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Keywords = 1,3-bis(4-Acetylphenoxy)propan-2-ylidenepropane

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8 pages, 237 KB  
Article
Synthesis and Characterization of Some New Tetraaldehyde and Tetraketone Derivatives and X-ray Structure of 1,1'-(4,4'-(2- (1,3-bis(4-Acetylphenoxy)propan-2-ylidene)propane-1,3-diyl) bis(oxy)bis(4,1-phenylene))diethanone
by Mustafa Er, Reşat Ustabaş, Ufuk Çoruh, Kemal Sancak and Ezequiel Vázquez-López
Int. J. Mol. Sci. 2008, 9(6), 1000-1007; https://doi.org/10.3390/ijms9061000 - 13 Jun 2008
Cited by 26 | Viewed by 14253
Abstract
Tetraketone and tetraaldehyde derivatives 2a-d were synthesized via the reaction of ethene-1,1,2,2,-tetra-yl-tetramethylene tetrabromide (1) with hydroxyketone and aldehyde derivatives. The molecular structures were identifed by IR, 1H-NMR, 13CNMR and MS analysis. The crystal structure of the title compound 2a, C38 [...] Read more.
Tetraketone and tetraaldehyde derivatives 2a-d were synthesized via the reaction of ethene-1,1,2,2,-tetra-yl-tetramethylene tetrabromide (1) with hydroxyketone and aldehyde derivatives. The molecular structures were identifed by IR, 1H-NMR, 13CNMR and MS analysis. The crystal structure of the title compound 2a, C38H36O8, is reported. Its crystal data are: monoclinic, space group P 2(1)/n with cell dimensions of a= 9.0395(12) Å ,b= 12.6114(17) Å, c = 13.8166(18) Å, β= 95.875(3), V= 1566.8(4) Å3, F.W.= 620.67, ρcalc =1.316 gcm3 for Z=2, μ=0.092 mm-1 Full article
(This article belongs to the Section Physical Chemistry, Theoretical and Computational Chemistry)
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