Kinetic Study of CO2 Hydration by Small-Molecule Catalysts with A Second Coordination Sphere that Mimic the Effect of the Thr-199 Residue of Carbonic Anhydrase
Abstract
:1. Introduction
2. Materials and Methods
2.1. General Consideration
2.2. Materials Synthesis
[(TPA)Zn(OH2)](ClO4)2 (1)
[(TPA-OH)Zn(OH2)](ClO4)2 (2)
2.3. Potentiometric pH Titration
2.4. Kinetic Measurements (Stopped-Flow Spectrophotometer)
3. Results and Discussion
3.1. General Consideration
3.2. pKa Measurement
3.3. Kinetic Measurements
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Conflicts of Interest
References
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Complexes | (1) | (2) |
---|---|---|
pKa | 8.0 | 6.8 |
Complexes | kobs | kind | σobs |
---|---|---|---|
(1) | 648.4 | 717.88 | 23.7 |
(2) | 730.6 | 735.21 | 53.7 |
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Park, D.; Lee, M.S. Kinetic Study of CO2 Hydration by Small-Molecule Catalysts with A Second Coordination Sphere that Mimic the Effect of the Thr-199 Residue of Carbonic Anhydrase. Biomimetics 2019, 4, 66. https://doi.org/10.3390/biomimetics4040066
Park D, Lee MS. Kinetic Study of CO2 Hydration by Small-Molecule Catalysts with A Second Coordination Sphere that Mimic the Effect of the Thr-199 Residue of Carbonic Anhydrase. Biomimetics. 2019; 4(4):66. https://doi.org/10.3390/biomimetics4040066
Chicago/Turabian StylePark, DongKook, and Man Sig Lee. 2019. "Kinetic Study of CO2 Hydration by Small-Molecule Catalysts with A Second Coordination Sphere that Mimic the Effect of the Thr-199 Residue of Carbonic Anhydrase" Biomimetics 4, no. 4: 66. https://doi.org/10.3390/biomimetics4040066