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Article

Two-Step Dopamine-to-Polydopamine Modification of Polyethersulfone Ultrafiltration Membrane for Enhancing Anti-Fouling and Ultraviolet Resistant Properties

1
Department of Chemical Engineering, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia
2
Department of Chemical Engineering, Universiti Teknologi PETRONAS, Bandar Seri Iskandar 32610, Perak, Malaysia
3
Division of Physical Sciences and Engineering (PSE), KAUST Solar Center (KSC), King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi Arabia
4
Research Center for Membrane and Film Technology, Department of Chemical Science and Engineering, Kobe University, Rokkodai-Cho 1-1, Nadaku, Kobe 657-8501, Japan
*
Authors to whom correspondence should be addressed.
Polymers 2020, 12(9), 2051; https://doi.org/10.3390/polym12092051
Received: 19 June 2020 / Revised: 1 August 2020 / Accepted: 7 August 2020 / Published: 9 September 2020
(This article belongs to the Special Issue Advanced Polymeric Materials)
Polydopamine has been widely used as an additive to enhance membrane fouling resistance. This study reports the effects of two-step dopamine-to-polydopamine modification on the permeation, antifouling, and potential anti-UV properties of polyethersulfone (PES)-based ultrafiltration membranes. The modification was performed through a two-step mechanism: adding the dopamine additive followed by immersion into Tris-HCl solution to allow polymerization of dopamine into polydopamine (PDA). The results reveal that the step of treatment, the concentration of dopamine in the first step, and the duration of dipping in the Tris solution in the second step affect the properties of the resulting membranes. Higher dopamine loadings improve the pure water flux (PWF) by more than threefold (15 vs. 50 L/m2·h). The extended dipping period in the Tris alkaline buffer leads to an overgrowth of the PDA layer that partly covers the surface pores which lowers the PWF. The presence of dopamine or polydopamine enhances the hydrophilicity due to the enrichment of hydrophilic catechol moieties which leads to better anti-fouling. Moreover, the polydopamine film also improves the membrane resistance to UV irradiation by minimizing photodegradation’s occurrence. View Full-Text
Keywords: polydopamine modified membrane; anti-ultraviolet; anti-fouling; polymerization; polyethersulfone polydopamine modified membrane; anti-ultraviolet; anti-fouling; polymerization; polyethersulfone
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MDPI and ACS Style

Mulyati, S.; Muchtar, S.; Arahman, N.; Syamsuddin, Y.; Mat Nawi, N.I.; Yub Harun, N.; Bilad, M.R.; Firdaus, Y.; Takagi, R.; Matsuyama, H. Two-Step Dopamine-to-Polydopamine Modification of Polyethersulfone Ultrafiltration Membrane for Enhancing Anti-Fouling and Ultraviolet Resistant Properties. Polymers 2020, 12, 2051. https://doi.org/10.3390/polym12092051

AMA Style

Mulyati S, Muchtar S, Arahman N, Syamsuddin Y, Mat Nawi NI, Yub Harun N, Bilad MR, Firdaus Y, Takagi R, Matsuyama H. Two-Step Dopamine-to-Polydopamine Modification of Polyethersulfone Ultrafiltration Membrane for Enhancing Anti-Fouling and Ultraviolet Resistant Properties. Polymers. 2020; 12(9):2051. https://doi.org/10.3390/polym12092051

Chicago/Turabian Style

Mulyati, Sri; Muchtar, Syawaliah; Arahman, Nasrul; Syamsuddin, Yanna; Mat Nawi, Normi I.; Yub Harun, Noorfidza; Bilad, Muhammad R.; Firdaus, Yuliar; Takagi, Ryosuke; Matsuyama, Hideto. 2020. "Two-Step Dopamine-to-Polydopamine Modification of Polyethersulfone Ultrafiltration Membrane for Enhancing Anti-Fouling and Ultraviolet Resistant Properties" Polymers 12, no. 9: 2051. https://doi.org/10.3390/polym12092051

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