Search Results (4)

M-edge X-ray absorption spectroscopy (XAS), which probes 3p→3d transitions in first-row transition metals, provides detailed insights into oxidation states, spin-states, and local electronic structure with high element and orbital specificity. Operating in the extreme ultraviolet (XUV) region, this technique provides sharp multiplet-resolved features with high sensitivity to ligand field and covalency effects. Compared to K- and L-edge XAS, M-edge spectra exhibit significantly narrower full widths at half maximum (typically 0.3–0.5 eV versus >1 eV at the L-edge and >1.5–2 eV at the K-edge), owing to longer 3p core-hole lifetimes. M-edge measurements are also more surface-sensitive due to the lower photon energy range, making them particularly well-suited for probing thin films, interfaces, and surface-bound species. The advent of tabletop high-harmonic generation (HHG) sources has enabled femtosecond time-resolved M-edge measurements, allowing direct observation of ultrafast photoinduced processes such as charge transfer and spin crossover dynamics. This review presents an overview of the fundamental principles, experimental advances, and current theoretical approaches for interpreting M-edge spectra. We further discuss a range of applications in catalysis, materials science, and coordination chemistry, highlighting the technique’s growing impact and potential for future studies. Full article

This study aims to tackle the challenge of high noise levels on balconies while preserving natural ventilation. Eight innovative balcony designs, incorporating elements like diffuser edges, undulating ceilings, Helmholtz resonators, grooves, or sound traps, were evaluated via finite element (FE) modeling. The insertion loss results showed that for many balcony designs, noise reduction in the balcony could deteriorate beyond an elevation of 8 m. However, the front jagged and full wavy ceiling designs were shown to be more robust in noise attenuation across balconies on different floors. The jagged ledge and grooved parapet designs yielded an overall 1.5 dBA lower SPL at the exterior regions, compared to other designs, which implies that the designs are less acoustically detrimental to nearby residential blocks as they tend to diffract and absorb incident noise. The jagged ledge design is more effective for lower floors while the jagged ceiling design is more effective for higher floors. A combination of the protruded jagged ledge for the lower floor and jagged balcony ceiling for the higher floor would result in the lowest noise ingress over three stories of residential units: this would be capable of achieving more than 3 dB noise reduction and would offer viable options for improving balcony noise mitigation, by providing valuable insights to architects and designers seeking practical solutions for outdoor noise reduction. Our study highlights that whereas the spectrum characteristics of acoustic absorption materials may be less tunable, and where reduced head space is traded for thicker material for greater ab-sorption and added affixation and maintenance cost, the jagged ledge and ceiling curvatures can actually be shape-tuned, say for every 3 to 4 floors up the high-rise to more effective reduce noise ingress and possibly improve the architecture façade outlook. Full article

Electrons are produced in the Earth’s quiet nighttime mesosphere by ionization by cosmic rays and ionization of NO by Lyman-$\alpha$ radiation. They are removed by attachment or recombination processes that are usually assumed in modelling to occur at the ambient temperature. However, the electrons have initial energies that are much higher than at thermal equilibrium, and so must have a range of energies as they progress towards equilibrium via interactions with atoms and molecules. As attachment and recombination rates are dependent on the electron energy, it is possible that modelling that considers the actual energy of the electrons will give different results to those based on assuming that the electrons are at the ambient temperature. In this work, starting with electrons at a higher initial energy, the detailed electron interactions (including elastic scattering and vibrational excitation of molecules) are tracked in a time-step simulation. This simulation is implemented by treating electrons in subranges of the electron energy spectrum as chemical species. This allows an investigation of two phenomena in the nighttime mesosphere: the origin of the D-region ledge and the production of radiative emissions from vibrationally excited molecules. It is found that there is negligible difference in the electron densities calculated using the ambient temperature or detailed interaction models, so this study does not provide an explanation for the D-region ledge. However, in the latter model, emissions at various wavelengths are predicted due to reactions involving vibrationally excited molecules. It is also found, using the time-step calculation, that it would take several hours for the predicted electron density to approach equilibrium. Full article

Rock-carved cultural heritage sites are often developed in slopes formed by weak rocks, which due to their peculiar lithological, geotechnical, and morpho-structural features are characterized by excellent carvability, which at the same time makes them prone to weathering, deterioration, and slope instability issues. In this context the use of advanced close-range nondestructive techniques, such as Infrared Thermography (IRT) and Unmanned Aerial vehicle-based Digital Photogrammetry (UAV-DP) can be profitably used for the rapid detection of conservation issues (e.g., open fractures, unstable ledges-niches, water seepage and moisture) that can lead to slope instability phenomena. These techniques, when combined with traditional methods (e.g., field surveys, laboratory analysis), can provide fundamental data (such as 3D maps of the kinematic mechanisms) to implement a site-specific and interdisciplinary approach for the sustainable protection and conservation of such fragile cultural heritage sites. In this paper some examples of conservation problems in several rupestrian sites characterized by different geological contexts, from the mountainous regions of Georgia to the ancient city of Petra in Jordan, are presented, with the aim of evaluating the potential of the proposed integrated approach. The final aim is to provide conservators, practitioners, and local authorities with a useful, versatile, and low-cost methodology, to be profitably used in the protection and conservation strategies of rock-carved sites. Full article