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Keywords = Kon-Tiki kiln

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23 pages, 3745 KiB  
Article
Towards Circularity in Anaerobic Digestion: Methane Yield Enhancement Using Biochar from Co-Pyrolysis of Anaerobic Sludge and Residual Lignocellulosic Biomass
by César Omar Díaz Lara, Diana Cabañas Vargas, Julio César Sacramento Rivero, Sergio Baz-Rodríguez, Juan Enrique Ruiz Espinoza, Erick Alberto Aguilera-Cauich, José Martín Baas-López and Daniella E. Pacheco-Catalán
Recycling 2025, 10(3), 84; https://doi.org/10.3390/recycling10030084 - 1 May 2025
Viewed by 1687
Abstract
Improper management of anaerobic pig sludge poses significant environmental and health risks. Converting this waste into biochar to enhance methane production during anaerobic digestion (AD) presents an environmentally sound and circular solution, especially when the biochar is produced through co-pyrolysis with lignocellulosic biomass [...] Read more.
Improper management of anaerobic pig sludge poses significant environmental and health risks. Converting this waste into biochar to enhance methane production during anaerobic digestion (AD) presents an environmentally sound and circular solution, especially when the biochar is produced through co-pyrolysis with lignocellulosic biomass residues. This study first determined the co-pyrolysis biomass ratio (anaerobic sludge to lignocellulosic biomass) that caused the highest increase on methane yield. Subsequently, the effects of biochar dosage (6, 12, 18, 24, and 30 g/L) and particle size (0.5–1 cm, 212–355 µm, and <53 µm) on methane production were assessed. Biochar derived from up to 25 % anaerobic pig sludge increased methane yield by 74.49 ± 1.25 % without compromising its catalytic effect. Methane yield was significantly affected by both biochar dosage and particle size, with best results observed at dosages of 12–18 g/L. These findings highlight the feasibility of the co-pyrolysis of anaerobic pig sludge and lignocellulosic residues as an attractive circular solution for integrated waste management and energy production. Full article
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18 pages, 5101 KiB  
Article
Life Cycle Assessment of Biochar from Residual Lignocellulosic Biomass Using Kon-Tiki Kilns: Applications in Soil Amendment and Wastewater Filtration
by Roxanna Pamela Ramírez López, Diana Cabañas Vargas, Erick Alberto Aguilera-Cauich and Julio César Sacramento Rivero
Recycling 2024, 9(6), 125; https://doi.org/10.3390/recycling9060125 - 17 Dec 2024
Cited by 2 | Viewed by 1342
Abstract
Producing biochar from residual biomass is an opportunity for health, environmental, and economic benefits to farmers in small traditional parcels, which are widespread in Latin America. This study presents a life cycle assessment of biochar in two circular economy scenarios: soil amendment and [...] Read more.
Producing biochar from residual biomass is an opportunity for health, environmental, and economic benefits to farmers in small traditional parcels, which are widespread in Latin America. This study presents a life cycle assessment of biochar in two circular economy scenarios: soil amendment and wastewater filtration. Seven mid-point environmental impact categories were assessed using the CML-IA method: acidification (AP), abiotic depletion (ADP), fossil fuels depletion (ADP-FF), eutrophication (EP), global warming (GWP), human toxicity (HTP), and smog formation (POCP). The soil amendment scenario showed lower impacts per tonne of biochar in all categories, especially for GWP (−801.3 kg CO2eq) and ADP-FF (−374.3 MJ), compared to the filtration scenario (−123.54 kg CO2eq and 827.85 MJ). Negative GWP values reflect reduced emissions from avoided fertilizers and carbon sequestration. However, POCP and HTP increased due to air emissions (CH4, NOx, NMVOC, and PM10) from the kiln. In both scenarios, biochar production contributed to 40–90% of the total impacts. Indirect emissions from electricity used for water pumping were identified as a hotspot in the filtration scenario. Full article
(This article belongs to the Special Issue Sustainability of the Circular Economy)
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10 pages, 260 KiB  
Article
Emission Factors for Biochar Production from Various Biomass Types in Flame Curtain Kilns
by Gerard Cornelissen, Clifton Makate, Jan Mulder, Jente Janssen, Jon Trimarco, Alfred Obia, Vegard Martinsen and Erlend Sørmo
Appl. Sci. 2024, 14(21), 9649; https://doi.org/10.3390/app14219649 - 22 Oct 2024
Cited by 1 | Viewed by 2455
Abstract
Simple and low-cost flame curtain (“Kon-Tiki”) kilns are currently the preferred biochar technology for smallholder farmers in the tropics. While gas and aerosol emissions have been documented for woody feedstocks (twigs and leaves) with varying moisture contents, there is a lack of data [...] Read more.
Simple and low-cost flame curtain (“Kon-Tiki”) kilns are currently the preferred biochar technology for smallholder farmers in the tropics. While gas and aerosol emissions have been documented for woody feedstocks (twigs and leaves) with varying moisture contents, there is a lack of data on emissions from other types of feedstocks. This study aims to document the gas and aerosol emissions for common non-woody feedstocks and to compare emissions from finely grained, high-lignin feedstock (coffee husk) with those from coarser, low-lignin feedstocks (maize cobs, grass, sesame stems). Throughout each pyrolysis cycle, all carbon-containing gases and NOx were monitored using hand-held sensitive instruments equipped with internal pumps. Carbon balances were used to establish emission factors in grams per kilogram of biochar. The resulting methane emissions were nearly zero (<5.5 g/kg biochar) for the pyrolysis of three dry (~10% moisture) maize cobs, grass, and a 1:1 mixture of grass and woody twigs. For sesame stems, methane was detected in only two distinct spikes during the pyrolysis cycle. Carbon monoxide (CO) and aerosol (Total Suspended Particles, TSP) emissions were recorded at levels similar to earlier data for dry twigs, while nitrogen oxide (NOx) emissions were negligible. In contrast, the pyrolysis of finely grained coffee husks generated significant methane and aerosol emissions, indicating that technologies other than flame curtain kilns are more suitable for finely grained feedstocks. The emission results from this study suggest that certification of biochar made from dry maize, sesame, and grass biomass using low-tech pyrolysis should be encouraged. Meanwhile, more advanced systems with syngas combustion are needed to sufficiently reduce CO, CH4, and aerosol emissions for the pyrolysis of finely grained biomasses such as rice, coffee, and nut husks. The reported data should aid overarching life-cycle analyses of the integration of biochar practice in climate-smart agriculture and facilitate carbon credit certification for tropical smallholders. Full article
19 pages, 1697 KiB  
Article
Characterization and Determination of the Toxicological Risk of Biochar Using Invertebrate Toxicity Tests in the State of Aguascalientes, México
by Felix Flesch, Pia Berger, Daniel Robles-Vargas, Gustavo Emilio Santos-Medrano and Roberto Rico-Martínez
Appl. Sci. 2019, 9(8), 1706; https://doi.org/10.3390/app9081706 - 25 Apr 2019
Cited by 24 | Viewed by 5685
Abstract
Following a quantitative analysis of adequate feedstock, comprising 11 woody biomass species, four biochars were generated using a Kon-Tiki flame curtain kiln in the state of Aguascalientes, Mexico. Despite the high quality (certified by European Biochar Certificate), the biochars contain substantial quantities of [...] Read more.
Following a quantitative analysis of adequate feedstock, comprising 11 woody biomass species, four biochars were generated using a Kon-Tiki flame curtain kiln in the state of Aguascalientes, Mexico. Despite the high quality (certified by European Biochar Certificate), the biochars contain substantial quantities of hazardous substances, such as polycyclic aromatic hydrocarbons, polychlorinated dibenzo-p-dioxins and dibenzofurans, polychlorinated biphenyls, and heavy metals, which can induce adverse effects if wrongly applied to the environment. To assess the toxicity of biochars to non-target organisms, toxicity tests with four benthic and zooplanktonic invertebrate species, the ciliate Paramecium caudatum, the rotifer Lecane quadridentata, and the cladocerans Daphnia magna and Moina macrocopa were performed using biochar elutriates. In acute and chronic toxicity tests, no acute toxic effect to ciliates, but significant lethality to rotifers and cladocerans was detected. This lethal toxicity might be due to ingestion/digestion by enzymatic/mechanic processes of biochar by cladocerans and rotifers of toxic substances present in the biochar. No chronic toxicity was found where biochar elutriates were mixed with soil. These data indicate that it is instrumental to use toxicity tests to assess biochars’ toxicity to the environment, especially when applied close to sensitive habitats, and to stick closely to the quantitative set-point values. Full article
(This article belongs to the Special Issue Biochar: Productions, Properties and Applications)
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