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Keywords = Neogene clay elevation

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27 pages, 11125 KB  
Article
Geochemical Insights and Mineral Resource Potential of Rare Earth Elements (REE) in the Croatian Karst Bauxites
by Erli Kovačević Galović, Nikolina Ilijanić, Nikola Gizdavec, Slobodan Miko and Zoran Peh
Minerals 2025, 15(2), 192; https://doi.org/10.3390/min15020192 - 19 Feb 2025
Cited by 1 | Viewed by 2369
Abstract
Karst bauxites are valuable terrestrial records of paleoclimate and tectonic evolution formed under tropical to subtropical conditions during the subaerial exposure of carbonate platforms. This study explores Croatian bauxite deposits within the Adriatic–Dinaric Carbonate Platform (ADCP), with a focus on the distribution and [...] Read more.
Karst bauxites are valuable terrestrial records of paleoclimate and tectonic evolution formed under tropical to subtropical conditions during the subaerial exposure of carbonate platforms. This study explores Croatian bauxite deposits within the Adriatic–Dinaric Carbonate Platform (ADCP), with a focus on the distribution and enrichment of rare earth elements (REE) across eight bauxite horizons from the Triassic to Neogene periods. The research applies statistical analyses of geochemical data, as well as developed models, to assess the factors influencing REE distribution and fractionation. The study found that variations in parent material, along with changes in paleogeographical and paleotectonic settings, significantly affected the REE content. The median REE concentrations in the analyzed bauxite horizons range from approximately 250 to 570 mg/kg. Notable REE enrichment was observed in the Late Paleogene, particularly in the Middle and Upper Eocene horizons. The analysis highlights the importance of physicochemical conditions, such as Eh and pH, during the weathering processes that lead to bauxite formation. The results suggest that the presence of REE-bearing minerals, rather than clay minerals, could possibly contribute to elevated concentrations of heavy REE (HREE). These findings indicate that Croatian bauxites, enriched in REE and associated trace elements, are significant not only as geological markers of past climatic and tectonic events but also as potential sources of critical raw materials. This study underscores the potential for the economic exploitation of these deposits in the context of modern technological demands. Full article
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15 pages, 7702 KB  
Article
The Influences of Local Glacitectonic Disturbance on Overconsolidated Clays for Upland Slope Stability Conditions: A Case Study
by Kamil Kiełbasiński, Paweł Dobak, Łukasz Kaczmarek and Sebastian Kowalczyk
Appl. Sci. 2021, 11(22), 10718; https://doi.org/10.3390/app112210718 - 13 Nov 2021
Cited by 9 | Viewed by 2502
Abstract
Reliability of equilibrium state evaluation about settlement slopes in the context of natural and human-made hazards is a complex issue. The geological structure of the vicinity of the upland slope in the urban environment of Warsaw is characterised by a significant spatial diversification [...] Read more.
Reliability of equilibrium state evaluation about settlement slopes in the context of natural and human-made hazards is a complex issue. The geological structure of the vicinity of the upland slope in the urban environment of Warsaw is characterised by a significant spatial diversification of the layers. This is especially due to the glacitectonics in the Mio-Pliocene clays, which are located shallowly under the sandy tills’ formations. With substantial variability in the clay roof surface, point recognition by drilling is often insufficient. The use of electrical resistivity imaging (ERI) in the quasi-3D variant provides accurate images of the real ground conditions, which is crucial in optimal geotechnical design. In forecasting the behaviour of the slope, it is necessary to quantify the impact of spatially differentiated systems of disturbed layers on changes in the safety factor (SF), which corresponds to the observed landslide activity of the Warsaw Slope. This study concerns numerous calculation model analyses of the optional clay position in the context of slope stability conditions. A wide range of soil properties variability was taken into account, resulting from both lithogenesis and subsequent processes disintegrating the original soil structure. Regarding the geological conditions of the slip surface, the use of classical computational methods and numerical modelling (FEM) was considered for comparative purposes. The results indicated that local changes in equilibrium conditions were affected by the different morphology of the clay roof surface of the slope and the alternation in strength characteristics on the slip surfaces. The findings of the study contribute to sustainable spatial planning of near-slope regions. Full article
(This article belongs to the Special Issue New Frontiers in Sustainable Geotechnics)
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