Functionalized Poly(arylene ether nitrile) Porous Membrane with High Pb(II) Adsorption Performance
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. SPEN and Porous Membrane Preparation
2.3. Adsorption Behaviour for Pb(II)
2.4. Characterization
3. Results and Discussion
3.1. Characterization of SPEN
3.2. Structure Characterization of Porous Membrane
3.3. Effect of Solution pH
3.4. Effect of CTAB Content in a Porous Membrane
3.5. Effect of Initial Concentrations
3.6. Adsorption Isotherm
3.7. Thermal Stability Changes before and after Adsorption
3.8. Adsorption Mechanism
3.9. Recycling of SPEN Porous Membranes
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Membrane | EWC (%) | Porosity (%) | Contact Angle (°) |
---|---|---|---|
SPEN-CTAB-0% | 73.93 | 78.95 | 54.7 |
SPEN-CTAB-5% | 74.02 | 79.03 | 61.9 |
SPEN-CTAB-15% | 79.40 | 83.60 | 70.6 |
Membrane | Parameters | SPEN-CTAB-0% | SPEN-CTAB-5% | SPEN-CTAB-15% |
---|---|---|---|---|
Pseudo-first-order | k1 (min−1) | 0.0278 | 0.0404 | 0.0398 |
qe (cal.) (mg/g) | 12.811 | 12.678 | 11.274 | |
qe (exp.) (mg/g) | 183.60 | 161.73 | 127.43 | |
R2 | 0.8703 | 0.8320 | 0.6967 | |
Pseudo-second-order | k2 (g/mg·min) | 0.00037 | 0.00036 | 0.0012 |
qe (cal.) (mg/g) | 202.43 | 185.53 | 134.05 | |
qe (exp.) (mg/g) | 183.60 | 161.73 | 127.43 | |
R2 | 0.9911 | 0.9693 | 0.9978 | |
Intraparticle diffusion | ki1 | 33.697 | 28.316 | 24.236 |
C | 2.4810 | −10.281 | −1.170 | |
R12 | 0.9879 | 0.7428 | 0.9948 | |
ki2 | 6.1267 | 2.1267 | 0.7810 | |
C | 115.84 | 137.61 | 117.76 | |
R22 | 0.9682 | 0.8814 | 0.5995 |
Adsorbent | pH | Pb(II) Adsorption Capacity (mg/g) | Reference |
---|---|---|---|
PSF/HFO NPs MMMs | 6.5–7 | 13.2 | [27] |
PES/PDA-R UFAMs | 5.4 | 20.23 | [28] |
PES/chitosan/PVA/A-Fe3O4 MMMs | 6 | 40 | [29] |
PES/HHZO nanoparticles | 5 | 104 | [30] |
PAN/chitosan/UiO-66-NH2 MOF nanofibers | 6 | 115 | [31] |
PES/PANI@GO MMMs | 6 | 145 | [32] |
PES/HMO MMMs | 7–8 | 204.1 | [33] |
SPEN porous membranes | 5 | 246.96 | This study |
C0 (mg/L) | Parameters | 50 | 70 | 100 | 150 | 200 |
---|---|---|---|---|---|---|
Pseudo-first-order | k1 (min−1) | 0.0284 | 0.0387 | 0.0450 | 0.0490 | 0.0201 |
qe (cal.) (mg/g) | 13.861 | 13.730 | 13.821 | 13.052 | 12.174 | |
qe (exp.) (mg/g) | 195.82 | 196.09 | 202.99 | 217.92 | 246.96 | |
R2 | 0.9370 | 0.9588 | 0.9712 | 0.8994 | 0.4650 | |
Pseudo-second-order | k2 (g/mg·min) | 1.8 × 10−4 | 3.4 × 10−4 | 3.8 × 10−4 | 8.1 × 10−4 | 1.1 × 10−3 |
qe (cal.) (mg/g) | 234.74 | 219.30 | 225.22 | 228.83 | 245.70 | |
qe (exp.) (mg/g) | 195.82 | 196.09 | 202.99 | 217.92 | 246.96 | |
R2 | 0.9896 | 0.9975 | 0.9978 | 0.9990 | 0.9951 | |
Intraparticle diffusion | ki1 | 23.188 | 28.463 | 31.556 | 44.485 | 55.225 |
C | −5.5100 | −1.8826 | −2.4937 | −0.9429 | 10.448 | |
R12 | 0.8930 | 0.9875 | 0.9877 | 0.9967 | 0.9446 | |
ki2 | 8.5084 | 5.5405 | 4.7350 | 2.1192 | 2.2246 | |
C | 101.91 | 136.41 | 153.10 | 195.22 | 197.36 | |
R22 | 0.9668 | 0.9819 | 0.9545 | 0.9806 | 0.3939 |
Isotherms | Parameters (Temperature = 298.15 K) | |
---|---|---|
Langmuir | qm (mg/g) | 281.69 |
KL (L/mg) | 0.1117 | |
RL | 0.08998 | |
R2 | 0.9807 | |
Freundlich | KF ((mg/g) (L/mg)1/n) | 12.861 |
n−1 | 0.1861 | |
R2 | 0.8046 |
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Liu, X.; Zhou, M.; Zhou, X.; Wang, L.; Liu, X. Functionalized Poly(arylene ether nitrile) Porous Membrane with High Pb(II) Adsorption Performance. Polymers 2019, 11, 1412. https://doi.org/10.3390/polym11091412
Liu X, Zhou M, Zhou X, Wang L, Liu X. Functionalized Poly(arylene ether nitrile) Porous Membrane with High Pb(II) Adsorption Performance. Polymers. 2019; 11(9):1412. https://doi.org/10.3390/polym11091412
Chicago/Turabian StyleLiu, Xiaocan, Meirong Zhou, Xuefei Zhou, Lingling Wang, and Xiaobo Liu. 2019. "Functionalized Poly(arylene ether nitrile) Porous Membrane with High Pb(II) Adsorption Performance" Polymers 11, no. 9: 1412. https://doi.org/10.3390/polym11091412