Micellar Electrokinetic Chromatography with Laser-Induced Fluorescence Detection for Separation of Red and Yellow Historical Dyes
Abstract
:1. Introduction
2. Experimental Section
Reagents
3. Results and Discussion
3.1. Separation Properties
3.2. Detection Limits
pH = 9.240% ACN | pH = 9.255% ACN | pH = 8.00% ACN | ||||
---|---|---|---|---|---|---|
ng·mL−1 | pg | ng·mL−1 | pg | ng·mL−1 | pg | |
Alizarin | 14 | 0.2 | 39 | 0.9 | 70 | 2.4 |
Purpurin | ND | ND | ND | ND | 13 | 0.5 |
Emodin | 40 | 1.0 | 12 | 0.2 | 38 | 1.1 |
Kaempferol | 10 | 0.2 | 0.7 | 0.01 | 6.3 | 0.2 |
Apigenin | 23 | 0.4 | 9.0 | 0.2 | 20 | 0.5 |
Luteolin | 17 | 0.3 | 7.2 | 0.1 | 19 | 0.5 |
Carmine | ND | ND | 230 | 3.8 | 400 | 12 |
Myricetin | 51 | 0.9 | 15 | 0.2 | 5.7 | 0.2 |
Quercetin | 12 | 0.2 | 1.8 | 0.03 | 2.9 | 0.1 |
Morin | 9.0 | 0.1 | 0.7 | 0.01 | 2.4 | 0.1 |
3.3. Extraction of Natural Dyes in Field Samples
4. Conclusions
Acknowledgments
Conflict of Interest
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Ahmadi, S.; Craig, D.B.; Goltz, D.M. Micellar Electrokinetic Chromatography with Laser-Induced Fluorescence Detection for Separation of Red and Yellow Historical Dyes. Chromatography 2014, 1, 9-23. https://doi.org/10.3390/chromatography1010009
Ahmadi S, Craig DB, Goltz DM. Micellar Electrokinetic Chromatography with Laser-Induced Fluorescence Detection for Separation of Red and Yellow Historical Dyes. Chromatography. 2014; 1(1):9-23. https://doi.org/10.3390/chromatography1010009
Chicago/Turabian StyleAhmadi, Shokoufeh, Douglas B. Craig, and Douglas M. Goltz. 2014. "Micellar Electrokinetic Chromatography with Laser-Induced Fluorescence Detection for Separation of Red and Yellow Historical Dyes" Chromatography 1, no. 1: 9-23. https://doi.org/10.3390/chromatography1010009