The Surprising Role of Endogenous Calcium Carbonate in Crab Shell-Mediated Biosorption of Pb (II)
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Methods
3. Results and Discussion
3.1. Scanning Electron Microscopy (SEM)
3.2. Batch Experiments
3.2.1. High Lead Concentration (100 mg/L)
3.2.2. Low Lead Concentration (10 mg/L)
3.3. Energy-Dispersive X-ray Spectroscopy (EDS)
3.4. Adsorption Isotherms
3.5. Kinetic Studies
3.6. BET Surface Area
3.7. Additional Extraction Studies
4. Conclusions
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Regression Parameter | Langmuir Isotherm | Freundlich Isotherm |
---|---|---|
0.32 | N/A | |
(mg/g) | 384.60 | N/A |
0.01 | N/A | |
N/A | 0.89 | |
N/A | 7.76 | |
N/A | 1.56 |
Pseudo-First-Order Fit | Pseudo-Second-Order Fit | |||
---|---|---|---|---|
Slope | R2 | qe | k2 | R2 |
−0.0008 | 0.9429 | 77.69 | 0.001 | 0.9936 |
Material Characteristics | Surface Area (m2/g) |
---|---|
Crab Shell 40 mesh | 28.7 |
Crab Shell No Protein (No Protein) | 49.1 |
Crab Shell No Mineral (No CaCO3) | 2.2 |
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Londoño-Zuluaga, C.; Jameel, H.; Gonzalez, R.W.; Yang, G.; Lucia, L. The Surprising Role of Endogenous Calcium Carbonate in Crab Shell-Mediated Biosorption of Pb (II). Physchem 2024, 4, 167-180. https://doi.org/10.3390/physchem4020013
Londoño-Zuluaga C, Jameel H, Gonzalez RW, Yang G, Lucia L. The Surprising Role of Endogenous Calcium Carbonate in Crab Shell-Mediated Biosorption of Pb (II). Physchem. 2024; 4(2):167-180. https://doi.org/10.3390/physchem4020013
Chicago/Turabian StyleLondoño-Zuluaga, Carolina, Hasan Jameel, Ronalds W. Gonzalez, Guihua Yang, and Lucian Lucia. 2024. "The Surprising Role of Endogenous Calcium Carbonate in Crab Shell-Mediated Biosorption of Pb (II)" Physchem 4, no. 2: 167-180. https://doi.org/10.3390/physchem4020013