Search Results (7)

This study presents theoretical and experimental investigations into the electron and hole color centers in BaFBr crystals, characterizing their electronic and optical properties. Stoichiometric BaFBr crystals grown by the Steber method were used in the experiments. Radiation defects in BaFBr crystals were created by irradiation with 147 MeV ⁸⁴Kr ions with up to fluences of 10¹⁰–10¹⁴ ions/cm². The formation of electron color centers (F(F⁻), F₂(F⁻), F₂(Br⁻)) and hole aggregates was experimentally established by optical absorption spectroscopy. Performed measurements are compared with theoretical calculations. It allows us to determine the electron transition mechanisms and investigate the processes involved in photoluminescence emission in Eu-doped BaFBr materials to enhance the understanding of the fundamental electronic structure and properties of electron and hole color centers formed in BaFBr crystals. Full article

The synthesis and characterization of novel luminescent amorphous POSS-based polysilsesquioxanes (PSQs) with Tb³⁺ and Eu³⁺ ions directly integrated in the polysilsesquioxane matrix is presented. Two different Tb³⁺/Eu³⁺ molar ratios were applied, with the aim of disclosing the relationships between the nature and loading of the ions and the luminescence properties. Particular attention was given to the investigation of site geometry and hydration state of the metal centers in the inorganic framework, and of the effect of the Tb³⁺ → Eu³⁺ energy transfer on the overall optical properties of the co-doped materials. The obtained materials were characterized by high photostability and colors of the emitted light ranging from orange to deep red, as a function of both the Tb³⁺/Eu³⁺ molar ratio and the chosen excitation wavelength. A good energy transfer was observed, with higher efficiency displayed when donor/sensitizer concentration was lower than the acceptor/activator concentration. The easiness of preparation and the possibility to finely tune the photoluminescence properties make these materials valid candidates for several applications, including bioimaging, sensors, ratiometric luminescence-based thermometers, and optical components in inorganic or hybrid light-emitting devices. Full article

This paper submits experimental results of a study directed towards the formation of Eu ions’ luminescent centers in CVD diamond films. A new approach is based on use of diamond nanoparticles with a surface modified with Eu ions for seeding at CVD growth. Nanocrystalline diamond films (NCD) doped with Eu have been grown from the gas phase on silicon substrates by microwave plasma-assisted CVD at a frequency of 2.45 GHz. The photoluminescence spectra clearly show several electronic transitions of the Eu³⁺ ions, which confirm the incorporation of Eu ions into the NCD film. Full article

An europium doped BaO–B₂O₃–BaCl₂ chloroborate glass-ceramic containing a BaCl₂ nanocrystalline phase was produced by melt-quenching followed by glass crystallization during annealing. Structural and morphological investigations using x-ray diffraction and scanning electron microscopy have shown fvBaCl₂ nanocrystals of about tens of nm size accompanied by a smaller amount of the BaB₂O₄ crystalline phase. Photoluminescence spectra have indicated the reduction of Eu³⁺ to Eu²⁺ during processing in air or a reducing atmosphere. The spectra analysis showed the presence of Eu³⁺ ions in the borate glass matrix, while the Eu²⁺ were incorporated in both the BaCl₂ nanocrystals and glass matrix. Thermoluminescence properties were due to the recombination of F(Cl) centers and Eu²⁺ related hole centers produced by irradiation within the BaCl₂ nanocrystals. The color impression of the samples and the photoluminescence quantum efficiency were influenced by the glass processing. Full article

Calcia-alumina binary compounds doped with rare earths and some transition metals cations show persistent luminescence from the visible to the infrared range. Specifically, the blue light can be obtained through the Eu²⁺ activator center in a potential host, such as dodecacalcium hepta-aluminate (Ca₁₂Al₁₄O₃₃) and monocalcium aluminate (CaAl₂O₄). By doping with Nd³⁺, the persistent luminescence can be substantially prolonged; for this reason, the Eu/Nd pair is a potential choice for developing long-lasting blue luminescence. Herein, the phase evolution of the calcia-alumina system via molten salt synthesis is reported as a function of the synthesis temperature and the atmospheric environment. The fraction of CaAl₂O₄ phase increases when the temperature is higher. Synthesized microparticles of platelet-type morphology represent isolated nanostructured ceramic pieces. Under visible light, the particles are white. This indicates that the followed process solves the dark-gray coloring of phosphor when is synthesized in a reduced atmosphere at high temperature. As regards the synthesis mechanism, which is assisted by the molten flux, the dissolution−diffusion transport process is promoted at the surface of the alumina microparticles. In fact, the emission intensity can be modulated through the phase of the Eu-doped calcium-aluminate discrete platelets synthesized. Consequently, the photoluminescence intensity depends also on the oxidation state of the Eu ion. X-ray absorption near-edge structure and photoluminescence measurements corroborate the Eu reduction and the grain coarsening with the enhancement of the blue emission. The doped phosphors with Eu/Nd show a broad and strong absorption in the region of 320–400 nm and a broad emission band at around 440 nm when they are excited in this absorption range. From a broader perspective, our findings prove that the Ca₁₂Al₁₄O₃₃ and CaAl₂O₄ phases open new opportunities for research into the design of blue long-lasting emitters for a wide range of fields from ceramic to optoelectronic materials. Full article

The effect of the polyvinylpyrrolidone (PVP, M_W = 130,000) molar content, PVP/Lu = 1, 2.5, 4 and 5; on the photoluminescent and structural properties of sol-gel derived Lu₂O₃:Eu³⁺, Bi³⁺ has been analyzed. Thin hybrid films were deposited by means of the dip-coating technique on silica quartz substrates. Films deposited at 700 °C presented a cubic structure, with non-preferential orientation, even with the presence of PVP. The photoluminescence (PL) spectrum and Comission Internationale de l’Éclairage (CIE) chromaticity diagram of films revealed a reddish Eu³⁺ emission at 612 nm (⁵D₀ → ⁷F₂) with an excitation at 320 nm of the Bi ions (6s² → 6s6p), showing a highly-effective energy transfer process form Bi³⁺ to Eu³⁺ luminescent centers. On the other hand, the color temperature of the samples is strongly dependent on the PVP content, as a consequence of the observed difference on the branching ratios of ⁵D₀ → ⁷F_J transitions of europium ions. Lifetime studies present two different behaviors for the thin films: A non-exponential nature for the lower PVP contents, and a simple exponential nature for the highest PVP one, showing that the PVP tends to promote a better dissolution of segregates and, therefore, increases the lifetime of the Eu³⁺ emission. Full article

White-light emitting materials have emerged as important components for solid state lighting devices with high potential for the replacement of conventional light sources. Herein, amine-functionalized organic-inorganic di-ureasil hybrids consisting of a siliceous skeleton and oligopolyether chains codoped with lanthanide-based complexes, with Eu³⁺ and Tb³⁺ ions and 4,4′-oxybis(benzoic acid) and 1,10-phenanthroline ligands, and the coumarin 1 dye were synthesized by in situ sol–gel method. The resulting luminescent di-ureasils show red, green, and blue colors originated from the Eu³⁺, Tb³⁺, and C1 emissions, respectively. The emission colors can be modulated either by variation of the relative concentration between the emitting centers or by changing the excitation wavelength. White light emission is achieved under UV excitation with absolute quantum yields of 0.148 ± 0.015, 0.167 ± 0.017, and 0.202 ± 0.020 at 350, 332, and 305 nm excitation, respectively. The emission mechanism was investigated by photoluminescence and UV–visible absorption spectroscopy, revealing an efficient energy transfer from the organic ligands to the Ln³⁺ ions and the organic dye, whereas negligible interaction between the dopants is discerned. The obtained luminescent di-ureasils have potential for optoelectronic applications, such as in white-light emitting diodes. Full article