Excellent Performance of Fe78Si9B13 Metallic Glass for Activating Peroxymonosulfate in Degradation of Naphthol Green B
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials and Chemicals
2.2. Methods
3. Results and Discussion
3.1. Characterizations of Fe78Si9B13
3.2. UV–Vis Spectra
3.3. Single Parameter Effect on Dye Degradation
3.3.1. Effect of PMS Concentration
3.3.2. Effect of Fe78Si9B13 Dosage
3.3.3. Effect of Irradiation Intensity
3.3.4. Effect of Dye Concentration
3.3.5. Stability and Reusability
4. Conclusions
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Structure | Empirical Formula | Molar Mass (g/mol) | λmax (nm) |
---|---|---|---|
C30H15FeN3Na3O15S3 | 878.45 | 714 |
Method | Material | Dosage (g/L) | Light Source | Complete Removal Time (min) | kobs (min−1) | Reference |
---|---|---|---|---|---|---|
Photocatalysis | 10% Al-doped ZnO particles | 1.0 | Solar light | 360 | 5.95 × 10−3 | [45] |
Photocatalysis | Semiconducting Sb2S3 | 2.0 | Visible light | 60 | 5.37 × 10−2 | [46] |
Photo-Fenton process | FeCl3 | 0.11 | Visible light | >20 | 1.01 × 10−1 | [48] |
Photo-enhanced sulfate-based oxidation | Fe78Si9B13 ribbons | 0.5 | UV–vis light | 10 | 3.14 × 10−1 | This work |
PMS Concentration (mmol/L) | Color Removal (%) at 4 min | Color Removal (%) at 8 min | Reaction Kinetics k (min−1) | R2 |
---|---|---|---|---|
0 | 3.2 | 3.9 | 0.004 | 0.9854 |
0.1 | 14.56 | 40.6 | 0.0557 | 0.9921 |
0.25 | 34.7 | 69.5 | 0.1526 | 0.9904 |
0.5 | 57.6 | 87.9 | 0.2654 | 0.9958 |
1.0 | 65.7 | 91.4 | 0.3140 | 0.9980 |
2.0 | 69.8 | 94.2 | 0.3509 | 0.9948 |
Dosage (g/L) | Color Removal (%) at 4 min | Color Removal (%) at 8 min | Reaction Kinetics k (min−1) | R2 |
---|---|---|---|---|
0 | 34.5 | 70.0 | 0.1489 | 0.9937 |
0.3 | 64.0 | 89.1 | 0.3011 | 0.9995 |
0.5 | 65.7 | 91.4 | 0.3140 | 0.9980 |
1.0 | 75.7 | 94.5 | 0.4357 | 0.9907 |
2.0 | 81.6 | 93.0 | 0.4691 | 0.9984 |
Irradiation Intensity (μW/cm2) | Color Removal (%) at 4 min | Color Removal (%) at 8 min | Reaction Kinetics k (min−1) | R2 |
---|---|---|---|---|
0.0 | 28.7 | 50.1 | 0.0816 | 0.9989 |
7.7 | 65.7 | 91.4 | 0.2736 | 0.9980 |
11.1 | 74.7 | 93.9 | 0.314 | 0.9950 |
14.8 | 87.7 | 95.4 | 0.5247 | 0.9947 |
NGB Concentration (ppm) | Color Removal (%) at 4 min | Color Removal (%) at 8 min | Reaction Kinetics k (min−1) | R2 |
---|---|---|---|---|
10 | 84.3 | 94.3 | 0.4566 | 0.9922 |
20 | 73.8 | 94.2 | 0.3841 | 0.9987 |
50 | 65.7 | 91.4 | 0.3140 | 0.9980 |
100 | 48.3 | 82.5 | 0.2032 | 0.9875 |
Reused Times | Color Removal (%) at 4 min | Color Removal (%) at 8 min | Reaction Kinetics k (min−1) | R2 |
---|---|---|---|---|
first run | 65.7 | 92.1 | 0.3170 | 0.9963 |
third run | 62.7 | 90.1 | 0.2913 | 0.9933 |
fifth run | 60.2 | 89.8 | 0.2811 | 0.9925 |
tenth run | 58.6 | 89.4 | 0.2708 | 0.9946 |
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Li, X.-F.; Liang, S.-X.; Xi, X.-W.; Jia, Z.; Xie, S.-K.; Lin, H.-C.; Hu, J.-P.; Zhang, L.-C. Excellent Performance of Fe78Si9B13 Metallic Glass for Activating Peroxymonosulfate in Degradation of Naphthol Green B. Metals 2017, 7, 273. https://doi.org/10.3390/met7070273
Li X-F, Liang S-X, Xi X-W, Jia Z, Xie S-K, Lin H-C, Hu J-P, Zhang L-C. Excellent Performance of Fe78Si9B13 Metallic Glass for Activating Peroxymonosulfate in Degradation of Naphthol Green B. Metals. 2017; 7(7):273. https://doi.org/10.3390/met7070273
Chicago/Turabian StyleLi, Xue-Fen, Shun-Xing Liang, Xiao-Wang Xi, Zhe Jia, Shi-Kun Xie, He-Chun Lin, Jun-Ping Hu, and Lai-Chang Zhang. 2017. "Excellent Performance of Fe78Si9B13 Metallic Glass for Activating Peroxymonosulfate in Degradation of Naphthol Green B" Metals 7, no. 7: 273. https://doi.org/10.3390/met7070273