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Proceeding Paper

Deuteration of Alkenes with NaBD4/AcOD in Pre-Sence of Pd on Carbon †

Department of Chemistry, College of Science, United Arab Emirates University, P.O. Box 15551 Al Ain, UAE
*
Author to whom correspondence should be addressed.
Presented at the 23rd International Electronic Conference on Synthetic Organic Chemistry, 15 November–15 December 2019; Available online: https://ecsoc-23.sciforum.net/.
Proceedings 2019, 41(1), 6; https://doi.org/10.3390/ecsoc-23-06461
Published: 14 November 2019

Abstract

Activated alkenes such as cinnamates and chalcones can easily be converted to 2,3-dideuterio-arylpropionates and dideuteriochalcones, respectively, by the action of NaBD4, AcOD in the presence of Pd on carbon. Toluene or benzene was used as solvent. It was shown that Pd on carbon was necessary for the reaction to proceed. Deuterium addition experiments were also carried out with NaBD4, AcOD, D2O in the presence of Pd on carbon.
Keywords: deuterium addition; in situ deuterium production; sodium borodeuteride deuterium addition; in situ deuterium production; sodium borodeuteride

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MDPI and ACS Style

AlJunaibi, F.; Aldhanhani, H.; Alawani, H.; Hmoudi, A.A.; Al-Hemyari, A.; Thiemann, T. Deuteration of Alkenes with NaBD4/AcOD in Pre-Sence of Pd on Carbon. Proceedings 2019, 41, 6. https://doi.org/10.3390/ecsoc-23-06461

AMA Style

AlJunaibi F, Aldhanhani H, Alawani H, Hmoudi AA, Al-Hemyari A, Thiemann T. Deuteration of Alkenes with NaBD4/AcOD in Pre-Sence of Pd on Carbon. Proceedings. 2019; 41(1):6. https://doi.org/10.3390/ecsoc-23-06461

Chicago/Turabian Style

AlJunaibi, Fatima, Hanan Aldhanhani, Halima Alawani, Amnah Al Hmoudi, Abdullah Al-Hemyari, and Thies Thiemann. 2019. "Deuteration of Alkenes with NaBD4/AcOD in Pre-Sence of Pd on Carbon" Proceedings 41, no. 1: 6. https://doi.org/10.3390/ecsoc-23-06461

APA Style

AlJunaibi, F., Aldhanhani, H., Alawani, H., Hmoudi, A. A., Al-Hemyari, A., & Thiemann, T. (2019). Deuteration of Alkenes with NaBD4/AcOD in Pre-Sence of Pd on Carbon. Proceedings, 41(1), 6. https://doi.org/10.3390/ecsoc-23-06461

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