Slow Rotation of Coaxial Slip Colloidal Spheres about Their Axis

Abstract

The flow field around a straight chain of multiple slip spherical particles rotating steadily in an incompressible Newtonian fluid about their line of centers is analyzed at low Reynolds numbers. The particles may vary in radius, slip coefficient, and angular velocity, and they are permitted to be unevenly spaced. Through the use of a boundary collocation method, the Stokes equation governing the fluid flow is solved semi-analytically. The interaction effects among the particles are found to be noteworthy under appropriate conditions. For the rotation of two spheres, our collocation results for their hydrodynamic torques are in good agreement with the analytical asymptotic solution in the literature obtained by using a method of twin multipole expansions. For the rotation of three spheres, the particle interaction effect indicates that the existence of the third particle can influence the torques exerted on the other two particles noticeably. The interaction effect is stronger on the smaller or less slippery particles than on the larger or more slippery ones. Torque results for the rotation of chains of many particles visibly show the shielding effect among the particles.

1. Introduction

The translation and rotation of small particles in Newtonian fluids at low Reynolds numbers play important roles in a variety of technological and industrial processes, such as centrifugation, sedimentation, aggregation, microfluidics, suspension rheology, and aerosol technology. The analysis of this subject was initiated by Stokes [1,2] on the motions of an isolated nonslip spherical particle in a viscous fluid. The phenomena that viscous fluids in creeping flow can frictionally slip at particle surfaces occur for numerous situations, such as a colloidal particle with lyophobic surface [3,4,5,6,7], an aerosol particle in low-density gas [8,9,10], and a porous particle [11,12]. The slip velocity is presumably proportional to the shear stress of the fluid at the particle surface with the proportionality constant ${\beta }^{-1}$ as the slip coefficient [13,14,15].

The hydrodynamic torque exerted on a slip sphere of radius $a$ rotating with angular velocity $\Omega$ in a fluid of viscosity $\eta$ was obtained by Basset [13] as follows:

$$T^{(0)}=-8\mathsf{\pi }\eta a^3\Omega \frac{1}{1+3\eta /\beta a},$$

(1)

where $\eta /\beta$ signifies a slip length. In the limiting case of the stickiness/slip parameter $\beta a/\eta =0$, the particle is perfectly slip (like a gas bubble in a liquid) and $T^{(0)}=0$. In the other limit $\beta a/\eta \to \infty$, the particle is nonslip and Equation (1) becomes the Stokes result. More recently, the creeping flow rotation of slip particles has been examined for a slightly deformed sphere [16,17], an axisymmetric particle, such as spheroid [18,19], and a circular cylinder [20].

In many technical applications, slip particles are not isolated. Thus, it is imperative to determine if the attendance of adjoining particles [21,22] or the proximity of confining walls [23,24,25] meaningfully affects the particle movement. Through an exact representation in spherical bipolar coordinates, the axisymmetric slow translation of two slip spherical particles was investigated semi-analytically and numerical results were calculated for the cases of identical spheres with equal magnitude of velocities [26] and arbitrary spheres with arbitrary velocities [27]. On the other hand, the translational and rotational motions of two arbitrarily oriented spheres with arbitrary radii and slip coefficients were analyzed using a method of twin multipole expansions [28]. Subsequently, the creeping flow around two arbitrary slip spheres translating along and rotating about their line of centers was studied by using a boundary collocation method [29]. It was found from these investigations that the two-sphere interaction effect decreases with increasing slip coefficients of the particles, may be pronounced as the distance between particle surfaces approaches zero, and is greater on the smaller particles than on the larger ones.

For a concentrated suspension, the interaction amongst multiple particles may be important. The objective of this article is to analyze the slow rotation of a chain of coaxial slip spherical particles about the axis. The particles may vary in radius, slip coefficient, and angular velocity, and they are permitted to be unevenly spaced. Through the use of the boundary collocation method, the Stokes equation is solved semi-analytically, and the torques exerted on the particles by the fluid are obtained with excellent convergence. For the simple case of rotation of two spherical particles, our collocation solutions for the torques agree well with the asymptotic solutions resulting from the method of twin multipole expansions [28] and with some numerical calculations [29]. These results may contribute significantly to the area of determining the rotational electrophoretic, diffusiophoretic, and thermophoretic mobilities of uniformly charged, non-uniformly charged, or uncharged particles [30,31,32].

2. Analysis

As shown in Figure 1, we consider the steady slow rotation of a straight chain of $N$ neutrally buoyant spherical particles in a boundless, quiescent, incompressible Newtonian fluid of viscosity $\eta$ about the line through their centers ($z$ axis), where the fluid may slip frictionally at the particle surfaces. The spherical coordinates $(r_i,{\theta }_i,\varphi )$ are measured from the center of particle $i$ (with radius $a_i$) for $i=1$, 2, …, and $N$, and the origin of the circular cylindrical coordinates $(\rho ,\varphi ,z)$ is set at the center of particle 1. The particles may vary in size, surface slippage, and angular velocity, and they are permitted to be unevenly spaced. The purpose is to obtain the correction to Equation (1) for the rotational motion of each particle owing to the presence of the other ones.

The Stokes equation governing the creeping flow around the rotating particles is [25]

$$({\nabla }^2-{\rho }^{-2})v_{\varphi }=\frac{1}{r_i{}^2}\{\frac{\partial }{\partial r_i}(r_i{}^2\frac{\partial v_{\varphi }}{\partial r_i})+\frac{\partial }{\partial {\theta }_i}[\frac{1}{\sin {\theta }_i}\frac{\partial }{\partial {\theta }_i}(v_{\varphi }\sin {\theta }_i)]\}=0,$$

(2)

where $v_{\phi }(r_i,{\theta }_i)$ or $v_{\varphi }(\rho ,z)$ is the $\phi$ (only nontrivial) component of the fluid velocity profile (with $r_1\ge a_1$, $r_2\ge a_2$, …, and $r_N\ge a_N$), the continuity equation is satisfied, and the dynamic pressure is constant everywhere. In Equation (2), any coordinate system $(r_i,{\theta }_i,\varphi )$ can be chosen. Because the slip velocity is proportional to the nontrivial tangential stress locally at each particle surface [13], the fluid velocity satisfies the boundary conditions as follows:

$$r_i=a_i: v_{\varphi }={\Omega }_i{a}_i\sin {\theta }_i+\frac{1}{{\beta }_i}{\tau }_{r_i\varphi }, i=1,2,\dots ,\mathrm{and} N,$$

(3)

$${({\rho }^2+z^2)}^{1/2}\to \infty :v_{\varphi }=0,$$

(4)

where ${\Omega }_i$ is the angular velocity of particle $i$,

$${\tau }_{r_i\phi }=\eta r_i\frac{\partial }{\partial r_i}(\frac{v_{\phi }}{r_i}),$$

(5)

which is the relevant shear stress, and $1/{\beta }_i$ is Navier’s slip coefficient of the particle $i$.

We can express a sufficiently general solution of the fluid velocity in the form

$$v_{\varphi }={\displaystyle \sum _{j=1}^N{\displaystyle \sum _{n=1}^{\infty }{A}_{jn}{r}_j{}^{-n-1}{P}_n^1(\cos {\theta }_j)}},$$

(6)

where $P_n^1$ is the associated Legendre function of the first kind of order $n$ and degree 1, and $A_{jn}$ are the unknown constants to be determined. The boundary condition (4) is satisfied immediately by Equation (6), in which the solutions in $N$ spherical coordinate systems can be superimposed due to the linearity of Equation (2). Substituting Equation (6) into Equation (3), we obtain

$${\displaystyle \sum _{j=1}^N{\displaystyle \sum _{n=1}^{\infty }{A}_{jn}\{r_j{}^{-n-1}[1+(n+2)\frac{\eta }{{\beta }_i{r}_j}]P_n^1(\cos {\theta }_j)}}{\}}_{r_i=a_i}={\Omega }_i{a}_i\sin {\theta }_i, i=1,2,\dots ,\mathrm{and} N.$$

(7)

To express Equations (6) and (7) in a single coordinate system, one can use the conversion formulas between the coordinates $(r_j,{\theta }_j)$ and $(\rho ,z)$,

$$r_j={[{\rho }^2+{(z-d_{1j})}^2]}^{1/2},$$

(8)

$$\cos {\theta }_j=(z-d_{1j})/r_j,$$

(9)

where $d_{ij}$ is the distance between the centers of particles $i$ and $j$ (thus $d_{jj}=0$).

The satisfaction of the boundary conditions in Equation (7) on the particle surfaces requires the solution of the unknown constants $A_{jn}$. The collocation technique [25,33,34] permits these boundary conditions to be imposed at $M$ points along the longitudinal arc of each sphere and the infinite series in Equation (6) is truncated after the $M$ terms, leading to $NM$ simultaneous algebraic equations in the truncated form of Equation (7). For sufficiently large number of $M$, these equations can be numerically solved to yield the $NM$ constants $A_{jn}$ required in the truncated form of Equation (6). The details of the adopted boundary collocation arrangement were given in an early article on the translation of a chain of fluid spheres along their line of centers [35].

The hydrodynamic torque acting on the particle $i$ is the integral of the product of the shear force ${\tau }_{r_i\varphi }(r_i=a_i)a_i^2\sin {\theta }_i\mathrm{d}{\theta }_i\mathrm{d}\varphi$ exerted on a differential surface element and the lever arm $a_i\sin {\theta }_i$ of that element over the particle surface, resulting in

$$T_i=8\mathsf{\pi }\eta A_{i1},i=1,2,\dots ,\mathrm{and} N.$$

(10)

The previous formula shows that only the lowest-order constants $A_{i1}$ contribute to the hydrodynamic torques $T_i^{}$.

The torque results can be expressed as follows:

$$T_i={\displaystyle \sum _{j=1}^N{g}_{ij}}{T}_j^{(0)},$$

(11)

with

$$T_j^{(0)}=-8\mathsf{\pi }\eta a_j{}^3{\Omega }_j\frac{{\beta }_j{a}_j}{{\beta }_j{a}_j+3\eta },$$

(12)

which is the torque acting on the isolated particle $j$ given by Equation (1). The torque correction parameters $g_{ij}$ are functions of the scaled radii, separation distances, and surface slippages of the particles. When the separation distances are infinite, obviously, $g_{ij}$ equals unity if $j=i$ and zero if $j\ne i$.

3. Results for Two Particles

In this section, we present the boundary collocation results for the rotation of two slip spheres ($N=2$) about their line of centers. Once the unknown constants $A_{1n}$ and $A_{2n}$ in Equation (6) for the fluid velocity are solved from the truncated form of Equation (7), Equation (10) can be used to calculate the torque exerted by the fluid on each particle. The numerical results of the four torque correction parameters $g_{11}$, $g_{12}$, $g_{21}$, and $g_{22}$ in Equation (11) are presented in

Table 1. The torque correction parameters $g_{11}$, $g_{12}$, $g_{21}$, and $g_{22}$ for the axisymmetric rotation of two identical spheres ($a_1=a_2=a$, ${\beta }_1={\beta }_2=\beta$). The asymptotic solution is calculated from Equations (13)–(19) for comparison.

$\frac{\mathit{\beta }\mathit{a}}{\mathit{\eta }}$	$\frac{2\mathit{a}}{{\mathit{d}}_{12}}$	Collocation Solution		Asymptotic Solution
		${\mathit{g}}_{11}={\mathit{g}}_{22}$	${\mathit{g}}_{12}={\mathit{g}}_{21}$	${\mathit{g}}_{11}={\mathit{g}}_{22}$	${\mathit{g}}_{12}={\mathit{g}}_{21}$
1	0.2	1.00000	−0.00033	1.00000	−0.00025
	0.3	1.00000	−0.00123	1.00000	−0.00084
	0.4	1.00001	−0.00322	1.00000	−0.00200
	0.5	1.00006	−0.00691	1.00002	−0.00391
	0.6	1.00023	−0.01306	1.00005	−0.00675
	0.7	1.00079	−0.02260	1.00011	−0.01072
	0.8	1.00247	−0.03676	1.00026	−0.01600
	0.9	1.00738	−0.05761	1.00052	−0.02278
	0.99	1.02224	−0.08900	1.00092	−0.06064
	1.0	1.02693	−0.09567	1.00098	−0.06250
10	0.2	1.00000	−0.00079	1.00000	−0.00077
	0.3	1.00001	−0.00271	1.00001	−0.00260
	0.4	1.00005	−0.00653	1.00004	−0.00615
	0.5	1.00020	−0.01295	1.00014	−0.01202
	0.6	1.00068	−0.02273	1.00043	−0.02077
	0.7	1.00199	−0.03674	1.00109	−0.03298
	0.8	1.00529	−0.05612	1.00242	−0.04923
	0.9	1.01351	−0.08313	1.00491	−0.07010
	0.99	1.03508	−0.12286	1.00870	−0.01971
	1.0	1.04120	−0.13103	1.00925	−0.02031
∞	0.2	1.00000	−0.00100	1.00000	−0.00100
	0.3	1.00001	−0.00338	1.00001	−0.00338
	0.4	1.00007	−0.00800	1.00007	−0.00800
	0.5	1.00030	−0.01563	1.00030	−0.01563
	0.6	1.00097	−0.02704	1.00096	−0.02703
	0.7	1.00273	−0.04306	1.00268	−0.04301
	0.8	1.00702	−0.06485	1.00669	−0.06451
	0.9	1.01727	−0.09494	1.01539	−0.09280
	0.99	1.04336	−0.13974	1.03082	−0.12569
	1.0	1.05097	−0.14943	1.03320	−0.12988

for the case of two identical spheres ($a_1=a_2=a$, ${\beta }_1={\beta }_2=\beta$, $g_{11}=g_{22}$, and $g_{12}=g_{21}$) with various values of the stickiness/slip parameter $\beta a/\eta$ and spacing parameter $2a/d_{12}$. In

Table 2. The torque correction parameters $g_{11}$, $g_{12}$, $g_{21}$, and $g_{22}$ for the axisymmetric rotation of two no-slip spheres (${\beta }_1={\beta }_2\to \infty$). The values in parentheses are the asymptotic solution calculated from Equations (13)–(19) for comparison.

$\frac{{\mathit{a}}_2}{{\mathit{a}}_1}$	$\frac{{\mathit{a}}_1+{\mathit{a}}_2}{{\mathit{d}}_{12}}$	${\mathit{g}}_{11}$	${\mathit{g}}_{12}$	${\mathit{g}}_{21}$	${\mathit{g}}_{22}$
2	0.5	1.00024	−0.00463	−0.03705	1.00019
		(1.00024)	(−0.00463)	(−0.03705)	(1.00019)
	0.6	1.00086	−0.00801	−0.06406	1.00058
		(1.00084)	(−0.00801)	(−0.06406)	(1.00058)
	0.7	1.00271	−0.01275	−0.10197	1.00153
		(1.00250)	(−0.01273)	(−0.10187)	(1.00152)
	0.8	1.00795	−0.01917	−0.15335	1.00363
		(1.00673)	(−0.01908)	(−0.15262)	(1.00358)
	0.9	1.02335	−0.02800	−0.22396	1.00809
		(1.01667)	(−0.02737)	(−0.21897)	(1.00769)
	0.99	1.06197	−0.04126	−0.33012	1.01787
		(1.03560)	(−0.03691)	(−0.29532)	(1.01444)
	1.0	1.09395	−0.04449	−0.35606	1.02075
		(1.03861)	(−0.03812)	(−0.30497)	(1.01544)
5	0.5	1.00007	−0.00058	−0.07234	1.00004
		(1.00007)	(−0.00058)	(−0.07234)	(1.00004)
	0.6	1.00030	−0.00100	−0.12504	1.00013
		(1.00027)	(−0.00100)	(−0.12503)	(1.00013)
	0.7	1.00110	−0.00159	−0.19873	1.00033
		(1.00086)	(−0.00159)	(−0.19862)	(1.00033)
	0.8	1.00412	−0.00238	−0.29764	1.00074
		(1.00247)	(−0.00237)	(−0.29679)	(1.00074)
	0.9	1.01743	−0.00344	−0.43050	1.00156
		(1.00653)	(−0.00339)	(−0.42353)	(1.00152)
	0.99	1.09830	−0.00508	−0.63487	1.00318
		(1.01468)	(−0.00453)	(−0.56594)	(1.00274)
	1.0	1.14324	−0.00556	−0.69390	1.00368
		(1.01601)	(−0.00467)	(−0.58361)	(1.00291)

, the collocation solutions of the torque correction parameters $g_{11}$, $g_{12}$, $g_{21}$, and $g_{22}$ for the axisymmetric rotation of two nonslip spheres (${\beta }_1={\beta }_2\to \infty$) with different radii (choosing $a_2/a_1$ equal to 2 and 5) at various values of the spacing parameter $(a_1+a_2)/d_{12}$ are given. In

Table 3. The torque correction parameters $g_{11}$, $g_{12}$, $g_{21}$, and $g_{22}$ for the axisymmetric rotation of two spheres differing in size or slippage.

$\frac{{\mathit{a}}_1+{\mathit{a}}_2}{{\mathit{d}}_{12}}$	${\mathit{g}}_{11}$	${\mathit{g}}_{12}$	${\mathit{g}}_{21}$	${\mathit{g}}_{22}$
$a_2/a_1=1$, ${\beta }_1{a}_1/\eta =1$, ${\beta }_2\to \infty$
0.2	1.00000	−0.00033	−0.00100	1.00000
0.3	1.00000	−0.00123	−0.00338	1.00000
0.4	1.00003	−0.00322	−0.00800	1.00003
0.5	1.00014	−0.00691	−0.01563	1.00013
0.6	1.00049	−0.01307	−0.02702	1.00046
0.7	1.00155	−0.02263	−0.04298	1.00140
0.8	1.00449	−0.03688	−0.06453	1.00387
0.9	1.01258	−0.05814	−0.09382	1.01021
0.99	1.03642	−0.09147	−0.13622	1.02710
1.0	1.04514	−0.09962	−0.14624	1.03280
$a_2/a_1=2$, ${\beta }_1{a}_1/\eta =3$, ${\beta }_2={\beta }_1$
0.2	1.00000	−0.00016	−0.00169	1.00000
0.3	1.00000	−0.00055	−0.00588	1.00000
0.4	1.00002	−0.00134	−0.01438	1.00002
0.5	1.00011	−0.00271	−0.02901	1.00009
0.6	1.00042	−0.00482	−0.05184	1.00028
0.7	1.00143	−0.00788	−0.08532	1.00079
0.8	1.00459	−0.01216	−0.13272	1.00201
0.9	1.01496	−0.01813	−0.20015	1.00479
0.99	1.05306	−0.02690	−0.30147	1.01124
1.0	1.06789	−0.02888	−0.32475	1.01311

, we list the typical collocation results of these torque correction parameters for cases of two slip spheres differing in either size or slippage at various values of the spacing parameter $(a_1+a_2)/d_{12}$. All of our results converge to at least five digits after the decimal point.

In Table 1, Table 2 and Table 3, for all values of $a_2/a_1$, ${\beta }_1{a}_1/\eta$, and ${\beta }_2{a}_2/\eta$, the parameters $g_{11}$ and $g_{22}$ are positive and increase with an increase of $(a_1+a_2)/d_{12}$ from unity at $(a_1+a_2)/d_{12}=0$, while $g_{12}$ and $g_{21}$ are negative and whose magnitudes also increase with an increase of $(a_1+a_2)/d_{12}$ but from zero at $(a_1+a_2)/d_{12}=0$. These results manifest that the particles’ interaction rises with diminishing gap thickness between them. In general, this interaction can be significant as $(a_1+a_2)/d_{12}\to 1$ and its influence is stronger on a smaller or less slippery (stickier) particle than on a larger or more slippery (less sticky) one for any given value of $(a_1+a_2)/d_{12}$.

Using a method of twin multipole expansions, Keh and Chen [28] analytically obtained the following power-series formulas of the torque correction parameters $g_{11}$, $g_{12}$, $g_{21}$, and $g_{22}$ for the axial rotation of two spheres with ${\beta }_1{a}_1={\beta }_2{a}_2=\beta a$:

$$g_{11}(s,\lambda )=g_{22}(s,{\lambda }^{-1})={\displaystyle \sum _{k=0}^{\infty }{f}_{2k}(\lambda )}{(1+\lambda )}^{-2k}{s}^{-2k},$$

(13)

$$g_{12}(s,\lambda )=g_{21}(s,{\lambda }^{-1})=-8{\displaystyle \sum _{k=0}^{\infty }{f}_{2k+1}(\lambda )}{(1+\lambda )}^{-2k-4}{s}^{-2k-1},$$

(14)

where

$$s=\frac{2d_{12}}{a_1+a_2},$$

(15)

$$\lambda =\frac{a_2}{a_1},$$

(16)

$$f_1=f_2=f_4=f_5=f_7=0,$$

(17)

$$f_0=1, f_3=8{\lambda }^3\frac{\beta a}{\beta a+3\eta }, f_6=64{\lambda }^3{(\frac{\beta a}{\beta a+3\eta })}^2.$$

(18)

Thus, there are two independent torque correction parameters to be determined for $0\le \lambda <\infty$ and $2\le s<\infty$. Alternatively, we could determine all four parameters in the range $1\le \lambda <\infty$ and $2\le s<\infty$. In the particular case of ${\beta }_1={\beta }_2\to \infty$ (two nonslip spheres), more terms of $f_k(\lambda )$ are available [36]:

$$f_8=768{\lambda }^5, f_9=512{\lambda }^6, f_{10}=6144{\lambda }^7, f_{11}=6144({\lambda }^6+{\lambda }^8).$$

(19)

The asymptotic solutions for the torque correction parameters obtained from the previous formulas are also listed in Table 1 and Table 2 for comparison. It is found that our collocation results are in good agreement with these asymptotic solutions as $(a_1+a_2)/d_{12}$ is small; however, the errors of these asymptotic solutions become significant when $(a_1+a_2)/d_{12}$ gets close to unity. Note that the method of twin multipole expansions can be used to deal with the rotational and translational motions of two slip spheres in an arbitrary (axisymmetric or asymmetric) configuration.

Using the reciprocal theorem of Lorentz [15] for the axisymmetric rotation of any two slip spheres with ${\beta }_1{a}_1={\beta }_2{a}_2$, we obtain

$$\frac{g_{21}}{g_{12}}={(\frac{a_2}{a_1})}^3.$$

(20)

The collocation results in Table 1 and Table 2 satisfy Equation (20) and the relations $g_{11}+g_{21}\le 1$ and $g_{12}+g_{22}\le 1$ (with $g_{11}$ and $g_{22}$ being positive and $g_{12}$ and $g_{21}$ negative), indicating that the rotation of one particle is enhanced (its hydrodynamic torque is reduced) by another nearby particle rotating with a comparable or larger angular velocity in the same direction but is hindered (the resisting torque is augmented) by another particle rotating with an arbitrary angular velocity in the opposite direction.

4. Results for Multiple Particles

We now present the boundary collocation results for the rotation of a chain of three or more slip spheres about their line of centers. From Equation (11), the general problem requires nine torque correction parameters to represent the hydrodynamic torques on the three-sphere chain. For the sake of brevity, here we only consider the rotation of three coaxial spheres with the same slip coefficient (${\beta }_1={\beta }_2={\beta }_3=\beta$) in a symmetric configuration, i.e., the spheres at both ends have equal radii ($a_3=a_1$) and are equally distant from the central sphere ($d_{23}=d_{12}=d$). For this symmetric case, it is clear that the torque correction coefficients

$$g_{11}=g_{33}, g_{12}=g_{32}, g_{23}=g_{21}, g_{31}=g_{13}.$$

(21)

In

Table 4. The torque correction parameters for the axisymmetric rotation of three identical slip spheres ($a_1=a_2=a_3=a$ and ${\beta }_1={\beta }_2={\beta }_3=\beta$) with equal spacings ($d_{23}=d_{12}=d$).

$\mathit{\beta }\mathit{a}/\mathit{\eta }$	$\frac{2\mathit{a}}{\mathit{d}}$	${\mathit{g}}_{22}$	${\mathit{g}}_{11}={\mathit{g}}_{33}$	$\begin{array}{l}{\mathit{g}}_{12}={\mathit{g}}_{32}\\ ={\mathit{g}}_{21}={\mathit{g}}_{23}\end{array}$	${\mathit{g}}_{13}={\mathit{g}}_{31}$
1	0.2	1.00000	1.00000	−0.00033	−0.00004
	0.3	1.00000	1.00000	−0.00123	−0.00013
	0.4	1.00002	1.00001	−0.00322	−0.00032
	0.5	1.00012	1.00006	−0.00691	−0.00063
	0.6	1.00046	1.00023	−0.01305	−0.00110
	0.7	1.00158	1.00080	−0.02256	−0.00171
	0.8	1.00493	1.00247	−0.03666	−0.00244
	0.9	1.01473	1.00739	−0.05740	−0.00322
	0.99	1.04441	1.02225	−0.08866	−0.00392
	1.0	1.05330	1.02724	−0.09501	−0.00399
10	0.2	1.00000	1.00000	−0.00079	−0.00010
	0.3	1.00002	1.00001	−0.00271	−0.00032
	0.4	1.00010	1.00005	−0.00652	−0.00075
	0.5	1.00040	1.00020	−0.01293	−0.00142
	0.6	1.00136	1.00069	−0.02267	−0.00232
	0.7	1.00396	1.00200	−0.03660	−0.00341
	0.8	1.01054	1.00531	−0.05582	−0.00461
	0.9	1.02693	1.01355	−0.08259	−0.00586
	0.99	1.06996	1.03511	−0.12204	−0.00695
	1.0	1.08354	1.04192	−0.13082	−0.00707
∞	0.2	1.00000	1.00000	−0.00100	−0.00012
	0.3	1.00002	1.00001	−0.00337	−0.00041
	0.4	1.00014	1.00007	−0.00799	−0.00094
	0.5	1.00059	1.00030	−0.01560	−0.00175
	0.6	1.00193	1.00098	−0.02695	−0.00282
	0.7	1.00545	1.00275	−0.04286	−0.00409
	0.8	1.01397	1.00705	−0.06445	−0.00546
	0.9	1.03439	1.01732	−0.09423	−0.00687
	0.99	1.08644	1.04341	−0.13864	−0.00812
	1.0	1.10321	1.05182	−0.14909	−0.00826

, the collocation results of the torque correction parameters in Equation (11) for the axisymmetric rotation of three identical slip spheres ($a_1=a_2=a_3=a$) with different values of the stickiness parameter $\beta a/\eta$ and spacing parameter $2a/d$ are offered. In

Table 5. The torque correction parameters for the axisymmetric rotation of three no-slip spheres (${\beta }_1={\beta }_2={\beta }_3\to \infty$) with $a_3=a_1$ and $d_{23}=d_{12}=d$.

${\mathit{a}}_1:{\mathit{a}}_2:{\mathit{a}}_3$	$\frac{{\mathit{a}}_1+{\mathit{a}}_2}{\mathit{d}}$	${\mathit{g}}_{22}$	${\mathit{g}}_{11}={\mathit{g}}_{33}$	${\mathit{g}}_{12}={\mathit{g}}_{32}$	${\mathit{g}}_{21}={\mathit{g}}_{23}$	${\mathit{g}}_{13}={\mathit{g}}_{31}$
1:2:1	0.2	1.00000	1.00000	−0.00030	−0.00237	−0.00004
	0.3	1.00002	1.00001	−0.00100	−0.00800	−0.00012
	0.4	1.00009	1.00006	−0.00237	−0.01896	−0.00026
	0.5	1.00037	1.00024	−0.00463	−0.03703	−0.00045
	0.6	1.00116	1.00087	−0.00800	−0.06402	−0.00067
	0.7	1.00306	1.00271	−0.01273	−0.10188	−0.00088
	0.8	1.00726	1.00795	−0.01915	−0.15320	−0.00103
	0.9	1.01616	1.02335	−0.02797	−0.22373	−0.00110
	0.99	1.03572	1.07433	−0.04123	−0.32982	−0.00110
	0.999	1.04058	1.09059	−0.04397	−0.35177	−0.00110
	1.0	1.04136	1.09376	−0.04445	−0.35557	−0.00110
2:1:2	0.2	1.00000	1.00000	−0.00237	−0.00030	−0.00030
	0.3	1.00002	1.00001	−0.00799	−0.00100	−0.00099
	0.4	1.00011	1.00005	−0.01892	−0.00236	−0.00233
	0.5	1.00049	1.00021	−0.03685	−0.00461	−0.00447
	0.6	1.00172	1.00064	−0.06346	−0.00793	−0.00756
	0.7	1.00536	1.00169	−0.10038	−0.01255	−0.01165
	0.8	1.01568	1.00396	−0.14971	−0.01871	−0.01681
	0.9	1.04600	1.00872	−0.21645	−0.02706	−0.02308
	0.99	1.14694	1.01894	−0.31689	−0.03961	−0.02980
	0.999	1.17932	1.02142	−0.33813	−0.04227	−0.03054
	1.0	1.18582	1.02188	−0.34194	−0.04274	−0.03062

, the numerical results of the torque correction parameters for the rotation of three nonslip spheres ($\beta \to \infty$) for two typical cases of relative particle sizes ($a_2/a_1$ equal to 2 and 1/2) at various values of the spacing parameter $(a_1+a_2)/d$ are given. In

Table 6. The torque correction parameters for the axisymmetric rotation of three slip spheres with ${\beta }_1={\beta }_2={\beta }_3=\beta$, $a_3=a_1$, $\beta a_2/\eta =1$, and $d_{23}=d_{12}=d$.

${\mathit{a}}_1:{\mathit{a}}_2:{\mathit{a}}_3$	$\frac{{\mathit{a}}_1+{\mathit{a}}_2}{\mathit{d}}$	${\mathit{g}}_{22}$	${\mathit{g}}_{11}={\mathit{g}}_{33}$	${\mathit{g}}_{12}={\mathit{g}}_{32}$	${\mathit{g}}_{21}={\mathit{g}}_{23}$	${\mathit{g}}_{13}={\mathit{g}}_{31}$
1:2:1	0.2	1.00000	1.00000	−0.00006	−0.00083	−0.00001
	0.3	1.00000	1.00000	−0.00023	−0.00322	−0.00002
	0.4	1.00001	1.00001	−0.00061	−0.00865	−0.00006
	0.5	1.00006	1.00004	−0.00133	−0.01896	−0.00011
	0.6	1.00021	1.00017	−0.00254	−0.03657	−0.00017
	0.7	1.00069	1.00067	−0.00442	−0.06463	−0.00024
	0.8	1.00202	1.00254	−0.00720	−0.10748	−0.00030
	0.9	1.00549	1.00977	−0.01125	−0.17256	−0.00033
	0.99	1.01456	1.04047	−0.01731	−0.27461	−0.00030
	0.999	1.01694	1.05118	−0.01849	−0.29502	−0.00030
	1.0	1.01726	1.05328	−0.01864	−0.29841	−0.00030
2:1:2	0.2	1.00000	1.00000	−0.00114	−0.00009	−0.00013
	0.3	1.00000	1.00000	−0.00417	−0.00033	−0.00046
	0.4	1.00002	1.00001	−0.01070	−0.00083	−0.00113
	0.5	1.00011	1.00005	−0.02252	−0.00174	−0.00228
	0.6	1.00047	1.00017	−0.04185	−0.00320	−0.00406
	0.7	1.00175	1.00052	−0.07142	−0.00541	−0.00658
	0.8	1.00619	1.00141	−0.11479	−0.00855	−0.00995
	0.9	1.02229	1.00358	−0.17814	−0.01300	−0.01428
	0.99	1.08748	1.00878	−0.27514	−0.01954	−0.01910
	0.999	1.10984	1.01016	−0.29470	−0.02083	−0.01964
	1.0	1.11423	1.01033	−0.29798	−0.02096	−0.01970

, we list the results of the torque correction parameters for the rotation of three slip spheres (with $\beta a_2/\eta =1$ and $a_2/a_1$ equal to 2 and 1/2) at various values of $(a_1+a_2)/d$. In general, particle interactions increase with a decreasing gap thickness between two adjacent particles. When the central particle (particle 2) is greater than the end ones, however, the torque correction parameters $g_{13}$ and $g_{31}$ for the interaction between the end particles are not always monotonical functions of $(a_1+a_2)/d$. Again, Equation (20) holds in Table 4 and Table 5 for the axisymmetric rotation of the three-sphere chain and the effect of particle interactions on the hydrodynamic torques is greater for smaller or less slippery particles than for larger or more slippery ones for a given value of $(a_1+a_2)/d$.

It may be interesting to realize how much the presence of a third particle affects the hydrodynamic torques of its two neighbors. The normalized torques $T_i^{}/T_{}^{(0)}$ of three identical spheres ($a_1=a_2=a_3=a$, ${\beta }_1={\beta }_2={\beta }_3=\beta$, and $T_1^{(0)}=T_2^{(0)}=T_3^{(0)}=T_{}^{(0)}$) rotating at equal angular velocities (${\Omega }_1={\Omega }_2={\Omega }_3=\Omega$) about their line of centers at equal spacings ($d_{12}=d_{23}=d$) are plotted versus the spacing parameter $2a/d$ by solid curves for various values of the stickiness parameter $\beta a/\eta$ in Figure 2. For comparison, the corresponding results of normalized torques of the first and second particles in the absence of the third one, which agree well with those obtained by Saad [29], are plotted in the same figure by dashed curves. Clearly, the presence of the third particle reduces the torques of the other two particles. As expected, the reduction in torque is much more pronounced on the center particle than on the end ones. When the particles are in contact with each other ($2a/d=1$), the presence of the third particle reduces the torque on the first (end) particle by merely about 0.8% in the case of no-slip particles ($\beta a/\eta \to \infty$) and about 0.3% in the case of slip particles with $\beta a/\eta =1$, as shown in Figure 2a (and Table 1 and Table 4). In contrast, as shown in Figure 2b (and Table 1 and Table 4), the torque on the second (center) particle is reduced by 10.7% in the case of no-slip particles and by 7.3% in the case of slip particles with $\beta a/\eta =1$ when the particles touch each other. Note that, due to the configurational symmetry, the torque results presented in Table 1 and Figure 2 for two identical slip spheres a distance $d$ apart and rotating at an identical angular velocity are the same as those for an isolated slip sphere rotating at an equal angular velocity at a distance $d/2$ from a large planar free surface (with vanishing shear stress) normal to the axis of rotation.

The solution to the problem of chains consisting of different numbers of $N$ (up to 101) identical slip spheres ($a_i=a$, ${\beta }_i=\beta$, and $T_i^{(0)}=T_{}^{(0)}$) with equal spacings ($d_{i(i+1)}=d$), rotating about their line of centers with equal angular velocities (${\Omega }_i=\Omega$), has also been obtained by the boundary collocation method. The results of the normalized torques $T_i^{}/T_{}^{(0)}$ for these chains with $2a/d=0.8$ are plotted against the particle number $i$ in Figure 3. It can be seen that the torques on the central particles decrease with an increasing chain length, indicating a shielding effect of the particle chain. When approaching the ends of the chain, the relative torques of neighboring particles change rapidly, demonstrating a strong end effect. As the chain length increases for a relatively long chain, the torques on the central particles change slowly. The torque on each particle will be the same in the limit of an infinite chain. The dashed curves in Figure 3 represent the change in torque of the ith particle in the chain as more particles are added to the chain. These curves are leveled out as the chain length is increased, again demonstrating the shielding effect exhibited by particle chains.

Figure 4 represents a plot of the normalized torques $T_i^{}/T_{}^{(0)}$ versus the particle number $i$ for a chain of nine identical and equally spaced slip particles with $2a/d=0.8$ rotating with equal angular velocities at different values of the stickiness parameter $\beta a/\eta$. These results show that as $\beta a/\eta$ increases, the torque on each particle in the chain decreases. Particle interactions are strictest for no-slip particle chains and weaker for corresponding more slippery particle chains.

To examine the effect of particle spacing, the normalized torques $T_i^{}/T_{}^{(0)}$ versus the particle number $i$ are plotted in Figure 5 for the chain containing nine identical and equally spaced particles rotating at equal angular velocities with $2a/d$ as a parameter. Both the case of no-slip ($\beta a/\eta \to \infty$) particle chains and a case of partly slip (with $\beta a/\eta =1$) particle chains are shown. The results in this figure illustrate that end effects decrease with increasing spacing (decreasing $2a/d$). As expected, the torque of each particle in the chain decreases as the particles get closer together.

Although the results in Figure 2, Figure 3, Figure 4 and Figure 5 about the torques variation by particle spacings, slip conditions, and chain lengths are based on the simulations of identical particles, similar figures for the coupling outcome with particles of different sizes can easily be plotted and demonstrate that the effect of particle interactions on the torques is greater for smaller particles than for larger ones. Also, the results in Figure 2, Figure 3, Figure 4 and Figure 5 can be applied to the axial rotation of a cluster of multiple spheres connected through their centers with very thin rigid rods that make no hydrodynamic contributions.

5. Concluding Remarks

The slow rotation of a straight chain of multiple slip spheres about their line of centers in a Newtonian fluid is analyzed in this article. The spheres may vary in radius, slip coefficient, and angular velocity, and they are permitted to be unevenly spaced. The boundary collocation method has been employed to obtain the fluid velocity field semi-analytically. The solutions of the hydrodynamic torques exerted on the particles can be obtained even when the number of particles is large and the particles touch one another. Section 2 presents the linear algebraic collocation formulations for solving the general axisymmetric problem of multi-sphere rotations, and numerical results of the torques for two-sphere, three-sphere, and multi-sphere systems to correct Equation (1) are given in Section 3 and Section 4. The interaction effects among the particles are found to be noteworthy under appropriate conditions. Although the current article is confined to the axisymmetric rotation of straight chains of particles, the solution procedure can be extended to investigate the slow rotation of arbitrary three-dimensional assemblages of spherical particles [30,32].

The results for the resistance problem are presented in previous sections, in which the hydrodynamic torques $T_i$ experienced by a chain of particles are calculated for specified angular velocities ${\Omega }_i$ according to Equations (11) and (12). In a mobility problem, on the other hand, the applied torques on the particles are specified, and the resultant angular velocities need to be determined. The presentation of the mobility problem is somewhat awkward since the boundary conditions involve the unknowns, but in some physical problems, the torques are the prescribed quantities, and the particles rotate accordingly. For the axisymmetric rotation of $N$ slip spheres, the angular velocity of particle $i$ can be expressed as follows:

$${\Omega }_i={\displaystyle \sum _{j=1}^N{m}_{ij}}{\Omega }_{j0}, i=1,2,\dots ,\mathrm{and}N,$$

(22)

with

$${\Omega }_{j0}=-\frac{{\beta }_j{a}_j+3\eta }{8\mathsf{\pi }\eta a_j{}^3{\beta }_j{a}_j}{T}_j,$$

(23)

which is the angular velocity of particle $j$ subject to an applied torque $-T_j$ in the absence of the other particles, and the mobility parameters $m_{ij}$ are functions of the scaled radii, separation distances, and surface slippages of the particles. For the case of two particles ($N=2$), one can use Equations (11), (12), (22) and (23) to obtain the following:

$$m_{11}={(g_{11}-g_{12}{g}_{21}/g_{22})}^{-1},$$

(24)

$$m_{12}={(\frac{a_2}{a_1})}^3\frac{{\beta }_2{a}_2({\beta }_1{a}_1+3\eta )}{{\beta }_1{a}_1({\beta }_2{a}_2+3\eta )}{(g_{21}-g_{11}{g}_{22}/g_{12})}^{-1},$$

(25)

where the corresponding expressions for $m_{22}$ and $m_{21}$ can be determined from the previous formulas by interchanging subscripts 1 and 2. The mobility parameters $m_{11}$, $m_{12}$, $m_{21}$, and $m_{22}$ can thus be calculated from using the torque correction parameters $g_{11}$, $g_{12}$, $g_{21}$, and $g_{22}$ obtained in Section 3 for its resistance problem.