategy, vanadium removal increased from 69.2 wt% to 92.3 wt% with a promotion by 23 wt%. Full article
(This article belongs to the Special Issue Recovery and Recycling of Valuable Metals)
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