Search Results (43)

The Changling Depression, located in the southern part of the central depression zone of the Songliao Basin, is characterized by complex structures and has been shaped by multiple phases of tectonic activity. The strata in this region have undergone significant uplift and denudation, resulting in an incomplete understanding of the prototype basin and hindering progress in oil and gas exploration. To better understand the geological characteristics and exploration potential of the Changling Depression, this study begins with the reconstruction of denudation amounts. Using the stratigraphic trend extrapolation method, the denudation of strata during the faulting period of the Changling Depression is quantified. By combining the denudation thickness with the remaining strata thickness, the original strata thickness is restored. Employing MOVE 2018version and Petrel 2021version software, the paleogeomorphology of different geological periods is reconstructed. Through an analysis of the prototype basin’s structure, its evolution history, sedimentary filling patterns, and paleogeomorphological features, it is determined that the maximum depositional thickness and rate during the Huoshiling period occurred in the Shenzijing, Heidimiao, and Fulongquan areas, with strong central deposition that weakened toward the north and south. During the Shahezi period, depositional thickness and rates exhibited a pattern of weaker deposition in the south and stronger in the north. In the Yingcheng Formation–Denglouku Formation period, the basin entered a subsidence phase, with an expanded range of strata subsidence. During the Denglouku period, the Qianbei area experienced strong deposition, while the Heidimiao area saw even more pronounced deposition; in contrast, the Shenzijing area displayed very weak depositional activity. The study reveals a south-to-north migration of lateral subsidence centers over time, influenced by left-lateral tectonic forces, reflecting a shift in the dominant influence pattern. These findings clarify the morphology of the prototype basin and the distribution and migration of subsidence centers across different periods, providing valuable insights that will facilitate deeper oil and gas exploration efforts in the Changling Depression. Full article

Sandstone bodies are distributed across a large area in the northeastern part of the Sulige gas field in the Ordos Basin. However, the production characteristics of gas wells in different areas are significantly different, and the success rate of drilling effective reservoirs is low. Therefore, studies on the patterns of natural gas enrichment are urgently needed. In this study, from the perspective of tectonic evolution, the mudstone sonic transit time method was used to calculate the denudation thickness of the study area in the Late Cretaceous; the denudation thickness was between 820 m and 1200 m, and the paleo-tectonic map of the top of He 8, which was the main layer at that time, was restored and analyzed in comparison with the present structure at the top of He 8, revealing that tectonic evolution has a controlling effect on the migration, accumulation and dispersion of natural gas after formation. During the critical period of hydrocarbon accumulation at the end of the Early Cretaceous, the short-axis nose uplift zone remaining in the central and western regions, and the long-axis nose uplift zone remaining in the central and eastern regions were favorable areas for natural gas migration and accumulation. The up-dip direction has lithological traps, and the gas reservoirs have survived to the present day. The short-axis nose uplift zone and anticline at the western margin disappeared through tectonic adjustment; thus, the paleo-gas reservoirs that formed there were destroyed, and the natural gas was adjusted to new traps. Full article

In the 20-year period from 2003 to 2022, water runoff and suspended sediment load in a forested gully system with a total length of 7.5 km was recorded. The branching gully system cuts through an agricultural catchment of 1.24 km² located within the loess plateau of the Nałęczów Plateau (E Poland). A rain gauge was installed close to the watershed and in the gully mouth water runoff was monitored using a limnigraph, installed with a water gauge on a Thomson triangular weir. To determine suspended sediment concentrations during erosion episodes, water was sampled at a frequency dependent on the rate and duration of the runoff. The aim of the monitoring studies was to specify the relationship between flow rate and suspended concentration for different water runoff conditions, which were used to calculate sediment load. The contribution of propluvial and pronivial runoff to gully development was assessed, particularly in the transport of sediment out of the catchment, and unit denudation rates were calculated as less than 1000 Mg km⁻² year⁻¹, average 173 Mg km⁻² year⁻¹, and during a single event as a maximal 900 Mg km⁻². Full article

During the Late Ordovician period, changes in climate and mass extinctions were observed; however, the factors influencing these phenomena have not been fully understood. In order to understand the relationships among redox water conditions, climates, and mass extinctions in the Late Ordovician, this study analyzes the chemical index of alteration (CIA) in shales and ⁸⁷Sr/⁸⁶Sr in carbonate leachates as proxies of changes in chemical weathering intensity and chemical weathering rate in the Late Ordovician (mainly from Katian to Hirnantian). The results show that an enhanced chemical weathering rate (increased ⁸⁷Sr/⁸⁶Sr ratios) and decreased chemical weathering intensity (decreased CIA values) characterized the late Katian, which might be attributed to the global orogenesis and enhanced precipitation/runoff under the warming climate (late-Boda warming). This enhanced chemical weathering rate contributed to the CO₂ drawdown in the P. pacificus biozone, corresponding to the initiation of cooling and further glaciation. Meanwhile, the enhanced weathering-induced high primary productivity could have contributed to the expansion of anoxic seawater in the Katian, which further caused the Katian extinction. The Hirnantian Glaciation was characterized by high ⁸⁷Sr/⁸⁶Sr ratios in carbonates and extremely low CIA values in shales, which were likely related to the exposure of continents during low sea level and the glacial grinding of unweathered rocks. This study shows that the highest denudation rate and lowest chemical weathering intensity in the Hirnantian stage might have resulted in enhanced CO₂ release and contributed to the end of glaciation. Full article

A number of regolith-hosted REE occurrences have recently been discovered in the Esperance region in southern Western Australia. This paper summarizes major characteristics of REE mineralization and discusses contributing factors and potential controls. The main aim is to explain why there is a lack of highly sought-after ion-adsorption-clay-type REE deposits across the region despite the presence of the regolith-hosted REE mineralization on a regional scale. Local mineralization mostly occurs as continuous flat-lying enrichment “blankets” within the residual regolith developed over Archaean–Proterozoic granite gneisses and granitoids with elevated REE content. The enriched horizon is commonly located in the lower saprolite and saprock and is accompanied by an overlying REE-depleted zone. This distribution pattern, together with the data on HREE fractionation and the presence of the supergene REE minerals, indicates chemogenic type enrichment formed by supergene REE mobilization into groundwater, downward transport, and accumulation in the lower part of the weathering profile. Residual REE accumulation processes due to bulk rock volume and mass reduction during weathering also contribute to mineralization. It is proposed that climate and groundwater chemistry are the critical regional controls on the distribution of REEs in the weathering profile and on their speciation in the enrichment zone. Cenozoic aridification of climate in southwest Australia heavily overprinted pre-existing REE distributions in the weathering profile. Acidic (pH < 4), highly saline groundwaters intensely leached away any relatively weakly bound, adsorbed or colloidal REE forms, moving them downward. Dissolved REEs precipitated as secondary phosphates in neutral to alkaline environment at lower Eh near the base of the weathering profile forming the supergene enrichment zone. Low denudation rates, characteristic of areas of low relief under the arid climate, are favourable for the preservation of the existing weathering profiles with REE mineralization. Full article

Chemical and physical denudation rates have been assessed in areas with different lithologies. Surprisingly, there are no studies that attempt to document these rates in the Poços de Caldas Alkaline Massif (PC), the largest alkaline magmatism in South America and an important Al supergene deposit in Brazil. Therefore, the chemical and physical denudation rates were assessed and explained in the PC. Surface water and rainwater samples were collected at the Amoras Stream basin, covering one complete hydrological cycle (2016). All samples were analyzed for dissolved cations, silica, anions, total dissolved solids (TDS), and total suspended solids (TSS). The results reflected the seasonal variation on discharge, water temperature, and electrical conductivity in the Amoras Stream, with most of the cations, anions, silica TDS, and TSS being carried in the wet season. Partial hydrolysis and silicate incongruent dissolution are the main water/rock interactions in the PC, with an atmospheric/soil CO₂ consumption rate of 1.6 × 10⁵ mol/km²/a. The annual fluxes of Cl⁻, PO₄³⁻, NO₃⁻, and Al³⁺ were significantly influenced from rainwater. Chemical and physical weathering rates were 4 ± 0.8 and 3.0 ± 0.6 m/Ma in the PC, respectively, indicating that under the current climatic condition, the weathering profile is in dynamic equilibrium. Full article

One of the main factors that influences the fertility of cattle in grazing systems in hot tropical climates is heat stress. The objective of this study was to evaluate the effect of season, breed, hormonal and physiological condition on the quantity and quality of cumulus–oocyte complexes (COCs) and embryos produced in vitro, from Romosinuano (RM) and Tropical Milking (TM) donors. Three ovum pick-up and in vitro fertilization (OPU-IVF) were performed, one per season: hot dry (HD; 10, 10), hot humid (HH; 9, 9) and fresh dry (FD; 7, 10) in RM and LT donors. Serum levels of cortisol, insulin and glucose were measured, in addition to heart rate (HR), respiratory rate (RR) and rectal temperature (RT). Effect of season x genotype interaction (p ≤ 0.05) was observed in all COC variables and only in cleavage embryos (CLI) (p ≤ 0.05). Body weight (BW) affected all COC variables (p ≤ 0.01), except unviable (UNV) although affected degenerated embryos (DEG) (p ≤ 0.01) and total blastocysts (BLAST) (p ≤ 0.01). Cow age only affected viable COCs (VIAB) (p ≤ 0.05), code one blastocysts (BC1) and BLAST (p ≤ 0.01). Cortisol affected total COCs (COCsT), VIAB and total matured in vitro (TMIV) (p ≤ 0.01), as well as CLI, BC1 (p ≤ 0.01) and BLAST (p ≤ 0.05). Insulin affected COCsT (p ≤ 0.01), UNV (p ≤ 0.05), denuded oocytes (DE) (p ≤ 0.01), BC1 and code two blastocysts (BC2) (p ≤ 0.01). Glucose affected all COC variables (p ≤ 0.01), except UNV and all embryo variables except BC2. HR affected COCsT, DE, TMIV (p ≤ 0.01), CLI, BLAST and DEG (p ≤ 0.05). RR affected COCsT, UNV, VIAB, CLI (p ≤ 0.05), BC1, BLAST and DEG (p ≤ 0.01). RT only affected DE, VIAB (p ≤ 0.01) and BLAST (p ≤ 0.05). The seasonal climatic year variation of Veracruz and changes in physiological and hormonal variables have diverse effects on the cumulus–oocyte complexes and embryos produced by RM and TM donors. Full article

Antioxidants protect cellular function and structure by neutralizing the oxidative stress caused by increased reactive oxygen species (ROS) during sperm freezing. Studies on cryopreservation using various antioxidants have demonstrated encouraging results. Many studies have used antioxidants to increase the efficiency of sperm freezing and to improve the success rate of artificial insemination and pregnancy. Manganese (III) tetrakis (4-benzoic acid) porphyrin chloride (MnTBAP) is a newly synthesized antioxidant with positive effects on sperm morphology and capacitation in humans, rams, and stallions. In this study, porcine semen was treated with 0, 50, 100, and 150 μM of MnTBAP based on a Tris–egg-yolk extender and frozen to determine whether MnTBAP can assist the status of sperm during cryopreservation. First, motility was assessed using the computer-assisted sperm analysis (CASA) system, with the 100 μM treatment group showing the highest motile rate (66.8%) compared with that of the other groups (control, 51.1%; 50 μM and 150 μM, 59.6%); therefore, the remaining analyses were conducted comparing the two groups (control vs. 100 μM group; p < 0.01). Second, fluorescence staining was applied to examine the control and 100 μM groups using fluorescence microscopy. The viability (41.7% vs. 62.4%) and the acrosome integrity (77.9% vs. 86.4%) differed significantly (p < 0.05). In addition, the mitochondrial membrane potential (MMP) was 46.5% vs. 51.9%; the fragmentation rate, estimated using the Sperm-sus-Halomax kit, was 63.4% vs. 57.4%; and the detected caspase activity was 30.1% vs. 22.9%. These tended to be higher in the treated group but did not differ significantly. Third, measurements using FACSLyric revealed that the 100 μM treatment group exhibited a state of elevated normal lipid arrangement within the plasma membrane and diminished levels of apoptosis and ROS (p < 0.01). We assessed the expression of genes relevant to antioxidant effectiveness using real-time RT-qPCR. Our findings indicated significant alterations in the expression levels of various mRNA species, with the exception of NOX5 (p < 0.05). Finally, the straws were dissolved and used to treat matured denuded oocytes to investigate the effect on fertilization and embryo development in vitro. The cleavage rate was (77.6% vs. 84.1%), and the blastocyst rate was 9.7% vs. 11.4% (p < 0.05). In conclusion, these results suggest that MnTBAP positively affected sperm freeze–thawing, improving the fertilization capacity, and leading to increased embryo development. Full article

Soil erosion is a challenge worldwide, including in China. The dendrogeomorphic method was applied, for the first time, at Xiaolong Mts in Gansu Province to obtain a quantitative estimate of the soil erosion rate. The dataset built in this pilot study allowed the identification of exhumation texture in exposed roots between 1967 and 2002. The calculated mean erosion rate estimates (Er_a) ranged from 2.6 to 16.5 mm yr⁻¹ and showed an increase with the slope steepness (s). The best fitting linear model (Er_a = 0.043(±0.017) × s + 3.09(±1.04); R² = 0.20; R²_adj = 0.16; F = 6.18; p = 0.02) could be used in future research to determine and to map soil denudation in this part of the Xiaolong Mts. Notable associations were found between erosive rainfalls and root exhumation events. Daily (Rx1day) and 5-day (Rx5day) precipitation totals of 56 and 73 mm, respectively, seem to be critical thresholds which if exceeded will always induce root exhumation in the same year or in the consecutive season in the forest of the Xiaolong Mts in the studied period. Full article

Long-term series of annual and seasonal water flow and major ions in the Pechora River were analyzed. Long-term phases of increased and decreased water flow were identified, ranging in duration from 11 to 49 years, and the major characteristics of these phases were determined. Changes in the sequence and boundaries of contrast phases in the annual and snowmelt spring–summer flood runoff were found to coincide. The difference between the mean seasonal water runoff during the phases of increased and decreased flow varied from 12 to 41%. The ion flow values of contrast phases typically differed by 9 to 36%, which is less than for water flow. This is due to the inverse dependence between ion concentrations and water discharge. Such peculiar negative feedback stabilizes the rates of chemical denudation in the river catchments to some extent and, thus, the discharge of major ions into seas, even during significant variations in water. Full article

A reconstruction of the tectonothermal evolution of the Laojunshan–Song Chai granite gneiss massif (North Vietnam, South China) was carried out, based on summaries of the latest isotopic and fission-track dating results. The recorded wide range (420–465 Ma) of the age of granite gneiss rocks testifies to the long-term existence of a partially molten layer at a depth of 20–30 km for several tens of Ma. By the Devonian–early Carboniferous, a section of the excessively thickened crust was denudated, the massif was exhumated to the level of the upper crust, and isotope systems were “frozen”. The rate of uplift of the rocks of the massif is estimated to be about 0.2–0.5 mm/year. In the further history of the granite gneiss massif, episodes of repeated burial to a depth of about 13 km are recorded, associated with the Indosinian collision. The rocks have experienced metamorphism of the amphibolite-green schist facies, accompanied by tectonic transport in the form of a thrust sheet. Over the next 200 Ma, the uplift of the massif and the erosion of the overlying strata occurred in discrete pulses, during a sequence of active tectonic events. Thus, the thermochronological and P-T history of the Laojunshan–Song Chai massif is a kind of chronicle of regional tectonic–thermal events. In the history of the massif, traces of two orogenic cycles associated with the collision of the Cathaysia and Yangtze blocks in the Lower Paleozoic and the Indosinian collision in the Triassic are recorded. Full article

The eastern Qaidam Basin (EQB), along with its surrounding orogenic belts, witnessed complicated tectonic movements in the period from the late Paleozoic to the early Mesozoic. As strategic succeeding strata, the Carboniferous strata (CST) in the EQB have gradually become a research hotspot in recent years. However, the question of how tectonism controlled the tempo-spatial evolution of the CST has yet to be studied. To resolve these issues, we collated statistics related to unconformities, seismic interpretation, and basin modeling in this study. The results show that the structure of the CST was mostly controlled by NNE-striking faults, namely the Zongjia and Ainan Fault, in the period from the Carboniferous to the Triassic time. During the Carboniferous time, the sedimentation of the CST was controlled by medium-high angle potential normal faults. The CST experienced two stages of tectonic subsidence and subsequent burial: the highest average subsidence and burial rate of 45 m/Ma and 12 m/Ma occurred at 340~285 Ma, decreasing to 15 m/Ma and 7.5 m/Ma between 305 Ma and 250 Ma. However, the maximum burial (~5500 m) took place at ~250 Ma. From the end of the late Permian to the late Triassic (254~195 Ma), the overall exhumation rate of the CST has averaged 38.71 m/Ma, and 75 m/Ma in the southern margin of the Huobuxun Depression. The CST near the piedmont margins of the EQB suffered essential denudation at 254~195 Ma, resulting in small amounts of the residual CST. In these areas, the CST were deformed with a steepening dip during this time and were characterized by the combinations of syncline-anticlinal asymmetric folds with the high-angle interlimb. These findings indicated that the tempo-spatial evolution of the CST was possibly influenced by the sedimentary and tectonic transition, and was a combined response to Paleo-Tethys Ocean subduction, and arc-continental collisions since the late Paleozoic to early Mesozoic periods. Full article

Hypersonic vehicles encounter hostile service environments of thermal/mechanical/chemical coupling, so thermal protection materials are crucial and essential. Ceramizable composites have recently attracted intensive interest due to their ability to provide large-area thermal protection for hypersonic vehicles. In this work, a novel ceramizable composite of quartz fiber/benzoxazine resin modified with fused SiO₂ and h-BN was fabricated using a prepreg compression molding technique. The effects of the fused SiO₂ and h-BN contents on the thermal, mechanical, and ablative properties of the ceramizable composite were systematically investigated. The ceramizable composite with an optimized amount of fused SiO₂ and h-BN exhibited superb thermal stability, with a peak degradation temperature and residue yield at 1400 °C of 533.2 °C and 71.5%, respectively. Moreover, the modified ceramizable composite exhibited excellent load-bearing capacity with a flexural strength of 402.2 MPa and superior ablation resistance with a linear ablation rate of 0.0147 mm/s at a heat flux of 4.2 MW/m², which was significantly better than the pristine quartz fiber/benzoxazine resin composite. In addition, possible ablation mechanisms were revealed based on the microstructure analysis, phase transformation, chemical bonding states, and the degree of graphitization of the ceramized products. The readily oxidized pyrolytic carbon (PyC) and the SiO₂ with a relatively low melting point were converted in situ into refractory carbide. Thus, a robust thermal protective barrier with SiC as the skeleton and borosilicate glass as the matrix protected the composite from severe thermochemical erosion and thermomechanical denudation. Full article

This study was part of a project designed to simulate the long-term landform equilibrium of a rehabilitated mine site. The project utilized event Fine Suspended Sediment (FSS) fluxes in a receiving stream following a rainfall event as an indicator of landform stability. The aim of this study was to use HEC-HMS to determine sediment and discharge quantity upstream to determine how it affects the downstream development of the catchment landform, in terms of sediment changes and geomorphology. Thus, the study focused on hydrology and sediment modelling of the upper catchment with HEC-HMS (Hydrologic Engineering Centre-Hydrologic Modelling System) to determine the daily discharge and sediment output at the catchment outlet. HEC-HMS was used to calibrate the stream discharge and FSS quantities at the catchment outlet to observed continuous discharge and FSS values. The calibration of the HEC-HMS model was carried out for two water years and then the same model parameters were used to validate the model for a third water year. The catchment discharge and FSS were calibrated and validated for continuous rainfall events against observed discharge and FSS data at the catchment outlet. The model was then run for a projected rainfall of 50 years. The denudation rate predicted by the model was 0.0245 mm per year, which falls in the range previously determined for the region. The simulated sediment output was compared to the rainfall trends over the years. As a result, the sediment spikes following a rainfall-runoff event gradually decreased over time. Reducing FSS spikes indicates that the landform gradually attains stability. This modelling study can be used for long-term simulations to determine erosion equilibrium over the years and to quantify sediment yield in catchments for projected time periods. Full article

High-quality eggs are essential for the sustainability of commercial aquaculture production. Melatonin is a potent candidate for regulating the growth and maturation of oocytes. Therefore, research on the effect of melatonin on marine fish oocytes in vitro has been conducted. The present study successfully established a culture system of turbot (Scophthalmus maximus) oocytes in vitro and investigated the effect of melatonin on oocyte meiotic maturation, antioxidant capacity, and the expression of apoptosis-related genes. The cultures showed that turbot Scophthalmus maximus late-vitellogenic denuded oocytes, with diameters of 0.5–0.7 mm, had a low spontaneous maturation rate and exhibited a sensitive response to 17α, 20β-dihydroxyprogesterone (DHP) treatment in vitro. Melatonin increased by four times the rate of oocyte germinal vesicle breakdown (GVBD) in a concentration- and time-dependent manner. The mRNA of melatonin receptor 1 (mtnr1) was significantly upregulated in the oocyte and follicle after treatment with melatonin (4.3 × 10⁻⁹ M) for 24 h in vitro, whereas melatonin receptor 2 (mtnr2) and melatonin receptor 3 (mtnr3) remained unchanged. In addition, melatonin significantly increased the activities of catalase, glutathione peroxidase, and superoxide dismutase, as well as the levels of glutathione, while decreasing the levels of malondialdehyde and reactive oxygen species (ROS) levels in turbot oocytes and follicles cultures in vitro. p53, caspase3, and bax mRNAs were significantly downregulated in oocytes and follicles, whereas bcl2 mRNAs were significantly upregulated. In conclusion, the use of turbot late-vitellogenesis oocytes (0.5–0.7 mm) is suitable for establishing a culture system in vitro. Melatonin promotes oocyte meiotic maturation and antioxidative capacity and inhibits apoptosis via the p53-bax-bcl2 and caspase-dependent pathways, which have important potential to improve the maturation and quality of oocytes. Full article