Enhanced Surface Precipitates on Ultrafine-Grained Titanium in Physiological Solution
Abstract
:1. Introduction
2. Materials and Methods
3. Results
3.1. Microstructure
3.2. Electrochemical Impedance Spectroscopy (EIS) Results
3.3. Response to Soaking
4. Discussion
5. Conclusions
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Specimen Types | Rs (Ω·cm2) | Q (Ω−1·cm−2·sn) | n | Rt (Ω·cm2) | σ (Ω−1·cm−2·s0.5) |
---|---|---|---|---|---|
FC | 21.82 + 2.27/−4.17 | (5.54 + 2.34/−1.28) × 10−5 | 0.863 + 0.034/−0.035 | 1201.13 + 467.9/−45.5 | 0.0063 + 0.0019/−0.0021 |
WQ | 25.19 + 2.66/−3.39 | (4.42 + 3.04/−2.12) × 10−5 | 0.882 + 0.048/−0.054 | 4452.0 + 664/−157 | 0.0049 + 0.0012/−0.0020 |
ECAP | 21.5 ± 5.93 | (7.85 ± 1.07) × 10−5 | 0.773 ± 0.019 | 6043.5 ± 733.5 | - |
Sample | O 1s | Ti 2p | Ca 2p | P 2p | N 1s |
---|---|---|---|---|---|
ECAP | 36.2 | 20.3 | 0.5 | 1.0 | 1.6 |
FC | 31.2 | 17.5 | 0.5 | 0.4 | 1.7 |
WQ | 22.2 | 17.2 | <0.1 | <0.1 | 4.3 |
Specimens | Measured Places | O | Ti | P | Ca | Ca:P |
---|---|---|---|---|---|---|
ECAP-1 * | Matrix | 13.72 | 74.18 | 0.152 | 0 | - |
Dark particle | 16.08 | 55.66 | 0.127 | 0.016 | 1:7.7 | |
ECAP-2 | Matrix | 12.34 | 72.18 | 0 | 0.019 | - |
Dark particle 1 | 17.55 | 46.86 | 0.076 | 0.015 | 1:5.2 | |
Dark particle 2 | 13.73 | 54.24 | 0.114 | 0.024 | 1:4.7 | |
FC-1 | Matrix | 3.49 | 92.54 | 0.015 | 0.023 | 1:0.6 |
Light particle | 12.84 | 58.83 | 0.295 | 0.441 | 1:0.7 | |
Dark particle | 8.01 | 61.89 | 0.033 | 0.043 | 1:0.8 | |
FC-2 | Matrix | 4.27 | 91.00 | 0.116 | 0 | - |
Light particle | 53.40 | 9.29 | 0 | 0 | - | |
Dark particle | 6.28 | 78.04 | 0.026 | 0 | - | |
WQ-1 | Matrix | 4.36 | 82.86 | 0.068 | 0 | - |
Light particle | 37.88 | 16.36 | 0.081 | 0.070 | 1:1.2 | |
WQ-2 | Matrix | 4.00 | 91.44 | 0.145 | 0 | - |
Dark particle 1 | 6.18 | 81.33 | 0.147 | 0 | - | |
Dark particle 2 | 3.61 | 90.37 | 0.187 | 0 | - |
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Zhou, Q.; Wang, L.; Zou, C.-H. Enhanced Surface Precipitates on Ultrafine-Grained Titanium in Physiological Solution. Metals 2017, 7, 245. https://doi.org/10.3390/met7070245
Zhou Q, Wang L, Zou C-H. Enhanced Surface Precipitates on Ultrafine-Grained Titanium in Physiological Solution. Metals. 2017; 7(7):245. https://doi.org/10.3390/met7070245
Chicago/Turabian StyleZhou, Qing, Lei Wang, and Cheng-Hong Zou. 2017. "Enhanced Surface Precipitates on Ultrafine-Grained Titanium in Physiological Solution" Metals 7, no. 7: 245. https://doi.org/10.3390/met7070245