Physicochemical Characterization and Oxidative Potential of Iron-Containing Particles Emitted from Xuanwei Coal Combustion
Abstract
:1. Introduction
2. Materials and Methods
2.1. Coal Burning Experiment and Coal Combustion Particle Sampling
2.2. Chemical Element Analysis of the Coal Combustion Particles
2.3. Detection of Environmentally Persistent Free Radicals (EPFRs) and OH Radicals in the Coal Combustion Particles
2.4. Identification of Iron-Containing Particles
2.5. Iron Dissolution from the Coal Combustion Particles
2.6. Oxidative Potential of Coal Combustion Particles
2.7. Statistical Analysis
3. Results
3.1. Percentage of Iron-Containing Particles among the Measured Particles
3.2. Intensity of Free Radicals Generated by Xuanwei Coal Combustion Particles
3.3. Chemical Elements in the Size-Resolved Particles from Xuanwei Coal Combustion
3.4. Dissolution Ratio of Iron-Bearing Minerals
3.5. Oxidation Potential of Iron
4. Discussion
4.1. Free Radicals Generated by Fe-Containing Particles
4.2. Solubility and Oxidative Potential of Iron-Containing Particles
5. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Coarse Particles | Fine Particles | Submicron Particles | |||
---|---|---|---|---|---|
>7.0 μm | 3.3–7.0 μm | 2.0–3.3 μm | 1.1–2.0 μm | <1.1 μm | |
Na | 891.45 | 480.61 | 71.16 | 27.26 | 130.77 |
Mg | 5215.94 | 2284.15 | 234.06 | 51.26 | 36.68 |
Al | 3926.18 | 1818.40 | 278.81 | 49.63 | 369.00 |
P | 9.48 | 4.95 | 0.45 | 0.41 | 0.86 |
S | 2693.32 | 629.26 | 322.67 | 244.08 | 1267.11 |
Cl | 322.44 | 104.05 | 105.17 | 103.73 | 4190.61 |
K | 246.57 | 123.87 | 12.08 | 16.27 | 8.20 |
Ca | 104.32 | 89.19 | 8.50 | 4.47 | 26.76 |
Sc | 9.48 | 4.95 | 1.34 | 1.63 | 18.13 |
Ti | 9.48 | 4.95 | 0.45 | 0.00 | 0.43 |
V | 9.48 | 0.00 | 0.00 | 0.00 | 1.29 |
Cr | 9.48 | 4.95 | 2.69 | 1.63 | 0.43 |
Mn | 9.48 | 0.00 | 0.90 | 0.41 | 0.43 |
Fe | 2976.69 | 2045.68 | 1399.80 | 1187.81 | 263.17 |
Co | 37.93 | 19.82 | 0.45 | 0.00 | 0.43 |
Ni | 85.35 | 49.55 | 4.48 | 5.70 | 0.00 |
Cu | 37.93 | 4.95 | 0.45 | 0.41 | 0.43 |
Zn | 37.93 | 9.91 | 1.79 | 3.66 | 8.63 |
Ga | 9.48 | 0.00 | 0.00 | 0.41 | 0.43 |
As | 9.48 | 0.00 | 0.45 | 0.41 | 5.18 |
Se | 18.97 | 4.95 | 2.69 | 2.44 | 58.69 |
Br | 85.35 | 29.73 | 14.77 | 12.61 | 444.09 |
Sr | 9.48 | 4.95 | 0.45 | 0.00 | 0.86 |
Ba | 28.45 | 24.77 | 6.71 | 2.03 | 10.36 |
Pb | 28.45 | 0.00 | 0.00 | 0.00 | 55.67 |
H2SO4 pH = 1 | 0.5 h | 1 h | 3 h | 6 h | 12 h | 24 h | 36 h | 48 h | |
---|---|---|---|---|---|---|---|---|---|
coarse particles (>2.0 μm) | FeT | 0.51 | 0.51 | 0.52 | 0.53 | 0.54 | 0.56 | 0.57 | 0.59 |
Fe2+ | 0.06 | 0.06 | 0.07 | 0.07 | 0.08 | 0.1 | 0.11 | 0.12 | |
Fe3+ | 0.45 | 0.45 | 0.45 | 0.46 | 0.46 | 0.46 | 0.46 | 0.47 | |
Fe2+/FeT | 0.12 | 0.12 | 0.13 | 0.13 | 0.15 | 0.18 | 0.19 | 0.20 | |
fine particles (1.1–2.0 μm) | FeT | 0.39 | 0.4 | 0.42 | 0.43 | 0.44 | 0.48 | 0.53 | 0.56 |
Fe2+ | 0.05 | 0.05 | 0.07 | 0.08 | 0.09 | 0.11 | 0.14 | 0.17 | |
Fe3+ | 0.34 | 0.35 | 0.35 | 0.35 | 0.35 | 0.37 | 0.39 | 0.39 | |
Fe2+/FeT | 0.13 | 0.13 | 0.17 | 0.19 | 0.20 | 0.23 | 0.26 | 0.30 | |
submicron particles (<1.1 μm) | FeT | 0.28 | 0.33 | 0.38 | 0.41 | 0.43 | 0.44 | 0.46 | 0.48 |
Fe2+ | 0.14 | 0.17 | 0.19 | 0.19 | 0.2 | 0.21 | 0.23 | 0.25 | |
Fe3+ | 0.14 | 0.16 | 0.19 | 0.22 | 0.23 | 0.23 | 0.23 | 0.23 | |
Fe2+/FeT | 0.50 | 0.52 | 0.50 | 0.46 | 0.47 | 0.48 | 0.50 | 0.52 |
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Lu, S.; Liu, J.; Hou, G.; Zhao, J.; Liu, X.; Xie, T.; Xiao, K.; Yonemochi, S.; Ebere, E.C.; Wang, W.; et al. Physicochemical Characterization and Oxidative Potential of Iron-Containing Particles Emitted from Xuanwei Coal Combustion. Toxics 2023, 11, 921. https://doi.org/10.3390/toxics11110921
Lu S, Liu J, Hou G, Zhao J, Liu X, Xie T, Xiao K, Yonemochi S, Ebere EC, Wang W, et al. Physicochemical Characterization and Oxidative Potential of Iron-Containing Particles Emitted from Xuanwei Coal Combustion. Toxics. 2023; 11(11):921. https://doi.org/10.3390/toxics11110921
Chicago/Turabian StyleLu, Senlin, Jin Liu, Guoqing Hou, Jiumei Zhao, Xinchun Liu, Tingting Xie, Kai Xiao, Shinichi Yonemochi, Enyoh Christian Ebere, Weiqian Wang, and et al. 2023. "Physicochemical Characterization and Oxidative Potential of Iron-Containing Particles Emitted from Xuanwei Coal Combustion" Toxics 11, no. 11: 921. https://doi.org/10.3390/toxics11110921