Search Results (8)

The ductile shear zones in northern Guangxi provide a crucial window for understanding Paleozoic collisional deformation and the tectonic evolution of the South China Block. The Jiufeng–Gandong ductile shear zone is located in the western part of the Motianling pluton in northern Guangxi. The penetrative mylonitic foliation within the ductile zone dips toward the ESE at angles of 55°–85°. Kinematic analyses indicate that the Jiufeng–Gandong ductile shear zone experienced sinistral thrust shearing. Anisotropy of magnetic susceptibility (AMS) results show that the shear zone generally strikes in an NNE direction, with a length exceeding 30 km and a maximum width of more than 2.5 km. The flattening degree (E value) of the magnetic susceptibility ellipsoid suggests that deformation within the shear zone is dominated by flattening strain, accompanied by a component of extensional strain. Quartz dynamic recrystallization mechanisms and electron backscatter diffraction (EBSD) analyses indicate that the sinistral thrust shearing occurred at deformation temperatures of approximately 350–650 °C. LA–ICP–MS U–Pb dating of zircons from a mafic mylonite yields a crystallization age of 443.0 ± 2.8 Ma. By integrating macro- and microstructural observations, magnetic fabric data, quartz EBSD fabric analyses, regional published geochronological constraints, and hydrothermal zircon U–Pb ages obtained in this study, we propose that the Jiufeng–Gandong ductile shear zone developed during Caledonian thrusting of the Cathaysia Block onto the Yangtze Block from SE to NW. Under collisional compression, the shear zone underwent medium- to high-temperature sinistral thrust shearing accompanied by dominant flattening strain. These results elucidate the geometry, strain characteristics, and tectonic regime of the Jiufeng–Gandong ductile shear zone, providing new insights into the Caledonian tectonic evolution of South China. Full article

The Pułtusk meteorite, classified as an H5 ordinary chondrite, is one of the best documented Polish falls, yet some important data on its physical and thermophysical properties remain limited. This study provides new measurements and derived parameters of its physical and thermophysical properties that complement existing datasets for the Pułtusk meteorite and H chondrites in two important ways. Firstly, they cover a temperature range previously not explored. Secondly, using techniques generally applied in geology to validate the novel techniques developed recently, bulk and grain densities, porosity, and specific heat capacity were determined using the Archimedean method and differential scanning calorimetry, supported by bulk chemical analyses performed by ICP-MS and ICP-ES. The chemical composition of Pułtusk closely matches that of average H chondrites, though Fe and Ni contents are about 15–20% lower, likely due to weathering effects. Measured bulk density, grain density, and porosity are 3.30 g/cm³, 3.41 g/cm³, and 3.22%, respectively. The specific heat capacity increases from 564 to 1147 J/(kg·K) between 223 and 773 K, with 699 J/(kg·K) at 300 K. Derived thermophysical parameters include thermal conductivity, thermal diffusivity, and thermal inertia at 200 K, 300 K, and low pressure, and in ambient air. These results are consistent with previous data for H chondrites and confirm Pułtusk as a representative sample of this group. The new dataset can enhance the accuracy of models describing the Yarkovsky effect, meteoroid atmospheric entry, and the thermal evolution of ordinary chondrite parent bodies. Full article

This study investigates the process of long-term (bio)degradation of polyethylene (PE) in an old municipal waste landfill (MWL) and its implications for environmental and human health. Advanced techniques, such as ICP–ES/MS and IC–LC, were used to analyze heavy metals and anions/cations, demonstrating significant concentration deviations from control samples. The soil’s chemical composition revealed numerous hazardous organic compounds, further indicating the migration of additives from PE to the soil. Toxicological assessments, including Phytotoxkit F^TM, Microtox^® bioassay, and Ostracodtoxkit^®, demonstrated phytotoxicity, acute toxicity, and high mortality in living organisms (over 85% for Heterocypris Incongruens). An unusual concentration of contaminants in the MWL’s middle layers, linked to Poland’s economic changes during the 1980s and 1990s, suggests increased risks of pollutant migration, posing additional environmental and health threats. Moreover, the infiltration capability of microorganisms, including pathogens, into PE structures raises concerns about potential groundwater contamination through the landfill bottom. This research underscores the need for vigilant management and updated strategies to protect the environment and public health, particularly in older landfill sites. Full article

Elaeocarpus sylvestris var. ellipticus (ES), which our research group had confirmed inhibits influenza A and SARS-CoV-2 viruses, was investigated to identify new potent and selective inhibitors of herpes simplex virus-1 (HSV–1) replication. To clarify the optimal condition for ES extract (ESE), ES was extracted at different concentrations of 0, 30, 50, 70, and 100%, to screen for its anti-HSV–1 effect. Among these ESE samples, ESE50 (50% concentration) exhibited the strongest inhibition of HSV–1 replication (EC₅₀ 23.2 μg/mL) while showing low cytotoxicity on host cells (IC₅₀ 342.8 μg/mL). The treatment of ESE50 clearly demonstrated a decrease in the expression of ICP0 in the lungs of HSV–1-infected BALB/c nude mice, compared to the MOCK group. Geraniin, which was isolated from ESE50 and analyzed using ESI−MS and 1D−(¹H− and ¹³C−) and 2D−NMR, showed greater potency in inhibiting HSV–1 replication, as determined by the plaque reduction assay (EC₅₀ 8.3 μg/mL) and luciferase inhibition (EC₅₀ 36.9 μg/mL). The results demonstrate that ESE50 and geraniin show great potential as candidates for new drug discovery in the treatment of HSV–1 and related diseases. Full article

The aim of this study is to determine the total iodine content in Korean abalone (Haliotis discus hannai) and to investigate the bioavailability of iodine using an in vitro method. This research paper focuses on total iodine quantification in abalone (Haliotis discus hannai) and its components (viscera and muscle) using inductively coupled plasma mass spectrometry (ICP-MS). Additionally, an in vitro bioavailability study explored iodine absorption potential. Abalone pretreatment involved both the European standard method (ES) and microwave-assisted extraction method (MAE). The limits of detection (LOD) were 0.11 ng/g for both ES and MAE, with a limit of quantification (LOQ) of 5.4 ng/g for MAE. Accuracy, assessed using a reference material (fish muscle, ERM—BB422), showed values of 1.5 ± 0.010 mg/kg for ES and 1.6 ± 0.066 mg/kg for MAE, within an acceptable range of 1.4 ± 0.42 mg/kg. Precision, evaluated using the Horwitz ratio (HorRat) with a reference material, was determined to be 0.45 for ES and 0.27 for MAE. Therefore, total iodine contents were estimated as 74 ± 2.2 µg/g for abalone viscera and 17 ± 0.77 µg/g for abalone muscle with ES, and 76 ± 1.0 µg/g for abalone viscera and 17 ± 0.51 µg/g for abalone muscle with MAE. Recovery tests demonstrated an acceptable range of 90–110%. In the in vitro bioavailability assessment, digestion efficiency yielded ranges of 42–50.2% for viscera and 67–115% for muscle. Absorption efficiency variations were determined as 37–43% for viscera and 48–75% for muscle. Full article

The main objective of this study is to map multi-element geochemical anomalies in soil on a regional scale. We aimed to determine and evaluate the baseline geochemical values and main geochemical trends in soil that may serve as reference values against any future changes. A total of 817 topsoil samples (0–10 cm) were collected in a 5 × 5 km grid and analyzed for 35 elements using ICP-ES after multi-acid digestions (HClO₄/HNO₃/HCl/HF) and 53 elements using ICP-MS after modified aqua regia digestion (HCl/HNO₃/H₂O). The analytical results for the two different digestion methods (multi-acid digestion vs. aqua regia) were also compared for each chemical element. Multivariate statistical methods were applied to identify the geochemical trends and main sources of trace elements over the territory of Slovenia. Based on these results, seven natural and one mixed natural/anthropogenic geochemical association were established. The contents and trends of the determined factors are presented according to 8 natural units, 4 drainage areas, and geological units characteristic of Slovenia. The identified anthropogenic geochemical association combines toxic elements (Ag, Bi, Cd, Hg, P, Pb, S, Sn, and Zn). Increased values of these elements can be found in mining areas and metallurgic centers, in Quaternary sediments of the Sava River, and Adriatic Basin as the consequence of past mining activities and in the Julian Alps, where their origin could be connected to the atmospheric deposition. Full article

The European Commission has adopted the European Green Deal strategy, which aims to achieve climate neutrality in the EU by 2050. To achieve this goal, it is necessary to shift the economy toward the use of green and renewable energy. Critical raw materials (CRMs), Li, Co, REE, Te, Sc and others, are used in renewable energy sources (RES) production. The EU lacks its own CRM deposits, and additionally, the access to already identified deposits is limited, which is making the EU countries search for alternative CRM sources. One such source of CRMs may be mining waste generated on the Indonesian island of Bangka as a result of processing cassiterite-bearing sands. Studies of the mineral composition of the waste using the XRD method reveal rich contents of xenotime (0.79–17.55 wt%), monazite (1.55–21.23 wt%), zircon (1.87–64.35 wt%) and other minerals, carriers of valuable metals, such as Sn, Ti, Nb, Ta. The point mineral chemistry analyses were performed using EPMA. Xenotime is the main carrier of heavy rare earth elements (HREE), especially the “most critical” HREEs: Gd₂O₃ (1.42–7.16 wt%), Dy₂O₃ (2.28–11.21 wt%), Er₂O₃ (2.44–7.85 wt%), and Yb₂O₃ (1.71–7.10 wt%). Xenotime is characterized by a complex internal structure resulting from metasomatic processes occurring during their formation. In SEM-BSE imaging, they show zonation of internal structure, which is the effect of an HREE, Y, Si and U substitution in the crystal structure. On the other hand, thorite ThSiO₄ and uranothorite (Th,U)SiO₄ inclusions are present in xenotimes. The ICP-MS/ES studies of tailings reveal very high contents of HREE + Y (up to 7.58 wt%), U (up to 0.11), Th (up to 0.75 wt%) and Sc (132 ppm). A CRM source diversification is part of the strategy to ensure the security of raw materials for countries of the European Union and the green transformation of the continent. Bilateral EU–Indonesia cooperation in the geological exploration and development of primary and secondary sources may contribute to an increase in the supply of HREEs to the global market. Full article

Loki’s Castle on the Arctic Mid-Ocean Ridge (AMOR) is an area of possible seafloor massive sulphide (SMS)-style mineralisation under Norwegian jurisdiction, which, due to mounting social pressure, may be a strategic future source of base and precious metals. The purpose of this study is to characterise mineralised material from a hydrothermal vent system on the AMOR in detail for the first time, and to discuss the suitability of methods used; reflected light microscopy, X-ray diffraction (XRD), whole rock geochemistry, electron probe micro-analysis (EPMA), and QEMSCAN. The primary sulphide phases, identifiable by microscopy, are pyrite and marcasite with minor pyrrhotite and galena, but multiple samples from the Loki’s Castle contain economically interesting quantities of copper (hosted in isocubanite and chalcopyrite) and zinc (hosted in sphalerite), as well as silver and gold. This reinforces the notion that slow spreading ridges may host significant base metal deposits. Micro-textures (chalcopyrite inclusions and exsolutions in sphalerite and isocubanite respectively) are typically undefinable by QEMSCAN, and require quantitative measurement by EPMA. QEMSCAN can be used to efficiently generate average grain size and mineral association data, as well as composition data, and is likely to be a powerful tool in assessing the effectiveness of SMS mineral processing. Full article