Mechanochemical Synthesis and Hydrogen Sorption Properties of a V-Ni Alloy
Abstract
:1. Introduction
2. Materials and Methods
3. Results and Discussion
3.1. Stoichiometric and Structural Analysis
3.2. Hydrogen Absorption/Desorption
4. Conclusions
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Element | Pristine | After H2 Exchange 2 |
---|---|---|
V | 88 ± 5 | 87 ± 6 |
Ni | 12 ± 5 | 13 ± 6 |
V/Ni ratio | 7.0 | 6.6 |
Pristine | After H2 Exchange | |
---|---|---|
a/Å | 2.99 ± 0.01 | 3.05 ± 0.01 |
Size/nm | 3.3 ± 0.1 | 4.9 ± 0.1 |
wRp | 8.6% | 8.3% |
Gof | 1.4 | 1.5 |
H/M | ΔHhyd (kJ/mol) | ΔShyd (J/mol K−1) |
---|---|---|
0.03 | 90 ± 10 | 160 ± 30 |
0.06 | 63 ± 1 | 117 ± 3 |
0.10 | 52 ± 3 | 105 ± 7 |
0.20 | 33 ± 4 | 87 ± 9 |
0.25 | 34 ± 7 | 100 ± 20 |
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Palumbo, O.; Carboni, N.; Trequattrini, F.; Brutti, S.; Paolone, A. Mechanochemical Synthesis and Hydrogen Sorption Properties of a V-Ni Alloy. Hydrogen 2022, 3, 112-122. https://doi.org/10.3390/hydrogen3010009
Palumbo O, Carboni N, Trequattrini F, Brutti S, Paolone A. Mechanochemical Synthesis and Hydrogen Sorption Properties of a V-Ni Alloy. Hydrogen. 2022; 3(1):112-122. https://doi.org/10.3390/hydrogen3010009
Chicago/Turabian StylePalumbo, Oriele, Nicholas Carboni, Francesco Trequattrini, Sergio Brutti, and Annalisa Paolone. 2022. "Mechanochemical Synthesis and Hydrogen Sorption Properties of a V-Ni Alloy" Hydrogen 3, no. 1: 112-122. https://doi.org/10.3390/hydrogen3010009