You are currently viewing a new version of our website. To view the old version click .
Proceedings
  • Abstract
  • Open Access

24 November 2023

From Organometallic Chemistry to Multifunctional Nanoparticle-Based Devices for Gas Detection and Degradation of Air Pollutants †

,
and
1
Laboratory of Coordination Chemistry (LCC), CNRS UPR 8241, University of Toulouse, 205 Route de Narbonne, 31077 Toulouse, France
2
Université de Toulouse, UT3 Paul Sabatier, 118 Route de Narbonne, CEDEX 04, 31062 Toulouse, France
*
Author to whom correspondence should be addressed.
Presented at the International Conference EcoBalt 2023 “Chemicals & Environment”, Tallinn, Estonia, 9–11 October 2023.
This article belongs to the Proceedings International Conference EcoBalt 2023 "Chemicals & Environment"
Considering the climate, societal and health-related current and emerging issues facing the world, our group, as part of the (nano-)material science community, will play a part in providing materials and technology that can tackle these issues. Our strategy focuses on the design and development of complex hybrid nano-objects and nanomaterials with unprecedented properties, with the aim of developing functional and innovative solutions to societal challenges (Figure 1). To achieve this, we are applying an organometallic approach for the synthesis of well-defined nanoparticles (NPs) and nanomaterials [1]. This bottom-up approach allows control of the NPs synthesis (size, shape, colloidal stability) on a molecular level with the help of cleverly designed starting molecular precursor(s), under mild reaction conditions and in safe-by-design approaches [2]. The presentation will focus on our team’s research related to the synthesis and properties of NPs and nanomaterials, their implementation into devices for either gas detection (i.e., sensors based on Cu [3], Zn [4,5], and Sn oxide NPs [6,7]) or degradation of air pollutants [8], and the interconnection between different fields (chemistry, physical chemistry, physics, and biology).
Figure 1. Positive feedback loop on the development of new nanomaterials and technological solutions to societal needs.

Author Contributions

Writing—original draft preparation, M.J.; writing—review and editing, K.F. and M.L.K.; supervision, K.F. and M.L.K. All authors have read and agreed to the published version of the manuscript.

Funding

This research was funded by the Centre National de la Recherche Scientifique, CNRS and Université de Toulouse.

Institutional Review Board Statement

Not applicable.

Data Availability Statement

The data presented during the oral presentation was based on the references above, from where relevant research data can be found.

Conflicts of Interest

The authors declare no conflict of interest.

References

  1. Amiens, C.; Chaudret, B.; Ciuculescu-Pradines, D.; Collière, V.; Fajerwerg, K.; Fau, P.; Kahn, M.; Maisonnat, A.; Soulantica, K.; Philippot, K. Organometallic approach for the synthesis of nanostructures. New J. Chem. 2013, 37, 3374–3401. [Google Scholar] [CrossRef]
  2. Carnide, C.; Champouret, Y.; Valappil, D.; Vahlas, C.; Mingotaud, A.-F.; Clergereaux, R.; Kahn, M.L. Secured Nanosynthesis–Deposition Aerosol Process for Composite Thin Films Incorporating Highly Dispersed Nanoparticles. Adv. Sci. 2022, 10, 2204929. [Google Scholar] [CrossRef] [PubMed]
  3. Jońca, J.; Ryzhikov, A.; Palussière, S.; Esvam, J.; Fajerwerg, K.; Menini, P.; Kahn, M.L.; Fau, P. Organometallic Synthesis of CuO Nanoparticles: Application in Low-Temperature CO Detection. ChemPhysChem 2017, 18, 2658–2665. [Google Scholar] [CrossRef] [PubMed]
  4. Jońca, J.; Ryzhikov, A.; Kahn, M.L.; Fajerwerg, K.; Chaudret, B.; Chappelle, A.; Menini, P.; Fau, P. Shape-controlled ZnO Nanistructures for Gas Sensing Applications. Procedia Eng. 2014, 87, 907–910. [Google Scholar] [CrossRef][Green Version]
  5. Ryzhikov, A.; Jońca, J.; Kahn, M.; Fajerwerg, K.; Chaudret, B.; Chappelle, A.; Menini, P.; Shim, C.H.; Gaudon, A.; Fau, P. Organometallic synthesis of ZnO nanoparticles for gas sensing: Towards selectivity through nanoparticles morphology. J. Nanopart. Res. 2015, 17, 280. [Google Scholar] [CrossRef]
  6. Jońca, J.; Ryzhikov, A.; Fajerwerg, K.; Kahn, M.L.; Chaudret, B.; Chappelle, A.; Menini, P.; Fau, P. A Novel SnO2 Sensor and its Selectivity Improvement with Catalytic Filter. Procedia Eng. 2014, 87, 923–926. [Google Scholar] [CrossRef]
  7. Jońca, J.; Ryzhikov, A.; Kahn, M.L.; Fajerwerg, K.; Chappelle, A.; Menini, P.; Fau, P. SnO2 “Russian Doll” Octahedra Prepared by Metalorganic Synthesis: A New Structure for Sub-ppm CO Detection. Chem. Eur. J. 2016, 22, 10127–10135. [Google Scholar] [CrossRef] [PubMed]
  8. Castelló Lux, K.; Hot, J.; Fau, P.; Bertron, A.; Kahn, M.L.; Ringot, E.; Fajerwerg, K. Nano-gold decorated ZnO: An alternative photocatalyst promising for NOx degradation. Chem. Eng. Sci. 2023, 267, 118377. [Google Scholar] [CrossRef]
Disclaimer/Publisher’s Note: The statements, opinions and data contained in all publications are solely those of the individual author(s) and contributor(s) and not of MDPI and/or the editor(s). MDPI and/or the editor(s) disclaim responsibility for any injury to people or property resulting from any ideas, methods, instructions or products referred to in the content.

Article Metrics

Citations

Article Access Statistics

Multiple requests from the same IP address are counted as one view.