Adsorption Process and Properties Analyses of a Pure Magadiite and a Modified Magadiite on Rhodamine-B from an Aqueous Solution
Abstract
:- Intercalated CTAB-MAG was characterized by ion exchange;
- Adsorption kinetics were well fitted in pseudo second order model and adsorption processes were dominated by film diffusion process which belonged to monomolecular layer adsorption;
- Adsorption capacity on Rhodamine-B of CTAB-MAG (67.19 mg/g) was increased by 40% over MAG (48.13 mg/g).
1. Introduction
2. Experimental
2.1. Experimental Reagents
2.2. Measuring Instruments
2.3. Preparation of Sorbents.
2.4. Adsorption Performance Experiment
2.4.1. Effect of the Initial Concentration of Rh-B
2.4.2. Effect of Adsorption Time
2.4.3. Effect of pH
2.4.4. Effect of the Absorbent Dosage
3. Results and Discussion
3.1. Characterization of Adsorbents
3.1.1. XRD Analyses
3.1.2. FTIR Analyses
3.1.3. SEM Analysis
3.2. Adsorption Performance
3.2.1. Influencing Factors of the Adsorption Capacity
3.2.2. Isothermal Adsorption Experiment
3.2.3. Adsorption Kinetics Model
3.2.4. Adsorption Ratio Model
3.2.5. The Greater Adsorption Performance of CTAB-MAG
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Langumir Model | Freundlich Model | |||||
---|---|---|---|---|---|---|
KL | qm | R2 | KF | 1/n | R2 | |
MAG | 0.0476 | 69.44 | 0.99718 | 9.611 | 0.40486 | 0.98432 |
CTAB-MAG | 0.1321 | 85.11 | 0.99327 | 21.304 | 0.32086 | 0.98763 |
Pseudo-First-Order Kinetic Model | Pseudo-Second-Order Kinetic Model | Experiment | |||||
---|---|---|---|---|---|---|---|
K1 | qeqc | R2 | K2 | qeqc | R2 | qeqe | |
MAG | 0.0501 | 22.81 | 0.98817 | 0.00449 | 50.994 | 0.99937 | 49.07 |
CTAB-MAG | 0.0448 | 27.99 | 0.97913 | 0.00336 | 71.327 | 0.99949 | 68.82 |
Film Diffusion | Particle Diffusion | Chemical Reaction | ||||
---|---|---|---|---|---|---|
k | R2 | k | R2 | k | R2 | |
MAG | 0.051 | 0.988 | 0.009 | 0.909 | 0.006 | 0.934 |
CTAB-MAG | 0.045 | 0.979 | 0.008 | 0.887 | 0.006 | 0.911 |
Adsorbents | Conditions | Isotherms | Kinetics | Adsorption Capacity | References |
---|---|---|---|---|---|
CTAB-MAG | Ph = 7; dosage 1 g/L; Rh-B concentration 100 mg/L | Langmuir and Freundlich | pseudo-second-order | 67.19 mg/g | This work |
MAG | Ph = 7; dosage 1 g/L; Rh-B concentration 100 mg/L | Langmuirand Freundlich | pseudo-second-order | 48.13 mg/g | This work |
Kaolinite | Ph = 7; dosage 3 g/L; Rh-B concentration 90 mg/L | Langmuir | pseudo-second-order | 46.08 mg/g | [40] |
Sodium montmorillonite | Ph = 7; dosage 0.3 g/L; Rh-B concentration 200 mg/L | Langmuir | pseudo-second-order | 42.19 mg/g | [41] |
Duolite C-20 resin | Ph = 7; dosage 0.4 g/L; Rh-B concentration 8.129 mg/L | Langmuir and Freundlich | pseudo-first-order | 28.57 mg/g | [42] |
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Ge, M.; Xi, Z.; Zhu, C.; Liang, G.; Yang, Y.; Hu, G.; Jamal, L.; S.M., J.A. Adsorption Process and Properties Analyses of a Pure Magadiite and a Modified Magadiite on Rhodamine-B from an Aqueous Solution. Processes 2019, 7, 565. https://doi.org/10.3390/pr7090565
Ge M, Xi Z, Zhu C, Liang G, Yang Y, Hu G, Jamal L, S.M. JA. Adsorption Process and Properties Analyses of a Pure Magadiite and a Modified Magadiite on Rhodamine-B from an Aqueous Solution. Processes. 2019; 7(9):565. https://doi.org/10.3390/pr7090565
Chicago/Turabian StyleGe, Mingliang, Zhuangzhuang Xi, Caiping Zhu, Guodong Liang, Yinye Yang, Guoqing Hu, Lafifa Jamal, and Jahangir Alam S.M. 2019. "Adsorption Process and Properties Analyses of a Pure Magadiite and a Modified Magadiite on Rhodamine-B from an Aqueous Solution" Processes 7, no. 9: 565. https://doi.org/10.3390/pr7090565
APA StyleGe, M., Xi, Z., Zhu, C., Liang, G., Yang, Y., Hu, G., Jamal, L., & S.M., J. A. (2019). Adsorption Process and Properties Analyses of a Pure Magadiite and a Modified Magadiite on Rhodamine-B from an Aqueous Solution. Processes, 7(9), 565. https://doi.org/10.3390/pr7090565