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Authors = Venkatraju Jella ORCID = 0000-0003-0269-9188

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13 pages, 2153 KiB  
Article
Dielectric Tailoring of Perovskite-Polymer Composites for High-Performance Triboelectric Nanogenerators
by Venkatraju Jella, Swathi Ippili and Soon-Gil Yoon
Polymers 2025, 17(7), 969; https://doi.org/10.3390/polym17070969 - 2 Apr 2025
Viewed by 594
Abstract
The rapid advancement of wearable electronics and the Internet of Things (IoT) has driven the demand for sustainable power sources to replace conventional batteries. In this study, we developed a high-performance, lead-free triboelectric nanogenerator (TENG) using methylammonium tin chloride (MASnCl3) perovskite–poly(methyl [...] Read more.
The rapid advancement of wearable electronics and the Internet of Things (IoT) has driven the demand for sustainable power sources to replace conventional batteries. In this study, we developed a high-performance, lead-free triboelectric nanogenerator (TENG) using methylammonium tin chloride (MASnCl3) perovskite–poly(methyl methacrylate) (PMMA) composite films. MASnCl3 was synthesized via an anti-solvent-assisted collision technique and incorporated into a flexible PMMA matrix to enhance dielectric properties, thereby improving triboelectric output. The optimized 10 wt% MASnCl3–PMMA composite-based TENG exhibited a maximum output voltage of 525 V, a current of 13.6 µA, and of power of 2.5 mW, significantly outperforming the many halide perovskite-based TENGs. The device demonstrated excellent pressure sensitivity, achieving 7.72 V/kPa in voltage detection mode and 0.2 μA/kPa in current detection mode. The device demonstrated excellent mechanical stability and was successfully used to power a small electronic device. The findings highlight the potential of halide perovskite–polymer composites in developing eco-friendly, efficient mechanical energy harvesters for next-generation self-powered electronics and sensor applications. Full article
(This article belongs to the Special Issue Advances in Polymer Composites for Nanogenerator Applications)
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25 pages, 17145 KiB  
Review
An Overview of Polymer Composite Films for Antibacterial Display Coatings and Sensor Applications
by Swathi Ippili, Jang-Su Jung, Alphi Maria Thomas, Van-Hoang Vuong, Jeong-Min Lee, Mizaj Shabil Sha, Kishor Kumar Sadasivuni, Venkatraju Jella and Soon-Gil Yoon
Polymers 2023, 15(18), 3791; https://doi.org/10.3390/polym15183791 - 17 Sep 2023
Cited by 9 | Viewed by 3421
Abstract
The escalating presence of pathogenic microbes has spurred a heightened interest in antimicrobial polymer composites tailored for hygiene applications. These innovative composites ingeniously incorporate potent antimicrobial agents such as metals, metal oxides, and carbon derivatives. This integration equips them with the unique ability [...] Read more.
The escalating presence of pathogenic microbes has spurred a heightened interest in antimicrobial polymer composites tailored for hygiene applications. These innovative composites ingeniously incorporate potent antimicrobial agents such as metals, metal oxides, and carbon derivatives. This integration equips them with the unique ability to offer robust and persistent protection against a diverse array of pathogens. By effectively countering the challenges posed by microbial contamination, these pioneering composites hold the potential to create safer environments and contribute to the advancement of public health on a substantial scale. This review discusses the recent progress of antibacterial polymer composite films with the inclusion of metals, metal oxides, and carbon derivatives, highlighting their antimicrobial activity against various pathogenic microorganisms. Furthermore, the review summarizes the recent developments in antibacterial polymer composites for display coatings, sensors, and multifunctional applications. Through a comprehensive examination of various research studies, this review aims to provide valuable insights into the design, performance, and real-time applications of these smart antimicrobial coatings for interactive devices, thus enhancing their overall user experience and safety. It concludes with an outlook on the future perspectives and challenges of antimicrobial polymer composites and their potential applications across diverse fields. Full article
(This article belongs to the Special Issue Polymer Composites with Antibacterial Properties)
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29 pages, 5468 KiB  
Review
The Recent Progress on Halide Perovskite-Based Self-Powered Sensors Enabled by Piezoelectric and Triboelectric Effects
by Swathi Ippili, Venkatraju Jella, Alphi Maria Thomas and Soon-Gil Yoon
Nanoenergy Adv. 2021, 1(1), 3-31; https://doi.org/10.3390/nanoenergyadv1010002 - 23 Jul 2021
Cited by 45 | Viewed by 8170
Abstract
Sensors have recently gathered significant attention owing to the rapid growth of the Internet of Things (IoT) technology for the real-time monitoring of surroundings and human activities. Particularly, recently discovered nanogenerator-based self-powered sensors are potential candidates to overcome the existing problems of the [...] Read more.
Sensors have recently gathered significant attention owing to the rapid growth of the Internet of Things (IoT) technology for the real-time monitoring of surroundings and human activities. Particularly, recently discovered nanogenerator-based self-powered sensors are potential candidates to overcome the existing problems of the conventional sensors, including regular monitoring, lifetime of a power unit, and portability. Halide perovskites (HPs), with an excellent photoactive nature, dielectric, piezoelectric, ferroelectric, and pyroelectric properties, have been potential candidates for obtaining flexible and self-powered sensors including light, pressure, and temperature. Additionally, the photo-stimulated dielectric, piezoelectric, and triboelectric properties of HPs make them efficient entrants for developing bimodal and multimode sensors to sense multi-physical signals individually or simultaneously. Therefore, we provide an update on the recent progress in self-powered sensors based on pyroelectric, piezoelectric, and triboelectric effects of HP materials. First, the detailed working mechanism of HP-based piezoelectric, triboelectric, and pyroelectric nanogenerators—operated as self-powered sensors—is presented. Additionally, the effect of light on piezoelectric and triboelectric effects of HPs, which is indispensable in multimode sensor application, is also systematically discussed. Furthermore, the recent advances in nanogenerator-based self-powered bimodal sensors comprising HPs as light-active materials are summarized. Finally, the perspectives and continuing challenges of HP-based self-powered sensors are presented with some opportunities for future development in self-powered multimode sensors. Full article
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