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Article

Holographic Lens Resolution Using the Convolution Theorem

by
Tomás Lloret
1,*,
Marta Morales-Vidal
2,
Víctor Navarro-Fuster
3,
Manuel G. Ramírez
2,3,
Augusto Beléndez
2,3 and
Inmaculada Pascual
1,2
1
Departamento de Óptica, Farmacología y Anatomía, Universidad de Alicante, Carretera San Vicente del Raspeig s/n, 03690 San Vicente del Raspeig, Spain
2
Instituto Universitario de Física Aplicada a las Ciencias y las Tecnologías, Universidad de Alicante, Carretera San Vicente del Raspeig s/n, 03690 San Vicente del Raspeig, Spain
3
Departamento de Física, Ingeniería de Sistemas y Teoría de la Señal, Universidad de Alicante, Carretera San Vicente del Raspeig s/n, 03690 San Vicente del Raspeig, Spain
*
Author to whom correspondence should be addressed.
Polymers 2022, 14(24), 5426; https://doi.org/10.3390/polym14245426
Submission received: 16 November 2022 / Revised: 7 December 2022 / Accepted: 8 December 2022 / Published: 11 December 2022
(This article belongs to the Section Polymer Applications)

Abstract

:
The similarity between object and image of negative asymmetrical holographic lenses (HLs) stored in a low-toxicity photopolymer has been evaluated theoretically and experimentally. Asymmetrical experimental setups with negative focal lengths have been used to obtain HLs. For this purpose, the resolution of the HLs was calculated using the convolution theorem. A USAF 1951 test was used as an object and the impulse responses of the HLs, which in this case was the amplitude spread function (ASF), were obtained with two different methods: using a CCD sensor and a Hartmann Shack (HS) wavefront sensor. For a negative asymmetrically recorded HL a maximum resolution of 11.31 lp/mm was obtained. It was evaluated at 473 nm wavelength. A theoretical study of object-image similarity had carried out using the MSE (mean squared error) metric to evaluate the experimental results obtained quantitatively.

1. Introduction

Holography is a three-dimensional image reconstruction technique based on Gabor’s principle named Wavefront reconstruction [1]. It is an extremely intriguing approach that enables the information to be recorded in a recording medium and has advanced significantly as a result of enhancements made to holographic recording mediums as photopolymers [2].
Holographic optical elements (HOEs) are one of the most significant holographic applications [3,4]. HOEs are crucial because they can supersede complex, heavy, and curved refractive optical elements with a straightforward, lightweight, and flat element. Two coherent beams that are spatially overlapping each other form an interference pattern, which HOEs store. This pattern produces a photonic structure that can bend light in the desired direction.
Denisyuk first proposed the idea of a holographic mirror as a holographic HOE concept in 1962 [5]. With the advantages of achieving high optical power on a tiny substrate, a HOE may turn a hitting optical beam like a traditional lens [6]. Additionally, due to the element’s simplicity in coupling for any type of manipulation and the ability to multiplex two or more HOEs, a variety of functionalities can be gathered on a single substrate in accordance with its properties of high diffraction efficiency and narrow-band frequency [7,8]. Filters, credit cards, displays, couplers, projection systems, and storage all utilise HOEs as basic optical components [9,10,11,12,13]. Holographic lenses (HLs) have changed as several industries, including communications, photonics, and information processing, have progressed. HLs are now a component of optical imaging systems that are mostly used in head-mounted displays for virtual and augmented reality [14,15,16,17,18] or as non-image systems in light deflectors and concentrators [19,20,21,22,23,24].
In these applications, the optical and image quality of HLs is very important. For this purpose, some authors have studied the resolution of HLs using the modulation transfer function (MTF) [25,26], the Fourier transform [27,28] or the study of some quality metrics [29,30]. The MTF does not provide complete information on the HLs resolution, as it only provides information on the cut-off frequency in a region of the image. For that reason, studying the convolution of an object resolution test with the impulse response of the HLs is a good option to not lose part of the information.
The main points of this applicability are the new recording materials, which can perform in the most specific situations and applications. The manufacturing of HOEs typically involves the use of a variety of materials, including silver halide emulsion [31,32], dichromate gelatine [33,34], photoresist [35,36], photorefractive [12,37], or photopolymer [38]. In 1969, Close et al., employed photopolymers for the first time as holographic optical components [39]. Since then, a wide variety of photopolymer compounds has been developed for optical applications [40]. This is primarily because of their adaptability in terms of composition and design, in addition to other intriguing qualities like self-processing ability [41], affordability, variable thickness, good dimensional stability, high energy sensitivity, sharp angular selectivity, wide dynamic range, and flexibility. The significance of photopolymers in this context is expanding quickly [42].
However, routinely used hydrophilic photopolymers also include gelatin binders, poly(vinyl alcohol), and similar monomers [43,44,45,46]. Certain of these photopolymers’ unfavourable traits include the toxicity of some of their constituent parts; for instance, acrylamide has a high propensity to cause cancer. Recent developments in photopolymers reduce this issue by using low-toxicity materials [47,48,49] instead of conventional solvents to enhance environmental compatibility [50,51]. Such materials also offer good recycling qualities. In order to serve as a holographic recording material in optical applications, we developed Biophotopol, a low-toxicity photopolymer [52,53,54].
In this work, we have studied the resolution of HLs recorded on a low-toxicity recording photopolymer in asymmetrical recordings and with negative focal length. In previous papers we obtained the best quality results for negative asymmetric HLs [19,26,30]. We have obtained the convolution between the impulse response, obtained from a CCD sensor and an HS wavefront sensor, and a USAF object test. The resolution obtained directly experimentally with the CCD sensor has also been calculated.

2. Materials and Methods

2.1. Recording Material Composition

Volume phase transmission HLs were recorded in a Biophotopol photopolymer, a low-toxicity hydrophilic material made-up of one or more monomers in a binder, an electron donor, and a dye sensitizer. In earlier works, the component concentrations of Biophotopol have been thoroughly investigated [52,53,54] to make up optimal photopolymer layers with good optical responses for storing holographic lenses. Biophotopol composition was developed using sodium acrylate (NaAO) as the monomer (NaAO was generated in situ through a reaction of acrylic acid (HAO) with sodium hydroxide (NaOH) in a 1:1 proportion), water as a unique solvent, triethanolamine (TEA) serving as the initiator and plasticizer, riboflavin 5’-monophosphate sodium salt (RF) serves as a dye, and polyvinyl alcohol (PVA) as a binder (Mw = 130,000 g/mol, hydrolysis grade = 87.7%). All compounds were purchased from Sigma-Aldrich Quimica SL (Madrid, Spain). Figure 1 shows the Biophotopol chemical structures of the prepolymer components.
The optimized Biophotopol photopolymer’s component concentrations adequate to produce layers with the highest possible diffraction efficiency are shown in Table 1. The prepolymer solution was deposited in square glass moulds 6.5 × 6.5 cm 2 (which have been previously washed and dried) by the force of gravity and left in dark inside an incubator (Climacell 111, Labexchange, Burladingen, Germany) for roughly 24 h at a controlled relative humidity, 60 ± 5 % and a temperature = 20 ± 1 °C. The procedure was also carried out in a controlled light environment in which the photopolymer layer was not sensitive. During the drying period, some of the water evaporated until it reached equilibrium with the surrounding environment inside the incubator. An ultrasonic pulse-echo gauge (PosiTector 200, DeFelsko, Ogdensburg, NY, USA) was used to measure the physical thickness of the photopolymer dry layer obtaining a 200 μ m thickness. The layers were now prepared for recording, which was started immediately.
We would like to point out that considering the capacity of TEA to form an H-bond with water, the low content of TEA made it more difficult for the NaAO to dissolve, stimulating crystallization during the drying process. The environmental conditions during the recording stage had to be controlled to avoid precipitation of NaAO on the surface of the photopolymer layer. Also, the permeability of PVA played an important role in the drying and recording stages. Therefore, the control of humidity, temperature, and TEA/water ratio in the dry layer with respect to the thickness and final composition of the photopolymer layer was very important to obtain high diffraction efficiency.
Not all of the dye in the photopolymer layer is used once the gratings are recorded, the dye remains in the unexposed zones and if the hologram is subjected to incoherent light, the reaction continues in these unexposed zones provoking the grating loss. Removing the extra dye after recording the grating is one approach to prevent this light response [55]. As a result, we exposed the register photopolymer layer to a 13.5 W (875 lumens at 6500 K, Lexman) LED bulb for 20 min. Due to the tiny amount of dye that is left in the exposed areas after curing, the gating is not removed. Over time the grating becomes more stable since this process only affects the leftover dye in the unexposed zones. The cured gratings were kept in natural lighting with seasonal variations in temperature and relative humidity without problems.

2.2. Experimental Setups

In Figure 2 it can be seen the experimental holographic setup used to calculate the HLs resolution in a direct experimental method. A 473 nm diode-pumped laser and a 633 nm He-Ne laser were used to illuminate the HLs. The beam, after being spatially filtered, was placed at the reconstruction angle θ C that matched the recording angle [30]. The distance from the USAF test to the HL and the distance from the HL to the CCD sensor was 2 f H L so that the magnification of the optical system M = 1 .
Table 2 shows the parameters of the HL reconstruction geometry. In addition, a typical experimental holographic setup for recording was used with the following parameters, recording wavelength 488 nm, object angle 0°, and reference angle 34.2° to obtain an HL focal length of 90 mm. More details such as impulse response using a CCD sensor and a Hartmann-Shack wavefront sensor can be found at [26,30].

2.3. Theoretical Background

2.3.1. Convolution Theorem

Mathematically, a complex extended object can be represented as a weighted sum of impulse functions [56]. The impulse response of the HL studied is the ASF, which can be independent of the object plane position, in which case it is called invariant under translations. In addition, if there is no distortion in the system, the image plane coordinates are related linearly with the coordinates of the object plane through the lateral magnification M. Therefore, the image of an extended object can be calculated as an overlay of weighted ASF through the following direct operation.
I ( x , y ) = O ( u , v ) · A S F u x M , v y m d u d v
where O ( u , v ) and I ( x , y ) represent the object and the image, respectively. This integral is called convolution. Therefore, the image of a complex object can be seen as a convolution of that object and the impulsive response of the system.
I m a g e = O b j e c t A S F

2.3.2. Amplitude Spread Function (ASF)

Let us start by considering that in the exit pupil of an HLs there is a spherical wavefront. It can be described through the sagitta of this wavefront.
Considering the geometry of Figure 3 and using the Pythagorean theorem, it can be seen that
( R z ) 2 + h 2 = R 2
2 z R + z 2 + h 2 = 0
Considering small apertures Z < < , it can be considered Z 2 0 , so knowing that h = x 2 + y 2 it can be shown
z h 2 2 R = ( x p 2 + y p 2 ) 2 R
Working within the paraxial approximation, we can define the field in the HL exit pupil plane as a complex exponential function of the sagitta of the outgoing wavefront.
u ( x p , y p ) = exp i k · Z = exp i k · ( x p 2 + y p 2 ) 2 f
Generalising this to the case of an object point O and to any optical system, we have that the field is given as
u ( x p , y p ) = exp i k · Z s = exp i k · ( x p 2 + y p 2 ) 2 s
Knowing that the size of the lenses is finite and the pupil is circular, we can write the field in the exit pupil plane as
u ( x p , y p ) = p ( x p , y p ) · exp i k · ( x p 2 + y p 2 ) 2 s
where
p ( x p , y p ) = p ( r p ) = 1 r p R e x i t p u p i l 0 r p > R e x i t p u p i l
and r p is defined as r p = x p 2 + y p 2 .
However, the objective is to obtain the Intensity or Amplitude distribution in a given plane, usually the paraxial image plane of the exit pupil. The tool we have to propagate the field is the Fresnel integral. Therefore
u s ( x , y ) = A · u ( x p , y p ) · e i π x p 2 + y p 2 λ s · e i 2 π x x p 2 + y y p 2 λ s d x p d y p
Applying the definition of the Fourier transform we have that
F T h ( x , y ) = H ( u , v ) = h ( x , y ) e i 2 π ( u x + v y ) d x d y
u s ( x , y ) = A · F T u ( x p , y p ) · e i π x p 2 + y p 2 λ s u = x λ s , v = y λ s
Using the relationship obtained in Equation (8), and applying the definition of the wavenumber as k = 2 π λ , it is obtained
u s ( x , y ) = A · T F p ( x p , y p ) · e i 2 π λ x p 2 + y p 2 2 s · e i π x p 2 + y p 2 λ s u = x λ s , v = y λ s
Therefore, u s ( x , y ) been simplified to
u s ( x , y ) = A · F T p ( x p , y p ) u = x λ s , v = y λ s
Doing the change of variable P ( u , v ) = F T p ( x p , y p ) , it can be shown that P ( u , v ) can be described as
P ( u , v ) = 2 J 1 2 π u 2 + v 2 R p s 2 π u 2 + v 2 R p s
that represents the impulse response function of the system. The impulse response function describes the response of an imaging system to an object point and can be defined in amplitude or intensity. For an optical system working with coherent light, and whose pupil is circular, the impulse response is called the Amplitude Spread Function (ASF). On the other hand, when the light source is incoherent, this function is called the Point Spread Function (PSF), and represents the intensity distribution in the image plane. Moreover, for an aberration-free (diffraction-limited) system with a circular pupil, the PSF has an analytical solution and is the well-known Airy’s Disc. Therefore we conclude that, while for systems working with incoherent light the impulse response is defined in intensity, for systems working with coherent light it is defined in amplitude.
Amplitude Intensity
P ( u , v ) = 2 J 1 2 π u 2 + v 2 R p s 2 π u 2 + v 2 R p s I ( u , v ) = 2 J 1 2 π u 2 + v 2 R p s 2 π u 2 + v 2 R p s 2
where J 1 represents a first order Bessel function.
To generalise this to the case where the emergent wavefront of the exit pupil is aberrated, we turn to the geometry of Figure 4. In the figure, it can be seen the relationship between the wave aberration (W) and the ray aberration ( Δ ( x , y ) ). In addition it can be seen that the ideal and real sagitta can be related as
Z r e a l = W + Z i d e a l
Therefore, the real field u r e a l ( x p , y p ) is defined as
u r e a l ( x p , y p ) = p ( x p , y p ) · e i k · Z r e a l = p ( x p , y p ) · e i k · W · e i k · Z i d e a l
which, as in the ideal case, we propagate by means of the Fresnel integral
u s ( x , y ) = A · u r e a l ( x p , y p ) · e i π x p 2 + y p 2 λ s · e i 2 π x x p 2 + y y p 2 λ s d x p d y p
and if we now introduce u r e a l obtained in (15), in the Equation (16) and considering (5) we obtain
u s ( x , y ) = A · p ( x p , y p ) · e i k · W · e i k · Z i d e a l e i π x p 2 + y p 2 λ s · e i 2 π x x p 2 + y y p 2 λ s
If, as before, we use the Fourier transform, we have that in the Gaussian image plane, the field is given as
u s ( x , y ) = A · F T p ( x p , y p ) · e i k · W ( x p , y p ) u = x λ s , v = y λ s
and using the characteristic equation of the generalised pupil function
P ( x p , y p ) = p ( x p , y p ) · e i k · W ( x p , y p )
we have that the field in the image plane, with the presence of aberrations, is defined as
u s ( x , y ) = A · F T P ( x p , y p ) u = x λ s , v = y λ s
In the case of an aberrated optical system, the impulse response can be defined as the Fourier transform of a complex function P, commonly referred to as the generalised pupil function. And we can further define the Amplitude Transfer Function (ATF) as the Fourier transform of the impulse response. This indicates that the ATF is proportional to the complex function P. It is evident that the bandwidth of the ATF is not affected by the presence of aberrations. It should be noted that the only effect of the aberrations is to introduce phase distortions into the bandpass.
A S F ( x , y ) = A · F T P ( x p , y p ) u = x λ s , v = y λ s
A T F ( x , y ) = F T A S F ( x , y )

2.3.3. Case 1: ASF Obtained Using a CCD Sensor

In this case, to perform the convolution between the impulse response and an objective test, it is necessary to obtain the impulse response in complex amplitude, but this is not possible because when working with a CCD sensor only the impulse response in intensity can be obtained. A good option is to make an approximation and obtain the absolute value of the amplitude. According to [26], the intensity in the image plane can be calculated as:
I ( x , y ; z ) = 1 B 2 S A ( x , y ) e x p i Δ ( x , y ; x , y ; z ) d x d y 2
and the amplitude approximation can be obtained as
A ( x , y ; z ) = 1 B S A ( x , y ) e x p i Δ ( x , y ; x , y ; z ) d x d y
so ASF can be considered to be A S F ( x , y ; z ) A ( x , y ; z ) .

2.3.4. Case 2: ASF Obtained Using an HS Wavefront Sensor

On the other hand, the complex amplitude impulse response can be obtained using the Hartmann-Shack wavefront sensor. Aberrations can be defined in the exit pupil plane using the wavefront aberration function as
W ( ρ , θ ) = n = 0 , m = n k n | m | = p a r n C n m · Z n m ( ρ , θ )
where C n m are the Zernike coefficients which for negative asymmetric HL according to [26,30] is dominated by spherical aberration ( C 0 4 ) and Z n m ( ρ , θ ) is the general form given by
Z n m ( ρ , θ ) = N n m R n | m | ( ρ ) cos ( m θ ) p a r a m 0 N n m R n | m | ( ρ ) sin ( m θ ) p a r a m < 0
where the superscript m denotes the angular frequency, and the subscript n denotes the degree of the radial polynomial. In addition, the explicit form of the radial polynomial, R n | m | , is defined as
R n | m | ( ρ ) = s = 0 ( n | m | ) / 2 ( 1 ) s ( n s ) ! s ! [ 0.5 ( n + | m | ) s ] ! [ 0.5 ( n | m | ) s ] ! ρ n 2 s
which is a polynomial of degree n containing the terms ρ n , ρ n 2 ,⋯, ρ m . It can also be deduced that the normalization factor, N n m , is defined as
N n m = 2 ( n + 1 ) 1 + δ m 0
where δ m 0 is the Kronecker delta.
Finally, the ASF is given as
A S F ( x , y ; z ) = A · F T p ( x , y ) · e i k · W ( x , y ) u = x λ f H L , v = y λ f H L
where x = r cos θ and y = r sin θ .

2.4. Metric Based on the Similarity between Object and Image: Mean Squared Error (MSE)

The most basic and popular full-reference quality statistic is the mean squared error ( M S E ), which is calculated by averaging the squared intensity differences of distorted and reference picture pixels [57].
M S E = 1 n i = 1 N ( O i I i ) 2
where N is the number of pixels and O i and I i are the intensity values in the pixel i.

3. Results and Discussion

3.1. HLs Resolution

A USAF Test 1951 has been used to determine the resolution of an optical system to assess how closely an object and its image resemble one another when holographic lenses are utilized. The test consists of a succession of groups of three bars repeated in a pattern. They typically fall within the 0.25 to 228 lp/mm range. Each group has six components. The group is identified by a Group Number (−2, −1, 0, 1, 2, etc.), which is equivalent to 2 raised to the power of the first element’s spatial frequency. Each element in the group is the sixth root of two units smaller than the element before it. The resolution of the system can be calculated using the equation or by reading the group and element number of the smallest pattern the optical system can resolve (using the condition of resolving at least 2 lines).
R e s o l u t i o n = 2 G r o u p + ( E l e m e n t 1 ) / 6
Convolution simulations of the USAF test with the A S F obtained by different methods were carried out.

3.1.1. Simulated Convolution for ASF Obtained with the HS Wavefront Sensor

Figure 5 shows simulations of the convolution images between the USAF 1951 object test and the ASF obtained with the HS wavefront sensor.

3.1.2. Simulated Convolution for A S F Obtained with the CCD Sensor

Figure 6 shows simulations of the convolution images between the USAF 1951 object test and the ASF obtained with the CCD sensor.

3.1.3. USAF Experimental Test Image Obtained with the CCD Sensor

Figure 7 shows the images of the experimental USAF object test obtained with the setup CCD sensor.
Table 3 shows the HL resolutions obtained in each of the methods. It can be seen that the best results were for the ASF obtained with the HS wavefront sensor (Figure 5). Secondly, good results were obtained for the direct experimental method (Figure 7). Finally, the worst results were obtained for the ASF obtained from the CCD sensor (Figure 6). It can be seen that the calculation of the resolution of HLs working with coherent light is not a simple task. The fact of approximating | A S F ( x , y ) | A S F ( x , y ) makes that part of the information is lost, which negatively affects the HLs resolution calculation.
In addition, to compare both methods, Table 4 shows the theoretical cut-off and Nyquist frequencies for the CCD and HS wavefront sensor. Previous works analysed both sensors in more detail [26,30].
To see the resolution of the HLs in more intuitive cases, simulations of the convolutions of the ASFs obtained with both methods (HS and CCD sensor) have been represented with the logo of the University of Alicante as an object (Figure 8). It can be seen that the image obtained for the HS sensor is sharper than the one obtained for the CCD sensor. Higher resolution can be seen in the case of the impulse response obtained with the HS sensor. In fact, it works as a low-pass filter smoothing the image.

3.2. MSE Metric

Finally, the MSE metric has been calculated to quantify the resolution of the HLs in terms of similarity between object and image. Figure 9 shows a scheme for the calculation of the MSE metric. Table 5 shows the results obtained for this metric. The difference between the object test and the image obtained from the convolution can be observed quantitatively. It can be seen that the results are consistent with the quality of the images obtained in each case.
Table 5 shows the results obtained for the MSE metric. It can be seen that the results obtained for the HS wavefront sensor are better than those obtained for the CCD sensor. This is in agreement with the previous results obtained for the resolution of the HLs.
To better understand the results, we can highlight some differences between the HS wavefront sensor and the CCD sensor. The HS wavefront sensor works with a CMOS (Complementary Metal Oxide Semiconductor) sensor which has some different characteristics than the CCD (Charge Coupled Device) sensor. We can compare both sensors using some important parameters. In terms of speed, CMOS is superior to CCD because all the processing is done inside the sensor itself, which offers higher speed. In the matter of noise, CCD is superior to CMOS. This is because the signal processing is done on an external chip, which may be better optimized to perform this function. In respect of blooming, CMOS sensors are superior to CCD. This phenomenon occurs when a pixel is saturated by the light incident on it and then begins to saturate the surrounding pixels. Finally, the dynamic range of the CCD sensor is twice that of the CMOS sensor. The dynamic range is the coefficient between the saturation of the pixels and the threshold below which they do not capture a signal. In this case, the CCD, being less sensitive, tolerates light extremes much better. Therefore, we have that the CMOS sensor has a higher speed and it’s better for the blooming phenomena, but the CCD sensor is better for the noise and dynamic range.

4. Conclusions

We have studied three different methods to analyze the resolution of HLs stored in a photopolymer material (Biophotopol). In this sense, we have improved the way to measure this resolution. The resolutions obtained with the CCD sensor using the convolution theorem are less reliable than those obtained with the Hartmann Shack sensor since part of the information is lost due to the way of obtaining the impulse response of the HL in this case. However, using the direct experimental method to calculate the resolution with the CCD sensor, similar results to those obtained with the HS sensor are obtained. The object-image similarity metric has also been analyzed to quantitatively evaluate the HL resolution. It can be observed that the best results have been for the negative asymmetric HLs reconstructed at 473 nm. It can be concluded that the HS wavefront sensor is a good tool to characterize the image quality and resolution of optical systems working with coherent light using the convolution theorem and the CCD sensor is a good tool to calculate the resolution by obtaining a direct experimental way the USAF test image. Moreover, the use of a low-toxicity photopolymer to store the holographic lenses allows us to obtain light, friendly, accurate, stable, and easy to fabricate systems compared with the traditional ones.

Supplementary Materials

The following supporting information can be downloaded at: https://www.mdpi.com/article/10.3390/polym14245426/s1. Video S1: Video of the HL stored on the photopolymer layer.

Author Contributions

Conceptualization, T.L., V.N.-F. and I.P.; Methodology and validation, T.L., M.M.-V. and I.P.; Formal analysis and writing original draft preparation, T.L., V.N.-F. and I.P.; Software and writing review, M.G.R. and A.B. All authors have read and agreed to the published version of the manuscript.

Funding

This research was funded by Universidad de Alicante (UAFPU20-23); Generalitat Valenciana (CIDEXG/2022/60, CDEIGENT/2018/024, IDIFEDER/2021/014, PROMETEO/2021/006); Ministerio de Ciencia e Innovación (PID2019-106601RB-I00, PID2021-123124OB-I00).

Institutional Review Board Statement

Not applicable.

Informed Consent Statement

Not applicable.

Data Availability Statement

Not applicable.

Conflicts of Interest

The authors declare no conflict of interest.

References

  1. Gabor, D. A New Microscopic Principle. Nature 1948, 161, 777–779. [Google Scholar] [CrossRef] [Green Version]
  2. Barachevsky, V.A. The Current Status of the Development of Light-Sensitive Media for Holography (a Review). Opt. Spectroc. 2018, 124, 373–407. [Google Scholar] [CrossRef]
  3. Schwar, M.J.R.; Pandya, T.P.; Weinberg, F.J. Point holograms as optical elements. Nature 1967, 215, 239–241. [Google Scholar] [CrossRef]
  4. Store, T.W.; Thompson, B.J. Holographic and diffractive lenses and mirrors. SPIE Milestore Ser. 1991, 34, 3–668. [Google Scholar]
  5. Denisyuk, Y.N. Photographic Reconstruction of the Optical Properties of an Object in Its Own Scattered Radiation Field. Sov. Phys. Dokl. 1962, 7, 543–545. [Google Scholar]
  6. Kostuk, R.K. Holography Principles and Applications; CRC Press: Boca Raton, FL, USA, 2019. [Google Scholar]
  7. Fernández, E.; Ortuño, M.; Gallego, S.; García, C.; Beléndez, A.; Pascual, I. Comparison of peristrophic multiplexing and a combination of angular and peristrophic holographic multiplexing in a thick PVA/acrylamide photopolymer for data storage. Appl. Opt. 2007, 46, 5368–5373. [Google Scholar] [CrossRef] [Green Version]
  8. Navarro-Fuster, V.; Ortuño, M.; Fernández, R.; Gallego, S.; Marquez, A.; Beléndez, A.; Pascual, I. Peristrophic multiplexed holograms recorded in a low toxicity photopolymer. Opt. Mater. Express 2017, 7, 133–147. [Google Scholar] [CrossRef] [Green Version]
  9. Piao, M.L.; Kim, N.; Park, J.H. Phase contrast projection display using photopolymer. J. Opt. Soc. Korea 2008, 12, 319–325. [Google Scholar] [CrossRef] [Green Version]
  10. Lee, K.Y.; Jeung, S.H.; Cho, B.M.; Kim, N. Photopolymer-based surface-normal input/output volume holographic grating coupler for 1550-nm optical wavelength. J. Opt. Soc. Korea 2012, 16, 17–21. [Google Scholar] [CrossRef] [Green Version]
  11. Fernández, E.; Márquez, A.; Gallego, S.; Fuentes, R.; García, C.; Pascual, I. Hybrid ternary modulation applied to multiplexing holograms in photopolymers for data page storage. J. Light. Technol. 2010, 28, 776–783. [Google Scholar] [CrossRef] [Green Version]
  12. Gunter, P.; Huignard, J.P. Photorefractive Materials and Their Applications 3; Buse, K., Havermeyer, F., Liu, W., Moser, C., Psaltis, D., Eds.; Springer: New York, NY, USA, 2007; pp. 295–317. [Google Scholar]
  13. Sheridan, J.T.; Kostuk, R.K.; Gil, A.F.; Wang, Y.; Lu, W.; Zhong, H.; Tomita, Y.; Neipp, C.; Francés, J.; Gallego, S.; et al. Roadmap on holography. J. Opt. 2020, 22, 123002. [Google Scholar] [CrossRef]
  14. Yeom, H.-J.; Kim, H.-J.; Kim, S.-B.; Zhang, H.; Li, B.; Ji, Y.-M.; Kim, S.-H.; Park, J.-H. 3D holographic head mounted display using holographic optical elements with astigmatism aberration compensation. Opt. Express 2015, 23, 32025–32034. [Google Scholar] [CrossRef]
  15. Chen, Z.; Sang, X.; Lin, Q.; Li, J.; Yu, X.; Gao, X.; Yan, B.; Wang, K.; Yu, C.; Xie, S. A see-through holographic head-mounted display with the large viewing angle. Opt. Commun. 2017, 384, 125–129. [Google Scholar] [CrossRef] [Green Version]
  16. Kim, N.; Piao, Y.-L.; Wu, H.-Y. Holographic Material and Optical Systems. In Holographic Optical Elements and Applications; Naydenova, I., Nazarova, D., Babeva, T., Eds.; InTech: Rijeka, Croatia, 2017; pp. 99–131. [Google Scholar]
  17. Lee, S.; Lee, B.; Cho, J.; Jang, C.; Kim, J.; Lee, B. Analysis and Implementation of Hologram Lenses for See-Through Head-Mounted Display. IEEE Photonics Technol. Lett. 2017, 29, 82–85. [Google Scholar] [CrossRef]
  18. Lin, W.-K.; Matoba, O.; Lin, B.-S.; Su, W.-C. Astigmatism and deformation correction for a holographic head-mounted display with a wedge-shaped holographic waveguide. Appl. Opt. 2018, 57, 7094–7101. [Google Scholar] [CrossRef]
  19. Morales-Vidal, M.; Lloret, T.; Ramírez, M.G.; Beléndez, A.; Pascual, I. Green and wide acceptance angle solar concentrators. Opt. Express 2022, 30, 25366–25379. [Google Scholar] [CrossRef] [PubMed]
  20. Marín-Sáez, J.; Chemisana, D.; Atencia, J.; Collados, M.V. Outdoor performance evaluation of a holographic solar concentrator optimized for building integration. Appl. Energy 2019, 250, 1073–1084. [Google Scholar] [CrossRef]
  21. Ferrara, M.A.; Striano, V.; Coppola, G. Volume Holographic Optical Element as Solar Concentrators: An Overview. Appl. Sci. 2019, 9, 193. [Google Scholar] [CrossRef] [Green Version]
  22. Chemisana, D.; Collados, M.V.; Quintanilla, M.; Atencia, J. Holographic lenses for building integrated concentrating photovoltaics. Appl. Energy 2013, 110, 227–235. [Google Scholar] [CrossRef]
  23. Ferrara, M.A.; Borbone, F.; Coppola, G. Holographic Optical Lenses Recorded on a Glassy Matrix-Based Photopolymer for Solar Concentrators. Photonics 2021, 8, 585. [Google Scholar] [CrossRef]
  24. Lee, J.H.; Wu, H.Y.; Piao, M.L.; Kim, N. Holographic Solar Energy Concentrator Using Angular Multiplexed and Iterative Recording Method. IEEE Photonics J. 2016, 8, 777–779. [Google Scholar] [CrossRef]
  25. García, C.; Rodriguez, J.D.; Fernandez, E.; Camps, V.; Fuentes, R.; Pascual, I. Holographic lens recorded on photopolymers: Fabrication and study of the image quality. J. Mod. Opt. 2009, 56, 1288–1295. [Google Scholar] [CrossRef]
  26. Lloret, T.; Navarro-Fuster, V.; Ramírez, M.G.; Ortuño, M.; Neipp, C.; Beléndez, A.; Pascual, I. Holographic Lenses in an Environment-Friendly Photopolymer. Polymers 2018, 10, 302. [Google Scholar] [CrossRef] [PubMed] [Green Version]
  27. Zhu, L.; Cui, Y. Abnormal phenomena in resolution limit of holographic lens. Proc. SPIE 2002, 4833, 342–347. [Google Scholar]
  28. Zhu, L.; Cui, Y. Study on the Limit of Resolution for Holographic Lenses. Proc. SPIE 2002, 4924, 39–45. [Google Scholar]
  29. Yeom, J.; Jeong, J.; Hong, J.; Choi, K.S. Analysis on image quality of a holographic lens with a non-converging signal wave for compact near-eye displays. Opt. Express 2022, 30, 36632–36643. [Google Scholar] [CrossRef]
  30. Lloret, T.; Navarro-Fuster, V.; Ramírez, M.G.; Morales-Vidal, M.; Beléndez, A.; Pascual, I. Aberration-Based Quality Metrics in Holographic Lenses. Polymers 2020, 12, 993. [Google Scholar] [CrossRef]
  31. Kim, J.M.; Choi, B.S.; Choi, Y.S.; Kim, J.M.; Bjelkhagen, H.I.; Phillips, N.J. Holographic optical elements recorded in silver halide sensitized gelatin emulsions Part 2 Reflection holographic optical elements. Appl. Opt. 2002, 41, 1522. [Google Scholar] [CrossRef]
  32. Beléndez, A.; Neipp, C.; Flores, M.; Pascual, I. High-efficiency silver-halide sensitized gelatin holograms with low absorption and scatter. J. Mod. Opt. 1998, 45, 1985–1992. [Google Scholar] [CrossRef] [Green Version]
  33. Oliva, J.; Boj, P.G.; Pardo, M. Dichromated gelatin holograms derivated from agfa 8E75 HD plates. Appl. Opt. 1984, 23, 196–197. [Google Scholar] [CrossRef]
  34. Kubota, T.; Ose, T. Lippmann color holograms recorded in methylene-blue sensitized dichromated gelatin. Opt. Lett. 1979, 1, 8–9. [Google Scholar] [CrossRef] [PubMed]
  35. Kozma, A. Effects of film-grain noise in holography. J. Opt. Soc. Am. 1968, 58, 436–438. [Google Scholar] [CrossRef]
  36. Mashev, L.; Tonchev, S. Formation of Holographic Diffraction Gratings in Photoresist. Appl. Phys.-Mater. Sci. Process. 1981, 26, 143–149. [Google Scholar] [CrossRef]
  37. Tsutsumi, N. Recent advances in photorefractive and photoactive polymers for holographic applications. Polym. Int. 2017, 66, 167–174. [Google Scholar] [CrossRef]
  38. Berneth, H.; Bruder, F.K.; Fäcke, T.; Hagon, T.; Hönel, D.; Jurbergs, D.; Rölle, T.; Weiser, M.S. Holographic Recording Aspects of High Resolution Bayfol HX Photopolymer. In Proceedings of the SPIE OPTO, San Francisco, CA, USA, 22–27 January 2011. [Google Scholar]
  39. Close, D.H.; Jacobson, A.D.; Margerum, J.D.; Brault, R.G.; McClung, F.J. Hologram recording on photopolymer materials. Appl. Phys. Lett. 1969, 14, 159–160. [Google Scholar] [CrossRef]
  40. Guo, J.; Gleeson, M.R.; Sheridan, J.T. A review of the optimisation of photopolymer materials for holographic data storage. Phys. Res. Int. 2012, 2012, 1–16. [Google Scholar] [CrossRef] [Green Version]
  41. Bianco, G.; Ferrara, M.A.; Borbone, F.; Roviello, A.; Striano, V.; Coppola, G. Photopolymer-based volume holographic optical elements: Design and possible applications. J. Eur. Opt. Soc. Rapid Publ. 2015, 10, 15057-25. [Google Scholar] [CrossRef] [Green Version]
  42. Malallah, R.; Li, H.; Kelly, D.P.; Healy, J.J.; Sheridan, J.T. A review of hologram storage and self-written waveguides formation in photopolymer media. Polymers 2017, 9, 337. [Google Scholar] [CrossRef]
  43. Gallego, S.; Márquez, A.; Méndez, D.; Neipp, C.; Ortuño, M.; Beléndez, A.; Fernández, E.; Pascual, I. Direct analysis of monomer diffusion times in polyvinyl/acrylamide materials. Appl. Phys. Lett. 2008, 92, 73306. [Google Scholar] [CrossRef] [Green Version]
  44. Gallego, S.; Ortuño, M.; Neipp, C.; Márquez, A.; Beléndez, A.; Pascual, I. Characterization of polyvinyl alcohol/acrylamide holographic memories with a first-harmonic diffusion model. Appl. Opt. 2005, 44, 6205–6210. [Google Scholar] [CrossRef] [Green Version]
  45. Weiss, V.; Millul, E.; Friesem, A.A. Photopolymeric holographic recording media: In-situ and real-time characterization. In Proceedings of the SPIE PHOTONICS WEST ’96, San Jose, CA, USA, 27 January–2 February 1996; Volume 2688, pp. 11–21. [Google Scholar]
  46. Zhu, J.; Wang, G.; Hao, Y.; Xie, B.; Cheng, A.Y.S. Highly sensitive and spatially resolved polyvinyl alcohol/acrylamide photopolymer for real-time holographic applications. Opt. Express 2010, 18, 18106–18112. [Google Scholar] [CrossRef]
  47. Olivares-Perez, A.; Fuentes-Tapia, I.F.; Hernández-Garay, M.P.; Ibarra-Torres, C.J. Holograms in polyvinyl alcohol photosensitized with CuCl2(2H2O). Opt. Eng. 2011, 50, 65801-6. [Google Scholar]
  48. Cody, D.; Gribbin, S.; Mihaylova, E.; Naydenova, I. Low-Toxicity Photopolymer for Reflection Holography. ACS Appl. Mater. Interfaces 2016, 8, 18481–18487. [Google Scholar] [CrossRef] [PubMed]
  49. Cody, D.; Naydenova, I.; Mihaylova, E. New non-toxic holographic photopolymer material. J. Opt. 2012, 14, 15601. [Google Scholar] [CrossRef] [Green Version]
  50. Peng, H.; Nair, D.P.; Kowalski, B.A.; Xi, W.; Gong, T.; Wang, C.; Cole, M.; Cramer, N.B.; Xie, X.; McLeod, R.R.; et al. High performance graded rainbow holograms via two-stage sequential orthogonal thiol-click chemistry. Macromolecules 2014, 47, 2306–2315. [Google Scholar] [CrossRef]
  51. Alim, M.D.; Glugla, D.J.; Mavila, S.; Wang, C.; Nystrom, P.D.; Sullivan, A.C.; McLeod, R.R.; Bowman, C.N. High Dynamic Range (Dn) Two-Stage Photopolymers via Enhanced Solubility of a High Refractive Index AcrylateWriting Monomer. ACS Appl. Mater. Interfaces 2018, 10, 1217–1224. [Google Scholar] [CrossRef]
  52. Navarro-Fuster, V.; Ortuño, M.; Gallego, S.; Márquez, A.; Beléndez, A.; Pascual, I. Biophotopol’s energetic sensitivity improved in 300 um layers by tuning the recording wavelength. Opt. Mater. 2016, 52, 111–115. [Google Scholar] [CrossRef] [Green Version]
  53. Ortuño, M.; Fernández, E.; Gallego, S.; Beléndez, A.; Pascual, I. New photopolymer holographic recording material with sustainable design. Opt. Express 2007, 15, 12425–12435. [Google Scholar] [CrossRef] [Green Version]
  54. Ortuño, M.; Gallego, S.; Márquez, A.; Neipp, C.; Pascual, I.; Beléndez, A. Biophotopol: A Sustainable Photopolymer for Holographic Data Storage Applications. Materials 2012, 5, 772–783. [Google Scholar] [CrossRef] [Green Version]
  55. Ramírez, M.G.; Sirvent, D.; Morales-Vidal, M.; Ortuño, M.; Martínez-Guardiola, F.J.; Francés, J.; Pascual, I. LED-Cured Reflection Gratings Stored in an Acrylate-Based Photopolymer. Polymers 2019, 11, 632. [Google Scholar] [CrossRef]
  56. Goodman, J.W. Introduction to Fourier Optics; Roberts and Company Publishers: Englewood, CO, USA, 2005; ISBN 978-0974707723. [Google Scholar]
  57. Guirao, A. Optics and Visual Metrics. In Handbook of Visual Optics; Artal, P., Ed.; CRC Press: London, UK, 2017; Volume II, pp. 276–297. ISBN 9781482237924. [Google Scholar]
Figure 1. Biophotopol chemical structures of the prepolymer components. PVA: polyvinyl alcohol, NaAO: sodium acrylate, TEA: triethanolamine, RF: riboflavin 5’- monophosphate sodium salt.
Figure 1. Biophotopol chemical structures of the prepolymer components. PVA: polyvinyl alcohol, NaAO: sodium acrylate, TEA: triethanolamine, RF: riboflavin 5’- monophosphate sodium salt.
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Figure 2. (a) Experimental setup for the HLs resolution evaluation. F: filter, SF: spatial filter, L: lens, D: diaphragm, HL: holographic lens, CCD Sensor: Charge Coupled Device. (b) Real photo of the experimental setup. (c) Picture of HL stored on the photopolymer layer. Video of HL stored on the photopolymer layer can be seen in S1.
Figure 2. (a) Experimental setup for the HLs resolution evaluation. F: filter, SF: spatial filter, L: lens, D: diaphragm, HL: holographic lens, CCD Sensor: Charge Coupled Device. (b) Real photo of the experimental setup. (c) Picture of HL stored on the photopolymer layer. Video of HL stored on the photopolymer layer can be seen in S1.
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Figure 3. Geometry for obtaining the impulse response (ASF) of the HLs.
Figure 3. Geometry for obtaining the impulse response (ASF) of the HLs.
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Figure 4. Geometry for the relation between the ideal sagittal, the real sagittal and the wave aberration function (W). The wave aberration (W) is also related to the ray aberration ( Δ ( x , y ) ).
Figure 4. Geometry for the relation between the ideal sagittal, the real sagittal and the wave aberration function (W). The wave aberration (W) is also related to the ray aberration ( Δ ( x , y ) ).
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Figure 5. Simulated convolution for negative asymmetrical HLs, with ASF obtained with the HS wavefront sensor, reconstructed at (a) 473 nm and (b) 633 nm.
Figure 5. Simulated convolution for negative asymmetrical HLs, with ASF obtained with the HS wavefront sensor, reconstructed at (a) 473 nm and (b) 633 nm.
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Figure 6. Simulated convolution for negative asymmetrical HLs, with ASF obtained with the CCD sensor, reconstructed at: (a) 473 nm, (b) 633 nm.
Figure 6. Simulated convolution for negative asymmetrical HLs, with ASF obtained with the CCD sensor, reconstructed at: (a) 473 nm, (b) 633 nm.
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Figure 7. Image obtained with the CCD sensor illuminated at: (a) 473 nm, (b) 633 nm.
Figure 7. Image obtained with the CCD sensor illuminated at: (a) 473 nm, (b) 633 nm.
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Figure 8. Convolution simulations of an object test (University of Alicante logo) with the ASFs obtained by the different methods (HS wavefront sensor and CCD sensor) using as reconstruction wavelength: (a) 473 nm and (b) 633 nm.
Figure 8. Convolution simulations of an object test (University of Alicante logo) with the ASFs obtained by the different methods (HS wavefront sensor and CCD sensor) using as reconstruction wavelength: (a) 473 nm and (b) 633 nm.
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Figure 9. Convolution simulations of an object test (University of Alicante logo) with the ASFs obtained by the different methods: HS wavefront sensor and CCD sensor.
Figure 9. Convolution simulations of an object test (University of Alicante logo) with the ASFs obtained by the different methods: HS wavefront sensor and CCD sensor.
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Table 1. Recording material composition quantities.
Table 1. Recording material composition quantities.
PVANaAOTEARF
(wt/V %) (wt/V %)(M) *(wt/V %)(M)(wt/V %)(M)
13.53.700.390.139.0 × 10 3 0.051.0 × 10 3
†: Weight by volume. *: Molarity.
Table 2. HL parameters for the reconstruction geometry.
Table 2. HL parameters for the reconstruction geometry.
λ (nm)Angles and Focal Length ϕ HL (mm)
θ c = 33 °
473 θ i = 0 °12
f H L = 93 mm
θ c = 46.8 °
633 θ i = 0 °12
f H L = 70 mm
Table 3. HLs resolution using the USAF test.
Table 3. HLs resolution using the USAF test.
λ USAF (Figure 5)USAF (Figure 6)Exp. USAF (Figure 7)
(nm)(lp/mm)(lp/mm)(lp/mm)
47311.314.0010.08
63311.313.178.98
Table 4. Theoretical cut-off and Nyquist frequencies for the CCD and HS wavefront sensor.
Table 4. Theoretical cut-off and Nyquist frequencies for the CCD and HS wavefront sensor.
λ FcutFNyqFNyq
(nm)TheoreticalHS SensorCCD Sensor
(lp/mm)(lp/mm)(lp/mm)
47367.785.76107.53
63368.285.76107.53
Table 5. Mean Squared Error (MSE) at 473 and 633 nm.
Table 5. Mean Squared Error (MSE) at 473 and 633 nm.
λ (nm) MSE MSE
(nm)(HS Wavefront Sensor)(CCD Sensor)
473628.281853.70
633629.313110.70
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Lloret, T.; Morales-Vidal, M.; Navarro-Fuster, V.; G. Ramírez, M.; Beléndez, A.; Pascual, I. Holographic Lens Resolution Using the Convolution Theorem. Polymers 2022, 14, 5426. https://doi.org/10.3390/polym14245426

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Lloret T, Morales-Vidal M, Navarro-Fuster V, G. Ramírez M, Beléndez A, Pascual I. Holographic Lens Resolution Using the Convolution Theorem. Polymers. 2022; 14(24):5426. https://doi.org/10.3390/polym14245426

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Lloret, Tomás, Marta Morales-Vidal, Víctor Navarro-Fuster, Manuel G. Ramírez, Augusto Beléndez, and Inmaculada Pascual. 2022. "Holographic Lens Resolution Using the Convolution Theorem" Polymers 14, no. 24: 5426. https://doi.org/10.3390/polym14245426

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