To reduce production costs and enhance the high-temperature resistance of SiO
2 aerogels, an aluminum-doped silica aerogel (ASA) was successfully prepared using the sol-gel method and atmospheric drying method. The composite silica sources included TEOS and inexpensive acidic silica sol, while the aluminum
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To reduce production costs and enhance the high-temperature resistance of SiO
2 aerogels, an aluminum-doped silica aerogel (ASA) was successfully prepared using the sol-gel method and atmospheric drying method. The composite silica sources included TEOS and inexpensive acidic silica sol, while the aluminum source was aluminum sol. The study investigated the influence of the molar ratio of acidic silica sol to TEOS, Al/Si, and calcination temperature on the composition, structure, and high-temperature resistance of the ASA. The results indicate that a sample with an acidic silica sol to TEOS molar ratio of 0.8 achieved a specific surface area of 683.204 m
2·g
−1. The Al/Si molar ratio significantly impacted the high-temperature resistance of the ASA, with the sample having a molar ratio of 0.02 Al/Si displaying the highest specific surface area of 705.956 m
2·g
−1 at 600 °C. Moreover, this surface area remained at 273.099 m
2·g
−1 after calcination at 1000 °C, notably higher than the sample without aluminum sol (16.082 m
2·g
−1). Mechanism analysis indicated that the addition of aluminum sol to the SiO
2 aerogel inhibited phase transitions, and both acidic silica sol and aluminum sol particles enhanced the aerogel structure, contributing to a marked improvement in high-temperature resistance.
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