Surface Characterization of Bone-Level and Tissue-Level PEEK and Titanium Dental Implant Scan Bodies After Repeated Autoclave Sterilization Cycles
Abstract
:1. Introduction
2. Materials and Methods
2.1. Autoclave Sterilizaiton
2.2. Fourier Transform Infrared Spectroscopy
2.3. X-Ray Photo Electron Spectroscopy
2.4. Optical Profilometery
3. Results
3.1. FTIR
3.2. XPS
3.3. Surface Roughness
4. Discussion
5. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Material | PEEK | PEEK | Titanium | Titanium |
---|---|---|---|---|
Manufacturer | Straumann® Basel Switzerland | Straumann® Basel Switzerland | Straumann® Basel Switzerland | Straumann® Basel Switzerland |
Type | Tissue Level | Bone Level | Tissue Level | Bone Level |
Wavenumber (cm−1) | Spectral Changes and Identification |
---|---|
1741 | Fluorenone peak formation |
1277 and 1305 | Two bands pertaining to high frequency of the ether peak at 1219 cm−1 |
1100 | Alterations in the diphenyl ether bonds |
1185 | Disappearance of peak of diphenyl ether group |
837 | Changes in the aromatic rings |
926 | Increased intensity after sterilization |
Neat (Pristine) | 1st ST | |||
---|---|---|---|---|
Elements | Ti BL | Ti TL | Ti BL | Ti TL |
C1s | 284.66, (1.3), 76.66 | 284.67, (1.11), 79.67 | 284.63, (1.09), 77.02 | 284.67, (1.11), 79.67 |
O1s | 531.96, (1.76), 15.79 | 530.88, (1.61), 14.66 | 531.78, (1.89), 17.21 | 531.88, (1.61), 14.66 |
Si2p | 101.87, (1.64), 7.24 | 101.9, (1.49), 4.84 | 101.9, (1.52), 3.9 | 101.9, (1.49), 4.84 |
Zr3d | 183.5, (1.68), 0.31 | 182.58, (1.24), 0.83 | 182.26, (1.24), 1.87 | 182.58, (1.24), 0.83 |
Ca2p | - | - | - | - |
2nd ST | 3rd ST | |||
Ti BL | Ti TL | Ti BL | Ti TL | |
C1s | 284.62, (1.49), 71.03 | 284.6, (1.32), 79.28 | 284.62, (1.49), 81.95 | 284.60, (1.32), 79.28 |
O1s | 531.92, (1.87), 17.9 | 531.8, (1.71), 13.95 | 531.92, (1.87), 11.50 | 531.80, (1.71), 13.95 |
Si2p | 101.87, (1.79), 9.2 | 101.76, (1.57), 5.2 | 101.87, (1.79), 5.33 | 101.76, (1.57), 5.20 |
Zr3d | 182.84, (1.47), 0.53 | 182.84, (1.25), 0.22 | 182.84, (1.47), 0.53 | 182.84, (1.25), 0.22 |
Ca2p | 347.02, (2.06), 1.34 | 347.02, (1.6), 1.36 | 347.29, (2.06), 1.22 | 347.02, (1.60), 1.36 |
Neat (Pristine) | 1st ST | |||
---|---|---|---|---|
Elements | PK BL | PK TL | PK BL | PK TL |
C1s | 284.61, (1.11), 81.05 | 284.65, (1.1), 83.08 | 284.61, (1.11), 81.05 | 284.69, (1.04), 78.3 |
O1s | 531.6, (1.79), 13.15 | 531.69, (1.7), 12.56 | 531.6, (1.79), 13.15 | 1531.88, (1.71), 5.11 |
Si2p | 101.79, (1.55), 2.29 | 101.83, (1.36), 2.10 | 101.79, (1.55), 2.29 | 101.94, (1.39), 5.03 |
Na1s | 1071.29, (1.71), 0.75 | 1071.42, (1.73), 0.21 | 1071.29, (1.71), 0.75 | 1071.13, (1.26), 0.68 |
Ca2p | 347.04, (1.46), 1.59 | 347.12, (1.44), 1.78 | 347.04, (1.46), 1.59 | 347.02, (1.41), 0.87 |
Zn2p | 1021.7, (1.61), 0.39 | - | 284.61, (1.11), 81.05 | - |
2nd ST | 3rd ST | |||
PK BL | PK TL | PK BL | PK TL | |
C1s | 284.68, (1.28), 79.81 | 284.67, (1.14), 84.4 | 284.68, (1.28), 79.81 | 284.67, (1.1.4), 84.40 |
O1s | 531.98, (2.06), 15.83 | 531.61, (1.80), 11.56 | 531.98, (2.06), 15.83 | 531.61, (1.80), 11.56 |
Si2p | 102.03, (1.73), 2.36 | 101.86, (1.80), 1.9 | 102.03, (1.63), 2.36 | 101.86, (1.43), 1.90 |
Na1s | 1071.10, (1.73), 0.78 | 1071.22, (1.94), 0.73 | 1071.10, (1.73), 0.78 | 1071.22, (1.94), 0.73 |
Ca2p | 346.98, (1.68), 1.21 | 347.06, (1.53), 1.41 | 346.98, (1.68), 1.21 | 347.06, (1.53), 1.41 |
Zn2p | - | - | - | - |
T1 | T2 | T3 | T4 | |
---|---|---|---|---|
PK BL | 3.40 ± 1.00 | 3.16 ± 1.38 (0.70) | 3.66 ± 0.68 (0.43) | 1.71 ± 0.33 (0.006) |
PK TL | 3.52 ± 0.72 | 1.54 ± 0.56 (<0.001) | 1.48 ± 0.18 (<0.001) | 1.95 ± 0.68 (<0.001) |
Ti BL | 4.39 ± 0.80 | 4.46 ± 0.61 (0.83) | 3.97 ± 0.70 (0.36) | 1.67 ± 0.49 (<0.001) |
Ti TL | 2.64 ± 0.70 | 2.76 ± 0.51 (0.68) | 2.21 ± 0.62 (0.25) | 2.57 ± 0.32 (0.82) |
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Qasim, S.S.B.; Akbar, A.A.; Sadeqi, H.A.; Baig, M.R. Surface Characterization of Bone-Level and Tissue-Level PEEK and Titanium Dental Implant Scan Bodies After Repeated Autoclave Sterilization Cycles. Dent. J. 2024, 12, 392. https://doi.org/10.3390/dj12120392
Qasim SSB, Akbar AA, Sadeqi HA, Baig MR. Surface Characterization of Bone-Level and Tissue-Level PEEK and Titanium Dental Implant Scan Bodies After Repeated Autoclave Sterilization Cycles. Dentistry Journal. 2024; 12(12):392. https://doi.org/10.3390/dj12120392
Chicago/Turabian StyleQasim, Syed Saad Bin, Aqdar A. Akbar, Haneen A. Sadeqi, and Mirza Rustum Baig. 2024. "Surface Characterization of Bone-Level and Tissue-Level PEEK and Titanium Dental Implant Scan Bodies After Repeated Autoclave Sterilization Cycles" Dentistry Journal 12, no. 12: 392. https://doi.org/10.3390/dj12120392
APA StyleQasim, S. S. B., Akbar, A. A., Sadeqi, H. A., & Baig, M. R. (2024). Surface Characterization of Bone-Level and Tissue-Level PEEK and Titanium Dental Implant Scan Bodies After Repeated Autoclave Sterilization Cycles. Dentistry Journal, 12(12), 392. https://doi.org/10.3390/dj12120392