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Membranes 2017, 7(2), 25;

Polymer Electrolyte Membranes for Water Photo-Electrolysis

CNR-ITAE Institute for Advanced Energy Technologies “N. Giordano”, Via Salita S. Lucia sopra Contesse 5, 98126 Messina, Italy
FUMATECH BWT GmbH Gesellschaft für Funktionelle Membranen und Anlagentechnologie mbH, Carl-Benz-Strasse 4, Bietigheim-Bissingen, D-74321 Baden-Württemberg, Germany
Author to whom correspondence should be addressed.
Academic Editor: Tongwen Xu
Received: 22 December 2016 / Revised: 9 April 2017 / Accepted: 25 April 2017 / Published: 29 April 2017
(This article belongs to the Special Issue Feature Papers)
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Water-fed photo-electrolysis cells equipped with perfluorosulfonic acid (Nafion® 115) and quaternary ammonium-based (Fumatech® FAA3) ion exchange membranes as separator for hydrogen and oxygen evolution reactions were investigated. Protonic or anionic ionomer dispersions were deposited on the electrodes to extend the interface with the electrolyte. The photo-anode consisted of a large band-gap Ti-oxide semiconductor. The effect of membrane characteristics on the photo-electrochemical conversion of solar energy was investigated for photo-voltage-driven electrolysis cells. Photo-electrolysis cells were also studied for operation under electrical bias-assisted mode. The pH of the membrane/ionomer had a paramount effect on the photo-electrolytic conversion. The anionic membrane showed enhanced performance compared to the Nafion®-based cell when just TiO2 anatase was used as photo-anode. This was associated with better oxygen evolution kinetics in alkaline conditions compared to acidic environment. However, oxygen evolution kinetics in acidic conditions were significantly enhanced by using a Ti sub-oxide as surface promoter in order to facilitate the adsorption of OH species as precursors of oxygen evolution. However, the same surface promoter appeared to inhibit oxygen evolution in an alkaline environment probably as a consequence of the strong adsorption of OH species on the surface under such conditions. These results show that a proper combination of photo-anode and polymer electrolyte membrane is essential to maximize photo-electrolytic conversion. View Full-Text
Keywords: anion exchange polymer electrolyte membrane; proton exchange polymer electrolyte membrane; water splitting; photo-electrolysis; TiO2; Ti-suboxides anion exchange polymer electrolyte membrane; proton exchange polymer electrolyte membrane; water splitting; photo-electrolysis; TiO2; Ti-suboxides

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Aricò, A.S.; Girolamo, M.; Siracusano, S.; Sebastian, D.; Baglio, V.; Schuster, M. Polymer Electrolyte Membranes for Water Photo-Electrolysis. Membranes 2017, 7, 25.

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