Acidic Mesoporous Zeolite ZSM-5 Supported Cu Catalyst with Good Catalytic Performance in the Hydroxysulfurization of Styrenes with Disulfides
Abstract
:1. Introduction
2. Experimental Section
2.1. Material Synthesis
2.2. Catalyst Preparation
2.3. Characterization
3. Results and Discussion
3.1. Catalyst Characterization
3.2. Catalytic Performance
4. Conclusions
Supplementary Materials
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Catalyst | Weak Acid Site (µmol·g−1) | Medium Acid Site (µmol·g−1) | Strong Acid Site (µmol·g−1) | Total Acid Site (µmol·g−1) |
---|---|---|---|---|
HZSM-5-M | 134 | 71 | 75 | 280 |
HZSM-5 | 282 | 110 | 106 | 498 |
Entry | Catalysts | Conversion (%) 3 | Selectivity (%) 4 | ||
---|---|---|---|---|---|
3a | 4 | 5 | |||
1 | - | 89 | 63 | 24 | 13 |
2 | HZSM-5-M | 91 | 79 | 15 | 16 |
3 | TS-1-M | 90 | 70 | 16 | 14 |
4 | HZSM-5 | 89 | 68 | 14 | 18 |
5 | Cu/HZSM-5-M | 92 | 85 | 10 | 5 |
6 | Fe/HZSM-5-M 2 | 89 | 65 | 21 | 14 |
7 | Co/HZSM-5-M 2 | 82 | 64 | 16 | 20 |
8 | Cu/HZSM-5 | 89 | 70 | 17 | 13 |
9 | Cu/ETS-10 | 71 | 66 | 22 | 12 |
10 | Cu/TS-1-M | 91 | 76 | 15 | 9 |
Entry | Recycle | Conversion (%) | Selectivity (%) |
---|---|---|---|
1 | Run 1 | 92 | 84 |
2 | Run 2 | 92 | 84 |
3 | Run 3 | 91 | 83 |
4 | Run 4 | 90 | 82 |
5 | Run 5 | 89 | 82 |
6 | Run 6 | 87 | 80 |
7 | Run 7 | 88 | 80 |
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Hu, J.; Zhu, C.; Xia, F.; Fang, Z.; Yang, F.; Weng, J.; Yao, P.; Zheng, C.; Dong, H.; Fu, W. Acidic Mesoporous Zeolite ZSM-5 Supported Cu Catalyst with Good Catalytic Performance in the Hydroxysulfurization of Styrenes with Disulfides. Nanomaterials 2017, 7, 459. https://doi.org/10.3390/nano7120459
Hu J, Zhu C, Xia F, Fang Z, Yang F, Weng J, Yao P, Zheng C, Dong H, Fu W. Acidic Mesoporous Zeolite ZSM-5 Supported Cu Catalyst with Good Catalytic Performance in the Hydroxysulfurization of Styrenes with Disulfides. Nanomaterials. 2017; 7(12):459. https://doi.org/10.3390/nano7120459
Chicago/Turabian StyleHu, Jun, Chaojie Zhu, Feifei Xia, Zhongxue Fang, Fengli Yang, Jushi Weng, Pengfei Yao, Chunzhi Zheng, Hai Dong, and Wenqian Fu. 2017. "Acidic Mesoporous Zeolite ZSM-5 Supported Cu Catalyst with Good Catalytic Performance in the Hydroxysulfurization of Styrenes with Disulfides" Nanomaterials 7, no. 12: 459. https://doi.org/10.3390/nano7120459