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Article

Study of Organosolv Lignins as Adhesives in Wood Panel Production

Centre de recherche de sur les Matériaux renouvelables, Département des Sciences du bois et de la forêt, Université Laval, Québec, QC 7337, Canada
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Academic Editor: Antonio Pizzi
Polymers 2017, 9(2), 46; https://doi.org/10.3390/polym9020046
Received: 30 December 2016 / Revised: 20 January 2017 / Accepted: 26 January 2017 / Published: 29 January 2017
(This article belongs to the Special Issue Renewable Polymeric Adhesives)
Organosolv lignins obtained from sugar maple bark and wood were studied as adhesives for wood particleboard production. Organosolv pulping of sugar maple wood and bark was carried out in the presence of Lewis acid FeCl3 as a catalyst. The organosolv lignins recovered from this process were investigated by determination of Klason plus acid-soluble lignin content, of sugars by HPLC analysis, and of ash content. Structural characterizations of these lignins were performed by Fourier-transform infrared (FT-IR) and by 31P NMR. The results of the latter studies indicate that the content of free phenolic groups was more important in bark than in wood lignin. The gel permeation chromatography (GPC) analyses results suggested that the weight-average molecular mass of wood lignin was higher than that of bark lignin. The studied organosolv lignins were used for the preparation of particleboards as recovered and in combination with glyoxal or isocyanate. It was found that sugar maple bark lignin, as such or modified with isocyanate, was a more efficient adhesive than its wood counterpart. On the contrary, it was the organosolv wood lignin combined with glyoxal which was a more efficient adhesive than its bark counterpart. In combination with isocyanate, it was the sugar maple bark organosolv lignin which was determined to have the best adhesive performance of all studied lignins. View Full-Text
Keywords: organosolv lignin; sugar maple bark and wood; adhesive performance organosolv lignin; sugar maple bark and wood; adhesive performance
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MDPI and ACS Style

Koumba-Yoya, G.; Stevanovic, T. Study of Organosolv Lignins as Adhesives in Wood Panel Production. Polymers 2017, 9, 46. https://doi.org/10.3390/polym9020046

AMA Style

Koumba-Yoya G, Stevanovic T. Study of Organosolv Lignins as Adhesives in Wood Panel Production. Polymers. 2017; 9(2):46. https://doi.org/10.3390/polym9020046

Chicago/Turabian Style

Koumba-Yoya, Georges, and Tatjana Stevanovic. 2017. "Study of Organosolv Lignins as Adhesives in Wood Panel Production" Polymers 9, no. 2: 46. https://doi.org/10.3390/polym9020046

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