Energy Relaxation of Porphycene in Atomic and Molecular Cryogenic Matrices
Abstract
:1. Introduction
2. Materials and Methods
3. Results and Discussion
3.1. Time-Resolved Fluorescence
3.2. Transient Absorption
4. Summary
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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<Spectral Region>\cm−1 | τ\ps | Amplitude | τ\ps | Amplitude |
---|---|---|---|---|
P0 15,486–16,029 | 58 ± 2 (R) | 8123 ± 80 | 5 ± 3 (R) | 1660 ± 150 |
P1 15,834–16,029 | 63 ± 3 (R) | 6500 ± 120 | - | - |
P2 15,700–15,834 | 18 ± 1 (R) | 2680 ± 90 | 300 ± 31 (D) | 2540 ± 100 |
P3 15,486–15,700 | 6 ± 0.5 (R) | 2474 ± 94 | 400 ± 45 (D) | 2187 ± 47 |
<Spectral Region>\cm−1 | τ\ps | Amplitude | τ\ps | Amplitude |
---|---|---|---|---|
P0 15,432–15,952 | 12 ± 0.4 (R) | 10,430 ± 152 | 1653 ± 321 (D) | 10,980 ± 132 |
P1 15,760–15,952 | 28 ± 2 (R) | 8854 ± 585 | 380 ± 75 (D) | 9072 ± 611 |
P2 15,606–15,760 | 8 ± 0.4 (R) | 5200 ± 100 | 24 ± 1 (D) | 2761 ± 30 |
P3 15,432–15,606 | 5 ± 1 (R) | 2560 ± 600 | 20 ± 7 (D) | 1213 ± 640 |
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Dobkowski, J.; Sazanovich, I.V.; Gorski, A.; Waluk, J. Energy Relaxation of Porphycene in Atomic and Molecular Cryogenic Matrices. Photochem 2022, 2, 299-307. https://doi.org/10.3390/photochem2020021
Dobkowski J, Sazanovich IV, Gorski A, Waluk J. Energy Relaxation of Porphycene in Atomic and Molecular Cryogenic Matrices. Photochem. 2022; 2(2):299-307. https://doi.org/10.3390/photochem2020021
Chicago/Turabian StyleDobkowski, Jacek, Igor V. Sazanovich, Aleksander Gorski, and Jacek Waluk. 2022. "Energy Relaxation of Porphycene in Atomic and Molecular Cryogenic Matrices" Photochem 2, no. 2: 299-307. https://doi.org/10.3390/photochem2020021