Fabrication of Efficient and Selective Modified Graphene Paste Sensor for the Determination of Catechol and Hydroquinone
Abstract
:1. Introduction
2. Materials and Methods
2.1. Chemicals
2.2. Apparatus
2.3. Electrode Preparation
3. Results and Discussion
3.1. FE-SEM Inspection
3.2. Electro-Polymerization of RA at BGPE through Pre-Treatment Process
3.3. Impact of Sustaining Electrolyte pH
3.4. CV Response of CC at Poly(RA)MGPE and Surface Area
3.5. Scan Rate Impact on Electrode Reaction, Peak Current, and Peak Potential of CC
3.6. Limit of Detection and Quantification
3.7. Oxidative Response of CC at Poly (RA)MGPE and BGPE via DPV
3.8. Selective DPV Analysis of CC with HQ at Poly(RA)MGPE
3.9. Reproducibility, Repeatability, and Stability
3.10. CC Analysis in Water Samples
4. Conclusions
Funding
Conflicts of Interest
References
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Method | Sensor | LOD, µM | Reference |
---|---|---|---|
DPV | Poly(calmagite) MCPE | 2.550 | [52] |
DPV | Zn/Al layered double hydroxide film MGCE | 1.200 | [53] |
DPV | Graphene oxide and multiwall carbon nanotubes | 1.800 | [54] |
DPV | Silsesquioxane-modified carbon paste electrode | 10.000 | [55] |
DPV | Influence of micelles/GCE | 3.000 | [56] |
DPV | Poly(RA)MGPE | 0.820 | Present work |
Environmental Sample | Added Concentration (µM) | Found Concentration (µM) | Recovery (%) |
---|---|---|---|
Water | 0.120 | 0.117 | 97.50 |
0.160 | 0.155 | 96.87 | |
0.200 | 0.196 | 98.00 |
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Manjunatha, J.G. Fabrication of Efficient and Selective Modified Graphene Paste Sensor for the Determination of Catechol and Hydroquinone. Surfaces 2020, 3, 473-483. https://doi.org/10.3390/surfaces3030034
Manjunatha JG. Fabrication of Efficient and Selective Modified Graphene Paste Sensor for the Determination of Catechol and Hydroquinone. Surfaces. 2020; 3(3):473-483. https://doi.org/10.3390/surfaces3030034
Chicago/Turabian StyleManjunatha, Jamballi G. 2020. "Fabrication of Efficient and Selective Modified Graphene Paste Sensor for the Determination of Catechol and Hydroquinone" Surfaces 3, no. 3: 473-483. https://doi.org/10.3390/surfaces3030034