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Authors = Vlatko Knežević

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16 pages, 1299 KiB  
Article
Detection of Leachable Components from Conventional and Dental Bulk-Fill Resin Composites (High and Low Viscosity) Using Liquid Chromatography-Tandem Mass Spectrometry (LC-MS/MS) Method
by Matea Lapaš Barišić, Hrvoje Sarajlija, Eva Klarić, Alena Knežević, Ivan Sabol and Vlatko Pandurić
Polymers 2023, 15(3), 627; https://doi.org/10.3390/polym15030627 - 25 Jan 2023
Cited by 9 | Viewed by 2782
Abstract
The aim of this study was to investigate leachable components (monomers) in high and low viscosity dental bulk-fill resin composites and conventional resin composite materials after polymerization. Six bulk-fill and six conventional dental resin composite materials were used in this study. The samples [...] Read more.
The aim of this study was to investigate leachable components (monomers) in high and low viscosity dental bulk-fill resin composites and conventional resin composite materials after polymerization. Six bulk-fill and six conventional dental resin composite materials were used in this study. The samples of each material (three sets of triplicates) were cured for 20 s with irradiance of 1200 mW/cm2 with a LED curing unit and immersed in a 75% ethanol solution at 37 °C. The eluates from each triplicate set were analyzed after 24 h, 7 days or 28 days using liquid chromatography coupled with triple quadrupole tandem mass spectrometry (LC-MS/MS). Detectable amounts of 2-Hydroxyethyl methacrylate (HEMA) were found in both Gradia materials and the amount observed across different time points was statistically different (p ˂ 0.05), with the amount in solution increasing for Gradia and decreasing for Gradia Direct flo. Bisphenol A diglycidildimethacrylate (BIS GMA) was found in Filtek and Tetric materials. Triethylene glycol dimethacrylate (TEGDMA) was detected in all materials. On the other hand, there were no statistically significant differences in the amounts of TEGDMA detected across different time points in either of the tested materials. Monomers HEMA, TEGDMA, 4-dimethylaminobenzoic acid ethyl ester (DMA BEE) and BIS GMA in bulk-fill and conventional composites (high and low viscosity) can be eluted after polymerization. The good selection of composite material and proper handling, the following of the manufacturer’s instructions for polymerization and the use of finishing and polishing procedures may reduce the elution of the unpolymerized monomers> responsible for the possible allergic and genotoxic potential of dental resin composites. Full article
(This article belongs to the Special Issue Progress in Polymer Composites for Different Applications)
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19 pages, 5209 KiB  
Article
Comparison of the on Board Measured and Simulated Exhaust Gas Emissions on the Ro-Pax Vessels
by Josip Orović, Marko Valčić, Vlatko Knežević and Zoran Pavin
Atmosphere 2022, 13(5), 794; https://doi.org/10.3390/atmos13050794 - 13 May 2022
Cited by 3 | Viewed by 2700
Abstract
Increasingly stringent environmental requirements for marine engines imposed by the International Maritime Organisation and the European Union require that marine engines have the lowest possible emissions of greenhouse and harmful exhaust gases into the atmosphere. In this research, exhaust gas emissions were measured [...] Read more.
Increasingly stringent environmental requirements for marine engines imposed by the International Maritime Organisation and the European Union require that marine engines have the lowest possible emissions of greenhouse and harmful exhaust gases into the atmosphere. In this research, exhaust gas emissions were measured on three Ro-Pax vessels sailing in the Adriatic Sea. Testo 350 Maritime exhaust gas analyser was used for monitoring the dry exhaust gas concentrations of CO2 and O2 in percentage, concentrations of CO and NOx in ppm and exhaust gas temperature in °C after the turbocharger at different engine loads. In order to compare and validate measured values, exhaust gas measurement data were also obtained from a Wartsila-Transas simulator model of a similar Ro-Pax vessel during the joint operation of the engine room and navigational simulators. All analysed main engines on three vessels had complete combustion processes in the cylinders with small differences which should be further investigated. Comparison of on board measured parameters with simulated parameters showed that significant fuel oil reduction per voyage could be accomplished by voyage and/or engine operation optimization procedures. Results of this analysis could be used for creating additional emission database and data-driven models for further analysis and improved estimation of exhaust gasses under various marine engine conditions. Additionally, the results could be useful to all interested parties in reducing the fuel oil consumption and emissions of greenhouse and harmful exhaust gases from vessels into the atmosphere. Full article
(This article belongs to the Special Issue Ocean Environment Modelling and Air Emissions from Shipping)
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19 pages, 2442 KiB  
Article
Fault Tree Analysis and Failure Diagnosis of Marine Diesel Engine Turbocharger System
by Vlatko Knežević, Josip Orović, Ladislav Stazić and Jelena Čulin
J. Mar. Sci. Eng. 2020, 8(12), 1004; https://doi.org/10.3390/jmse8121004 - 9 Dec 2020
Cited by 41 | Viewed by 11979
Abstract
The reliability of marine propulsion systems depends on the reliability of several sub-systems of a diesel engine. The scavenge air system is one of the crucial sub-systems of the marine engine with a turbocharger as an essential component. In this paper, the failures [...] Read more.
The reliability of marine propulsion systems depends on the reliability of several sub-systems of a diesel engine. The scavenge air system is one of the crucial sub-systems of the marine engine with a turbocharger as an essential component. In this paper, the failures of a turbocharger are analyzed through the fault tree analysis (FTA) method to estimate the reliability of the system and to predict the cause of failures. The quantitative method is used for assessing the probability of faults occurring in the turbocharger system. The main failures of a scavenge air sub-system, such as air filter blockage, compressor fouling, turbine fouling (exhaust side), cooler tube blockage and cooler air side blockage, are simulated on a Wärtsilä-Transas engine simulator for a marine two-stroke diesel engine. The results obtained through the simulation can provide improvement in the maintenance plan, reliability of the propulsion system and optimization of turbocharger operation during exploitation time. Full article
(This article belongs to the Special Issue Marine Power Systems)
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