Solution-Processed Efficient Nanocrystal Solar Cells Based on CdTe and CdS Nanocrystals
AbstractSolution-processed CdTe nanocrystals solar cells have attracted much attention due to their low cost, low material consumption, and potential for roll-to-roll production. Among all kinds of semiconductor materials, CdS exhibits the lowest lattice mismatch with CdTe, which permits high junction quality and high device performance. In this study, high quality CdS nanocrystals were prepared by a non-injection technique with tetraethylthiuram disufide and 2,2′-dithiobisbenzothiazole as the stabilizers. Based on the CdTe and CdS nanocrystals, devices with the architecture of ITO/ZnO/CdS/CdTe/MoOx/Au were fabricated successfully by a solution process under ambient condition. The effects of annealing conditions, film thickness, and detailed device structure on the CdTe/CdS nanocrystal solar cells were investigated and discussed in detail. We demonstrate that high junction quality can be obtained by using CdS nanocrystal thin film compared to traditional CdS film via chemical bath deposition (CBD). The best device had short circuit current density (Jsc), open circuit voltage (Voc) and fill factor (FF) of 17.26 mA/cm2, 0.56 V, and 52.84%, respectively, resulting in a power conversion efficiency (PCE) of 5.14%, which is significantly higher than that reported using CBD CdS as the window layer. This work provides important suggestions for the further improvement of efficiency in CdTe nanocrystal solar cells. View Full-Text
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Liu, S.; Liu, W.; Heng, J.; Zhou, W.; Chen, Y.; Wen, S.; Qin, D.; Hou, L.; Wang, D.; Xu, H. Solution-Processed Efficient Nanocrystal Solar Cells Based on CdTe and CdS Nanocrystals. Coatings 2018, 8, 26.
Liu S, Liu W, Heng J, Zhou W, Chen Y, Wen S, Qin D, Hou L, Wang D, Xu H. Solution-Processed Efficient Nanocrystal Solar Cells Based on CdTe and CdS Nanocrystals. Coatings. 2018; 8(1):26.Chicago/Turabian Style
Liu, Songwei; Liu, Weigeng; Heng, Jingxuan; Zhou, Wenfeng; Chen, Yanru; Wen, Shiya; Qin, Donghuan; Hou, Lintao; Wang, Dan; Xu, Hui. 2018. "Solution-Processed Efficient Nanocrystal Solar Cells Based on CdTe and CdS Nanocrystals." Coatings 8, no. 1: 26.
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