Molecularly Imprinted Plasmonic Sensors as Nano-Transducers: An Effective Approach for Environmental Monitoring Applications
Abstract
:1. Introduction
2. History of Molecularly Imprinted Polymers (MIPs)
2.1. Molecularly Imprinted Polymers: A General Overview
2.2. The Concept of Producing Molecularly Imprinted Polymers
2.3. Organophosphate Pesticides and Environmental Pollution
3. Plasmonic Sensing with Molecular Imprinting Technology
3.1. Surface Plasmon Resonance and Surface-Enhanced Raman Spectroscopy MIP Sensors
3.2. Nanomaterial-Based Sensors for Environmental Monitoring
3.3. Nanoparticle MIPs (NanoMIPs) for Chemosensing of Environmental Pollutants
- (i)
- High specificity and enhanced affinity that has unparalleled recognition characteristics when coupled with a transducer.
- (ii)
- An intensely sensitive transducer for monitoring and processing the binding potential between the monomer and the imprinted cavities.
4. Conclusions and Outlook
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Analyte | Sample | Method | Sensing Layer/Substrate | LOD | References |
---|---|---|---|---|---|
Escherichia coli O157:H7 | Contaminated water | SPR | Antibody/Gold-coated thin glass | 1.0 × 105 CFU/mL | [65] |
Aflatoxin B1 | Peanuts | SPR | Antigen/Gold-coated thin glass | 0.2 ng/gr | [66] |
Fenthion | Milk | Chemiluminescence | MIP | 2.36 pg/mL | [35] |
Diazinon | Milk | Chemiluminescence | MIP | 4.6 pg/mL | [35] |
Paracetamol | Wastewater | SERS | MIP-AuNPs | 300 nM | [67] |
Atrazine | Drinking water | SPR | Silver MIP/Fiber optic core | 1.92 × 10−14 | [68] |
VOCs (1-octanol) | Organic compounds | SPRi | Biomimetic peptides/Gold-coated thin glass | 375 ppb | [43] |
Lead (II) ions | Wastewater | SPR | Silver-Cesium/Gold-coated thin glass | 30 ppb | [69] |
Carbendazim | Water | SERS | Ag-MIP | 1.0 × 10−9 M | [70] |
Parathion | Milk | Chemiluminescence | MIP | 1.14 pg/mL | [35] |
Fenitrothion | Milk | Chemiluminescence | MIP | 1.1 pg/mL | [35] |
Trinitrotoluene (TNT) | Soil/water | SPR | Gold MIP/Fiber optic core | 5.1 × 10−5 M | [71] |
Oxytetracycline | Fruits and vegetables | SPR | Silver MIP/Fiber optic core | 0.01 µM | [72] |
Caffeine | Wastewater | SERS | Silver MIP | 100 ng L−1 | [73] |
Ochratoxin A | Dried fig | SPR | MIP | 0.028 ng/mL | [74] |
Erythromycin | Vegetables | SPR | Silver MIP/Fiber optic core | 6.2 × 10−8 M | [75] |
Vitamin B3 | Fruits and vegetables | SPR | Silver MIP/Fiber optic core | 0.5 mg/mL | [76] |
Polycyclic aromatic hydrocarbons (PAH) | Sea water | SERS | MIP/Gold-coated thin glass | 1 nM | [77] |
Chlorpyrifos | Milk | Chemiluminescence | MIP | 2.14 pg/mL | [35] |
Copper (II) ions | Drinking water | SPR | CTA-NCC-GO/Gold-coated thin glass | 0.01 ppm | [78] |
Simetryn | Rice | SERS | GoldNPs-MIP | 0.05 mg/Kg | [79] |
Fenchlorphos | Milk | Chemiluminescence | MIP | 1.7 pg/mL | [35] |
Tetracycline | Vegetables | SPR/LSPR | Silver NP/MIP/Fiber optic core | 2.2 × 10−9 M | [80] |
Prometryn | Wheat | SERS | MIP-AuNPs | 0.05 mg/Kg | [79] |
Ochratoxin A | Wheat/wine | SPR | Polypyrrole (MIP) film | 0.01 mg/mL | [81] |
Coumaphos | Milk | Chemiluminescence | MIP | 1.8 pg/mL | [35] |
Orange II dye | Lake water | SERS | Ag-MIP | 10−10 M | [82] |
Chlorpyrifos | Apples | SPR | MIP Fe3O4-PDA NPs/Gold-coated thin glass | 0.76 nM | [83] |
Nicotine | Vegetables | SPR | Gold MIP/Fiber optic core PMMA | 1.86 pM | [84] |
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Ayivi, R.D.; Adesanmi, B.O.; McLamore, E.S.; Wei, J.; Obare, S.O. Molecularly Imprinted Plasmonic Sensors as Nano-Transducers: An Effective Approach for Environmental Monitoring Applications. Chemosensors 2023, 11, 203. https://doi.org/10.3390/chemosensors11030203
Ayivi RD, Adesanmi BO, McLamore ES, Wei J, Obare SO. Molecularly Imprinted Plasmonic Sensors as Nano-Transducers: An Effective Approach for Environmental Monitoring Applications. Chemosensors. 2023; 11(3):203. https://doi.org/10.3390/chemosensors11030203
Chicago/Turabian StyleAyivi, Raphael D., Bukola O. Adesanmi, Eric S. McLamore, Jianjun Wei, and Sherine O. Obare. 2023. "Molecularly Imprinted Plasmonic Sensors as Nano-Transducers: An Effective Approach for Environmental Monitoring Applications" Chemosensors 11, no. 3: 203. https://doi.org/10.3390/chemosensors11030203