Deuteration of Alkenes with NaBD4/AcOD in Pre-Sence of Pd on Carbon †
by
Fatima AlJunaibi
, 
Hanan Aldhanhani
,
Halima Alawani
,
Amnah Al Hmoudi
,
Abdullah Al-Hemyari
and
Thies Thiemann
* Department of Chemistry, College of Science, United Arab Emirates University, P.O. Box 15551 Al Ain, UAE
*
Author to whom correspondence should be addressed.
†
Presented at the 23rd International Electronic Conference on Synthetic Organic Chemistry, 15 November–15 December 2019; Available online: https://ecsoc-23.sciforum.net/.
Proceedings 2019, 41(1), 6; https://doi.org/10.3390/ecsoc-23-06461
Published: 14 November 2019
(This article belongs to the Proceedings of The 23rd International Electronic Conference on Synthetic Organic Chemistry)
Abstract
Activated alkenes such as cinnamates and chalcones can easily be converted to 2,3-dideuterio-arylpropionates and dideuteriochalcones, respectively, by the action of NaBD4, AcOD in the presence of Pd on carbon. Toluene or benzene was used as solvent. It was shown that Pd on carbon was necessary for the reaction to proceed. Deuterium addition experiments were also carried out with NaBD4, AcOD, D2O in the presence of Pd on carbon.
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MDPI and ACS Style
AlJunaibi, F.; Aldhanhani, H.; Alawani, H.; Hmoudi, A.A.; Al-Hemyari, A.; Thiemann, T. Deuteration of Alkenes with NaBD4/AcOD in Pre-Sence of Pd on Carbon. Proceedings 2019, 41, 6. https://doi.org/10.3390/ecsoc-23-06461
AMA Style
AlJunaibi F, Aldhanhani H, Alawani H, Hmoudi AA, Al-Hemyari A, Thiemann T. Deuteration of Alkenes with NaBD4/AcOD in Pre-Sence of Pd on Carbon. Proceedings. 2019; 41(1):6. https://doi.org/10.3390/ecsoc-23-06461
Chicago/Turabian StyleAlJunaibi, Fatima, Hanan Aldhanhani, Halima Alawani, Amnah Al Hmoudi, Abdullah Al-Hemyari, and Thies Thiemann. 2019. "Deuteration of Alkenes with NaBD4/AcOD in Pre-Sence of Pd on Carbon" Proceedings 41, no. 1: 6. https://doi.org/10.3390/ecsoc-23-06461
