1. Introduction
Nanotechnology is the manipulation of matter on a near-atomic scale to produce new structures, materials, and devices. This technology promises scientific advancement in many sectors such as medicine, consumer products, energy, materials, and manufacturing. Thus, nanotechnology involves understanding and controlling matter at the nanometer scale. The so-called nanoscale deals with dimensions between approximately 1 and 100 nanometers. As a result, nanomaterials are the foundation of nanotechnology.
Nobel laureate Richard P. Feynman was the first to speak about nanotechnology in 1959 during his famous lecture “There’s Plenty of Room at the Bottom” [
1]. Since then, a revolution in this field has taken place, demonstrating Feynman’s ideas of manipulating matter at the nanoscale.
Nanomaterials show a distinct state of matter from the normally referred to states (solid, liquid, or gaseous state). Materials exhibit unique properties at the nanoscale that affect physical, chemical, and biological behavior. Quantum effects, surface effects, and confinement of electrons cause these properties and change the conductivity, reactivity, strength, and optical behavior of materials. The incorporation of nanoparticles into materials to create tailored properties is possible because nanotechnology allows for the modification of nanoparticles at the atomic and molecular levels [
2].
Because of the versatility of nanotechnology, nanotech innovations influence many areas, including the construction industry, where nanotechnology represents a major opportunity to develop more sustainable materials for buildings and other constructions. Currently, there is a rapidly growing interest in using nanotechnology in concrete products to reduce their environmental impact, improve their sustainability, and mitigate climate change [
3,
4].
In this context, the tremendous potential of nanoparticles as nano-additives to concrete technology has been demonstrated. Nanoparticles have a very large specific surface area relative to their size. So, the incorporation of small quantities, less than 5 wt%, causes significant changes in the properties of concretes. In general, mechanical properties and durability have been enhanced using ultrafine size nanoparticles (<100 nm) with a very large specific surface area (SSA) [
5]. The following three strategies were proposed to modify the regular properties of cement-based material:
Nanoparticles provide a seeding surface for the deposition of hydrates and therefore facilitate the hydration of OPC and mineral admixtures.
Nano-SiO2 and other nano-clays increase pozzolanic reactivity, thus increasing the production of cementitious phases, most notably, C-S-H.
Nanoparticles fill gaps among larger particles and modify nano and micro-scale density.
There are also limitations in the use of nanoparticles in cement-based materials. The main limitations are the following:
The high cost of nanoparticles in comparison with other concrete components.
Changes in the flowability and set times of OPC products, although this may be a benefit in some applications.
High variability in OPC products with nanoparticles.
In general terms, wide-range variability has been appreciated in the incorporation of nanoparticles into cement-based material [
5].
Nano-SiO
2 is strongly recommended for several applications because it improves early strength, reduces porosity, and enhances the corrosion resistance of modified concrete composites [
6]. Most mixed cement-based materials with nanoparticles enhance strength performance, but it was seen that high percentages of nanoparticles may negatively affect the mechanical properties and durability of concrete. These inconveniences were associated with the difficulty of dispersion and the formation of weak spots in the matrix [
6]. Previous works revealed that the careful use of nanoparticles as additives may be a novel strategy to enhance the micro- and nano-scale structure of cement-based materials. So, more deep research works are needed to develop a clear understanding of the effect of nanoparticles on OPC materials [
5,
6].
Some studies provide results indicating the performance of cement-based materials using nano-Al
2O
3. Diffusivity and permeability are lower than control mixtures with no additives. The compressive strength of mixtures with nano-alumina at 28 days is also discussed. Nano-Al
2O
3 improves the contact structure in the interface between cement, creating a stronger bond and reducing cracks [
7]. Other research works report that nano-Al
2O
3 modifies the concrete microstructure, mainly the pore structure and interstitial transition zone, increasing the modulus of elasticity and improving compressive and bending strength [
8].
The single and combined effects of nanoparticles on cement-based materials were also analyzed by other authors [
9]. It was seen that the amount and type of nanoparticles had a significant influence on the fresh and hardened cement mortars studied. The combination of nanoparticles had negative effects on the physical and mechanical properties of the mortars.
Titanium oxide (TiO
2) nanoparticles are well known as a good additive to improve building sustainability and are widely used nano-additives in cement-based materials. Titanium oxide (TiO
2) nanoparticles exist in three different polymorphs including rutile, anatase, and brookite. Rutile and anatase are commonly used in the construction industry among other industries. Their effect is mainly related to the acceleration of the hydration process, an improvement in resistance, self-cleaning properties, and CO
2 uptake [
10,
11].
In this context, several novel nanomaterials have been explored as good additives to improve building sustainability, including nano-ZnO. Nano-ZnO is a by-product material from the zinc manufacturing industry. It is identified as a promising material because of its unique properties such as low cost, environmental benefits, and photocatalytic performance. Thus, some studies show that the incorporation of ZnO resulted in the contrary effect of a remarkable delay in the hydration process [
12,
13]. Nano-ZnO has a wide range of applications such as in chemical sensors, the biomedical sector, solar cells, photocatalysis, and the construction field [
14]. Recent research has assessed the effect of ZnO on High-Performance Concrete (HPC) [
15], concrete block pavements [
12], and alkali-activated slag (AAS) [
16].
In the construction industry, nano-ZnO has been assessed as a suitable alternative to TiO
2, although a few studies have compared the effectiveness of ZnO and TiO
2 [
5,
15,
17]. Both nanoparticles, individually and combined, are used as nano-additives to enhance photocatalytic properties [
15]. Previous studies reported the effect of ZnO nanoparticles on the hydration of Portland cement [
15,
17]. Even a very low percentage of ZnO incorporation retards the hydration of cement by forming other compounds such as Zn(OH)
2 or Zn
2Ca(OH)
6·H
2O. The formation of Zn(OH)
2 is responsible for the hydration delay and an increment in pH at the initial setting time of regular concrete [
18] Zn(OH)
3− and Zn(OH)
42− do not influence cement hydration, but they contribute to forming Zn silicate, which is transformed into calcium zincate. Tests on normal concrete using ordinary Portland cement (OPC) incorporating percentages of 1% and 3% of ZnO showed a reduction of 30% in compressive strength [
19]. However, it was seen that ZnO increased the durability of concrete in marine environments with high Cl
− concentrations [
18].
Recent research studies have analyzed the influence of small additions of ZnO nanoparticles in the mechanical properties of cement-based materials [
5,
18,
20]. However, to the knowledge of the authors, there are no studies about the effect of ZnO nanoparticles on lightweight concrete (LWC).
LWC is an adequate material to improve the sustainability of the construction industry because of its versatile properties (density below 2000 kg/m
3, porosity, recyclability, etc.) [
21]. LWC use has been of great interest in recent years for many structures, such as off-shore structures, bridges, and large building roofs [
22]. So, the lightness of LWC and its thermal properties make it an excellent solution for creating more sustainable materials and dealing with climate change [
23]. The lightness of LWC reduces gas emissions from transportation, material extraction, civil construction, and building processes (auxiliary systems for building and supporting) [
23]. The great thermal performance of LWC makes it a suitable material for energy-efficient solutions in buildings. Although LWC presents eco-friendly advantages, its environmental benefits may be enhanced by using nanotechnology, and for this, it is necessary to increase our understanding by analyzing the effect of small additions of ZnO nanoparticles. The broader scope of this research is to study the effect of ZnO nanoparticles on the performance of lightweight concrete to determine its applicability in sustainable construction and more resilient infrastructures. Other authors have studied the effect of nano-SiO
2 on the performance of lightweight concrete [
24]. However, the assessment of the performance of LWC with ZnO nanoparticles is still outstanding.
Key factors to successfully incorporate ZnO nanoparticles into LWC are the incorporation method, the manufacturing process, and the effect of ZnO nanoparticles on the compressive strength of LWC.
This work designs new types of lightweight concrete (LWC) by incorporating nano-ZnO in two ways, as an additive and as a substitute for cement. The effect of ZnO incorporation in the curing process and mechanical properties is assessed.
Samples with four different percentages of ZnO additives were tested to evaluate the influence of nanoparticles on the compressive strength of the LWC. Scanning electron microscopy (SEM) coupled with energy-dispersive X-ray spectroscopy (EDX) was used to characterize the LWC morphologically. The incorporation of ZnO nanoparticles into lightweight concrete has a direct effect on its mechanical behavior. This study reveals that an increase in the percentage of ZnO nanoparticles as a substitute for cement significantly decreases the compressive strength of lightweight concrete. However, the behavior is different for mixtures where ZnO nanoparticles are incorporated by the addition method. The use of these nanoparticles as additives in LWC leads to very similar compressive strengths for percentages of ZnO from 0.5 to 1.5 wt%. Although the compressive strength of the LWC is 10% lower than that of regular structural LWC, its resistance is stabilized for specific amounts of ZnO nanoparticles incorporated by the addition method. The conclusions show that different ways of incorporating nanoparticles may result in different mechanical responses for percentages of ZnO from 0 to 2 wt%.