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Keywords = Akbari-Ganji’s method

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13 pages, 4787 KiB  
Article
New Analytical Expressions of Concentrations in Packed Bed Immobilized-Cell Electrochemical Photobioreactor
by Ponraj Jeyabarathi, Marwan Abukhaled, Murugesan Kannan, Lakshmanan Rajendran and Michael E. G. Lyons
Electrochem 2023, 4(4), 447-459; https://doi.org/10.3390/electrochem4040029 - 29 Sep 2023
Cited by 3 | Viewed by 1907
Abstract
An electrochemical photobioreactor with a packed bed containing transparent gel granules and immobilized photosynthetic bacterial cells is shown with a one-dimensional two-phase flow and transport model. We consider the biological/chemical events in the electrochemical photobioreactor, the intrinsically connected two-phase flow and mass transport, [...] Read more.
An electrochemical photobioreactor with a packed bed containing transparent gel granules and immobilized photosynthetic bacterial cells is shown with a one-dimensional two-phase flow and transport model. We consider the biological/chemical events in the electrochemical photobioreactor, the intrinsically connected two-phase flow and mass transport, and other factors. This model is based on a system of nonlinear equations. This paper applies Akbari-Ganji’s and Taylor series methods to find analytical solutions to nonlinear differential equations that arise in an immobilized-cell electrochemical photobioreactor. Approximate analytical expressions of the concentration of glucose and hydrogen are obtained in liquid and gas phases for different parameter values. Numerical simulations are presented to validate the theoretical investigations. Full article
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11 pages, 5449 KiB  
Article
Theory for Electrochemical Heat Sources and Exothermic Explosions: The Akbari–Ganji Method
by Ramalingam Vanaja, Ponraj Jeyabarathi, Lakshmanan Rajendran and Michael Edward Gerard Lyons
Electrochem 2023, 4(3), 424-434; https://doi.org/10.3390/electrochem4030027 - 5 Sep 2023
Cited by 2 | Viewed by 2294
Abstract
A device that transforms chemical energy into electrical energy is an electrochemical cell. The reaction type inside the cell determines whether it is exothermic or endothermic. This paper discusses the mathematical modelling of exothermic explosions in a slab. This model is based on [...] Read more.
A device that transforms chemical energy into electrical energy is an electrochemical cell. The reaction type inside the cell determines whether it is exothermic or endothermic. This paper discusses the mathematical modelling of exothermic explosions in a slab. This model is based on a nonlinear equation containing a nonlinear term related to Arrhenius, bimolecular, and sensitised laws of reaction kinetics. The absolute temperature can be derived by solving the nonlinear equation using the Akbari–Ganji technique. The mathematical model also numerically solved and simulated in the MATLAB® v2016b software. The new simple theoretical result is validated with previously identified analytical and numerical findings. The influence of the parameters of Frank-Kamenetskii number, activation energy and the numerical exponent on temperature is discussed. The Frank-Kamenetskii number is observed to drop as the temperature is found to decrease, while the activation energy parameter is shown to increase. The numerical exponent has little or no effect on the temperature. An extension of this model to cylinder and sphere geometry is also provided. Full article
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14 pages, 1199 KiB  
Article
Theoretical Analysis of Mass Transfer Behavior in Fixed-Bed Electrochemical Reactors: Akbari-Ganji’s Method
by Ponraj Jeyabarathi, Lakshmanan Rajendran, Michael E. G. Lyons and Marwan Abukhaled
Electrochem 2022, 3(4), 699-712; https://doi.org/10.3390/electrochem3040046 - 17 Oct 2022
Cited by 15 | Viewed by 2978
Abstract
The theoretical model for a packed porous catalytic particle of the slab, cylindrical, and spherical geometries shape in fixed-bed electrochemical reactors is discussed. These particles have internal mass concentration and temperature gradients in endothermic or exothermic reactions. The model is based on a [...] Read more.
The theoretical model for a packed porous catalytic particle of the slab, cylindrical, and spherical geometries shape in fixed-bed electrochemical reactors is discussed. These particles have internal mass concentration and temperature gradients in endothermic or exothermic reactions. The model is based on a nonlinear reaction–diffusion equation containing a nonlinear term with an exponential relationship between intrinsic reaction rate and temperature. The porous catalyst particle’s concentration is obtained by solving the nonlinear equation using Akbari-Ganji’s method. A simple and closed-form analytical expression of the effectiveness factor for slab, cylindrical, and spherical geometries was also reported for all values of Thiele modulus, activation energy, and heat reaction. The accordance with results of a reliable numerical method shows the good accuracy that their approximate solution yields. Full article
(This article belongs to the Special Issue Feature Papers in Electrochemistry)
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13 pages, 1345 KiB  
Article
Modelling of Irreversible Homogeneous Reaction on Finite Diffusion Layers
by Singaravel Anandhar Salai Sivasundari, Rathinam Senthamarai, Mohan Chitra Devi, Lakshmanan Rajendran and Michael E. G. Lyons
Electrochem 2022, 3(3), 479-491; https://doi.org/10.3390/electrochem3030033 - 26 Aug 2022
Cited by 4 | Viewed by 2410
Abstract
The mathematical model proposed by Chapman and Antano (Electrochimica Acta, 56 (2010), 128–132) for the catalytic electrochemical–chemical (EC’) processes in an irreversible second-order homogeneous reaction in a microelectrode is discussed. The mass-transfer boundary layer neighbouring an electrode can contribute to the electrode’s measured [...] Read more.
The mathematical model proposed by Chapman and Antano (Electrochimica Acta, 56 (2010), 128–132) for the catalytic electrochemical–chemical (EC’) processes in an irreversible second-order homogeneous reaction in a microelectrode is discussed. The mass-transfer boundary layer neighbouring an electrode can contribute to the electrode’s measured AC impedance. This model can be used to analyse membrane-transport studies and other instances of ionic transport in semiconductors and other materials. Two efficient and easily accessible analytical techniques, AGM and DTM, were used to solve the steady-state non-linear diffusion equation’s infinite layers. Herein, we present the generalized approximate analytical solution for the solute, product, and reactant concentrations and current for the small experimental values of kinetic and diffusion parameters. Using the Matlab/Scilab program, we also derive the numerical solution to this problem. The comparison of the analytical and numerical/computational results reveals a satisfactory level of agreement. Full article
(This article belongs to the Special Issue Feature Papers in Electrochemistry)
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18 pages, 1471 KiB  
Article
Modelling of Biotrickling Filters for Treatment of NOx Analytical Expressions for the NOx Concentration in Both Gas and Biofilm Phases
by Ramasamy Umadevi, Ponraj Jeyabarathi, Kothandapani Venugopal, Michael E. G. Lyons and Lakshmanan Rajendran
Electrochem 2022, 3(3), 361-378; https://doi.org/10.3390/electrochem3030025 - 5 Jul 2022
Cited by 2 | Viewed by 2398
Abstract
A mathematical model of an ideal biotrickling filter (BF) system that inoculates a recently identified strain of Chelatococcus daeguensis TAD1 and brings about efficient nitrogen oxide treatment is discussed. The proposed model is based on nonlinear mass transport equations at the gas–biofilm interface. [...] Read more.
A mathematical model of an ideal biotrickling filter (BF) system that inoculates a recently identified strain of Chelatococcus daeguensis TAD1 and brings about efficient nitrogen oxide treatment is discussed. The proposed model is based on nonlinear mass transport equations at the gas–biofilm interface. Using Akbari–Ganji’s technique, approximate analytical expressions for the nitric oxide concentration in the gaseous and biofilm phases were developed for all feasible system parameters. In addition, to investigate the dynamic behaviour of the system, a numerical analysis of the problem is provided using MATLAB tools. To demonstrate this new approach, graphical data are provided and quantitatively discussed. This theoretical result has good agreement with the numerical simulation (MATLAB) results for the experimental values of parameters. Full article
(This article belongs to the Special Issue Feature Papers in Electrochemistry)
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17 pages, 1690 KiB  
Article
Akbari–Ganji Method for Solving Equations of Euler–Bernoulli Beam with Quintic Nonlinearity
by Iman Khatami, Mohsen Zahedi, Abolfazl Zahedi and Mohammad Yaghoub Abdollahzadeh Jamalabadi
Acoustics 2021, 3(2), 337-353; https://doi.org/10.3390/acoustics3020023 - 9 May 2021
Cited by 4 | Viewed by 5197
Abstract
In many real word applications, beam has nonlinear transversely vibrations. Solving nonlinear beam systems is complicated because of the high dependency of the system variables and boundary conditions. It is important to have an accurate parametric analysis for understanding the nonlinear vibration characteristics. [...] Read more.
In many real word applications, beam has nonlinear transversely vibrations. Solving nonlinear beam systems is complicated because of the high dependency of the system variables and boundary conditions. It is important to have an accurate parametric analysis for understanding the nonlinear vibration characteristics. This paper presents an approximate solution of a nonlinear transversely vibrating beam with odd and even nonlinear terms using the Akbari–Ganji Method (AGM). This method is an effective approach to solve nonlinear differential equations. AGM is already used in the heat transfer science for solving differential equations, and in this research for the first time, it is applied to find the approximate solution of a nonlinear transversely vibrating beam. The advantage of creating new boundary conditions in this method in additional to predefined boundary conditions is checked for the proposed nonlinear case. To illustrate the applicability and accuracy of the AGM, the governing equation of transversely vibrating nonlinear beams is treated with different initial conditions. Since simply supported and clamped-clamped structures can be encountered in many engineering applications, these two boundary conditions are considered. The periodic response curves and the natural frequency are obtained by AGM and contrasted with the energy balance method (EBM) and the numerical solution. The results show that the present method has excellent agreements in contrast with numerical and EBM calculations. In most cases, AGM is applied straightforwardly to obtain the nonlinear frequency– amplitude relationship for dynamic behaviour of vibrating beams. The natural frequencies tested for various values of amplitude are clearly stated the AGM is an applicable method for the proposed nonlinear system. It is demonstrated that this technique saves computational time without compromising the accuracy of the solution. This approach can be easily extended to other nonlinear systems and is therefore widely applicable in engineering and other sciences. Full article
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