Exploring the Topological Landscape Exhibited by Binary Zinc-triad 1,1-dithiolates
Abstract
:1. Introduction
2. Methodology and Organisation
3. Discussion
3.1. Zinc-Triad Binary Xanthate Structures
3.1.1. Zinc Xanthates
3.1.2. Cadmium Xanthates
3.1.3. Mercury Xanthates
3.2. Zinc-Triad Binary Dithiophosphate Structures
3.2.1. Zinc Dithiophosphates
3.2.2. Cadmium Dithiophosphates
3.2.3. Mercury Dithiophosphates
3.3. Zinc-Triad Binary Dithiocarbamate Structures
3.3.1. Zinc Dithiocarbamates
3.3.2. Cadmium Dithiocarbamates
3.3.3. Mercury Dithiocarbamates
4. Overview and Conclusions
Acknowledgments
Conflicts of Interest
References and Notes
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Compound | R/R’ | Donor set | Motif | Designation | Ref. |
---|---|---|---|---|---|
1 | Et | S4 | layer | A | [22] |
2 | n-Pr | S4 | chain | B | [23] |
3 | i-Pr | S4 | tetramer | C | [24] |
41 | n-Bu | S4 | tetramer | C | [25] |
5 | Me | S6 | chain | D | [26] |
62 | Et | S4 | layer | A | [27] |
73 | Et | S4 | layer | A | [28] |
8 | i-Pr | S4 | layer | A | [29,30] |
9 | n-Bu | S4 | layer | A | [31] |
10 | CH2CH2OMe | S6 | chain | D | [32] |
11 | Me | S3 | chain | E | [33] |
124 | Et | S4 | layer | A | [34] |
133 | Et | S4 | layer | A | [35] |
14 | n-Pr | S4 | layer | A | [36] |
15 | i-Pr | S4 | layer | F | [37] |
16 | n-Bu | S4 | layer | A | [38] |
17 | (CH2)2C(H)Me2 | S4 | layer | A | [38] |
18 | (CH2)2CMe3 | S4 | layer | A | [38] |
19 | Pent | S4 | layer | A | [38] |
20 | C(H)[(CH2)2]2NCH2Ph | S5 | chain | G | [39] |
Compound | R | Donor set | Motif | Designation | Ref. |
---|---|---|---|---|---|
21 | Me | S4 | H | chain | [51] |
22 | i-Pr | S4 | I | dimer | [52] |
23 | i-Bu | S4 | I | dimer | [53] |
24 | Cy | S4 | I | dimer | [54] |
25 | Me | S4 | J | chain | [55] |
26 | n-Pr | S4 | J | chain | [56] |
27 | i-Pr | S4 | I | dimer | [52] |
28 | n-Bu | S4 | J | chain | [56] |
29 | i-Bu | S4 | J | chain | [57] |
30 | s-Bu | S4 | I | dimer | [58] |
31 | Cy | S4 | K | dimer | [59] |
32 | Me | S4 | A | layer | [60] |
331 | i-Pr | S4 | L | chain | [61] |
342 | i-Pr | S4 | L | chain | [62] |
35 | c-Pentyl | S4 | L | chain | [63] |
Compound | R/R’ | Donor Set | Motif | Designation | Ref. |
---|---|---|---|---|---|
36 | CH2CH2OMe/CH2CH2OMe | S4 | M | monomer | [64] |
37 | Cy/Cy | S4 | M | monomer | [25] |
38 | Benzyl/Benzyl | S4 | M | monomer | [65] |
39 | Me/Cy | S4 | M | monomer | [66] |
40 | n-Pr/CH(Me)Et | S4 | M | monomer | [67] |
41 | NRR’ = 3,4-dihydroquinoline | S4 | M | monomer | [68] |
42 | n-Bu/5-t-Bu-3-Me-2-OH-benzyl | S4 | M | monomer | [69] |
43 | CH2CH2OH/CH2(ferrocenyl) | S4 | M | monomer | [70] |
44 | (CH2)3OEt/3,5-di-t-Bu-4-OH-benzyl | S4 | M | monomer | [71] |
45 | Benzyl/CH2(1-Me-pyrrol-2-yl) | S4 | M | monomer | [72] |
46 | Benzyl/4-OMe-benzyl | S4 | M | monomer | [73] |
47 | Benzyl/R1 1 | S4 | M | monomer | [74] |
48 | CH2(4-OMe-phenyl)/CH2(2-furyl) | S4 | M | monomer | [75] |
49 | Me/Me | S4 + 1 | N | dimer | [76] |
502 | n-Bu/n-Bu | S4 + 1 | N | dimer | [77] |
513 | n-Bu/n-Bu | S4 + 1 | N | dimer | [78] |
52 | Me/CH2(ferrocenyl) | S4 + 1 | N | dimer | [74] |
53 | Et/Et | S4 + 1 | O | dimer | [79] |
54 | n-Pr/n-Pr | S4 + 1 | O | dimer | [80] |
55 | i-Pr/i-Pr | S4 + 1 | O | dimer | [81] |
56 | CH2C(H)=CH2/CH2C(H)=CH2 | S4 + 1 | O | dimer | [82] |
574 | CH2CH2OH/CH2CH2OH | S4 + 1 | O | dimer | [83] |
582 | CH2CH2OH/CH2CH2OH | S4 + 1 | O | dimer | [84] |
595 | CH2CH2OH/CH2CH2OH | S4 + 1 | O | dimer | [85] |
60 | R + R’ = (CH2)4 | S4 + 1 | O | dimer | [86] |
61 | R + R’ = (CH2)5 | S4 + 1 | O | dimer | [87] |
62 | R + R’ = (CH2)6 | S4 + 1 | O | dimer | [88] |
63 | R + R’ = (CH2)5-4-Me | S4 + 1 | O | dimer | [89] |
64 | R + R’ = (CH2)5-4-C(=O)OEt | S4 + 1 | O | dimer | [72] |
656 | R + R’ = (CH2)5-4-C(=O)ON[C(=O)CH2]2 | S4 + 1 | O | dimer | [90] |
66 | R + R’ = (CH2CH2)2NEt | S4 + 1 | O | dimer | [91] |
67 | R + R’ = (CH2CH2)2NPh | S4 + 1 | O | dimer | [92] |
68 | R + R’ = (CH2CH2)2NC6H4-3-OMe | S4 + 1 | O | dimer | [93] |
69 | R + R’ = (CH2CH2)2NC6H4-4-OMe | S4 + 1 | O | dimer | [93] |
70 | Me/Et | S4 + 1 | O | dimer | [94] |
71 | Me/n-Pr | S4 + 1 | O | dimer | [94] |
72 | Me/i-Pr | S4 + 1 | O | dimer | [94] |
73 | Me/n-Bu | S4 + 1 | O | dimer | [94] |
74 | Me/Ph | S4 + 1 | O | dimer | [95] |
757 | Me/CH2CH2OH | S4 + 1 | O | dimer | [96] |
768 | Me/CH2CH2OH | S4 + 1 | O | dimer | [83] |
77 | Me/CH2C(=O)OMe | S4 + 1 | O | dimer | [97] |
78 | Me/CH2C(H)(OMe)2 | S4 + 1 | O | dimer | [98] |
799 | Me/R2 9 | S4 + 1 | O | dimer | [74] |
80 | Et/i-Pr | S4 + 1 | O | dimer | [99] |
81 | Et/n-Bu | S4 + 1 | O | dimer | [100] |
82 | Et/Cy | S4 + 1 | O | dimer | [25] |
833 | Et/Ph | S4 + 1 | O | dimer | [101] |
845 | Et/Ph | S4 + 1 | O | dimer | [102] |
85 | Et/CH2CH2OH | S4 + 1 | O | dimer | [83] |
86 | n-Pr/i-Pr | S4 + 1 | O | dimer | [103] |
8710 | i-Pr/CH2CH2OH | S4 + 1 | O | dimer | [96] |
88 | c-Pr/CH2C6H4-4-OMe | S4 + 1 | O | dimer | [104] |
89 | n-Bu/Ph | S4 + 1 | O | dimer | [105] |
90 | Benzyl/(CH2)13Me | S4 + 1 | O | dimer | [106] |
919 | Benzyl/R2 9 | S4 + 1 | O | dimer | [74] |
92 | CH2(2-furyl)/CH2C6H4-4-Cl | S4 + 1 | O | dimer | [75] |
93 | CH2(2-furyl)/R2 9 | S4 + 1 | O | dimer | [74] |
94 | CH2C6H4-4-OMe/(CH2)2N(CH2CH2)2O | S4 + 1 | O | dimer | [74] |
95 | i-Bu/i-Bu | S4 | M | monomer | [107] |
S4 + 1 | O | ||||
96 | R + R’ = (CH2)4NMe | NS4 | P | polymer | [108] |
9711 | Benzyl/CH2(3-py) | NS4 | Q | dimer | [72] |
98 | CH2(ferrocenyl)/CH2(3-py) | NS4 | Q | dimer | [109] |
9912 | Et/CH2(4-py) | NS4 | P | polymer | [110] |
10013 | CH2(ferrocenyl)/CH2(4-py) | N2S4 | R | layer | [109] |
Compound | R/R’ | Donor set | Motif | Designation | Ref. |
---|---|---|---|---|---|
101 | n-Bu/n-Bu | S5 | N | dimer | [111] |
102 | Et/Et | S5 | O | dimer | [112,113] |
103 | n-Pr/n-Pr | S5 | O | dimer | [114] |
104 | i-Pr/i-Pr | S5 | O | dimer | [115] |
105 | CH2C(H)=CH2/CH2C(H)=CH2 | S5 | O | dimer | [116] |
106 | i-Bu/i-Bu | S5 | O | dimer | [117] |
1071 | Cy/Cy | S5 | O | dimer | [118] |
1082 | Benzyl/Benzyl | S5 | O | dimer | [119] |
1093 | Benzyl/Benzyl | S5 | O | dimer | [120] |
110 | CH2CH2OH/CH2CH2OH | S5 | O | dimer | [121] |
111 | R + R’ = (CH2)5 | S5 | O | dimer | [122] |
112 4 | R + R’ = (CH2)5 | S5 | O | dimer | [123] |
113 | R + R’ = (CH2)5Me | S5 | O | dimer | [124] |
114 | R + R’ = (CH2)6 | S5 | O | dimer | [125] |
115 | Me/Ph | S5 | O | dimer | [126] |
116 | Et/Cy | S5 | O | dimer | [118] |
117 | n-Pr/i-Pr | S5 | O | dimer | [127] |
1185 | i-Pr/CH2CH2OH | S5 | O | dimer | [128] |
1196 | i-Pr/CH2CH2OH | S5 | O | dimer | [129] |
1207 | i-Pr/CH2CH2OH | S5 | O | dimer | [129] |
121 | Benzyl/CH2(2-furyl) | S5 | O | dimer | [130] |
122 | Benzyl/CH2C6H4-3-Cl | S5 | O | dimer | [131] |
123 | Benzyl/CH2C6H4-4-Cl | S5 | O | dimer | [73] |
124 | Me/(CH2)3NMe2 | NS4 | Q | dimer | [132] |
125 | CH2(3-py)/R1 8 | NS4 | Q | dimer | [133] |
126 | CH2C6H4-4-Cl/CH2(furyl) | 2 × S5 + S6 | S | trimer | [131] |
127 | CH2C6H4-4-Me/CH2(furyl) | 2 × S5 + S6 | S | trimer | [133] |
128 | Me/(CH2)2NMe2 | NS4 | T | polymer | [134] |
1299 | Et/CH2(4-py) | N2S4 | U | double-layer | [135] |
130 | Benzyl/CH2(3-py) | N2S4 | R | layer | [133] |
131 | CH2(furyl)/CH2(3-py) | N2S4 | R | layer | [133] |
132 | CH2(thiophen-2-yl)/CH2(3-py) | N2S4 | R | layer | [133] |
133 | CH2(ferrocenyl)/CH2(3-py) | N2S4 | R | layer | [109] |
134 | CH2(3-py)/CH2(3-py) | N2S4 | R | layer | [133] |
135 | Me/Me | S6 | V | polymer | [136] |
13610 | i-Pr/CH2CH2OH | S6 | V | polymer | [129] |
137 | Benzyl/R2 11 | S6 | V | polymer | [131] |
138 | CH2(furyl)/CH2C6H4-4-F | S6 | V | polymer | [131] |
139 | CH2(furyl)/CH2C6H4-4-NO2 | S6 | V | polymer | [131] |
140 | Me/CH2C(H)(OMe)2 | S6 | W | polymer | [98] |
14112 | i-Pr/CH2CH2OH | S6 | W | polymer | [128] |
Compound | R/R’ | Donor Set | Motif | Designation | Ref. |
---|---|---|---|---|---|
142 | i-Pr/i-Pr | S4 | M | monomer | [139] |
143 | Cy/Cy | S4 | M | monomer | [140] |
144 | Benzyl/Benzyl | S4 | M | monomer | [141] |
145 | R + R’ = (CH2)4 | S4 | M | monomer | [142] |
146 | i-Bu/i-Bu | S4 | K | monomer | [143] |
147 | R + R’ = (CH2)4NCH2C(H)=C(H)Ph | S4 | M | monomer | [144] |
148 | N(RR’) = R1 1 | S4 | M | monomer | [145] |
1492 | Et/Ph | S4 | M | monomer | [101] |
150 | i-Pr/Cy | S4 | M | monomer | [143] |
1513 | Me/Ph; n-Bu/Ph | S4 | M | monomer | [105] |
152 | Benzyl/CH2(1-Me-1H-pyrrol-2-yl) | S4 | M | monomer | [146] |
153 | Benzyl/CH2(ferrocenyl) | S4 | M | monomer | [147] |
154 | CH2(3-py)/CH2(1-Me-1H-pyrrol-2-yl) | S4 | M | monomer | [39] |
155 | CH2CH2OH/CH2(ferrocenyl) | S4 | M | monomer | [70] |
156 | Me/Me | S4 | X | monomer | [148] |
157 | Et/Et | S4 | X | monomer | [149] |
158 | Benzyl/CH2(3-py) | S4 | X | monomer | [72] |
159 | Benzyl/CH2(4-py) | S4 | X | monomer | [150] |
160 | CH2CH2OH/CH2CH2OH | S4 | X | monomer | [151] |
161 | n-Bu/CH2(1H-pyrrol-2-yl) | S4 | Y | monomer | [152] |
162 | CH2(4-py)/CH2(1H-pyrrol-2-yl) | S4 | Z | monomer | [146] |
163 | Et/Et | S4 + 1 | O | dimer | [149,153] |
164 | i-Pr/i-Pr | S4 + 1 | O | dimer | [154] |
165 | n-Bu/n-Bu | S4 + 1 | N | dimer | [143] |
166 | R + R’ = (CH2)4 | S4 + 1 | O | dimer | [155] |
167 | R + R’ = (CH2)5Me | S4 + 1 | O | dimer | [156] |
168 | R + R’ = (CH2)6 | S4 + 1 | O | dimer | [157] |
169 | CH2(2-furyl)/CH2(2-furyl) | S4 + 1 | O | dimer | [158] |
170 | Me/Ph | S4 + 1 | O | dimer | [159] |
171 | Me/(CH2)2Ph | S4 + 1 | O | dimer | [160] |
172 | Et/Cy | S4 + 1 | O | dimer | [143] |
173 | Et/Ph | S4 + 1 | O | dimer | [161] |
174 | i-Pr/CH2CH2OH | S4 + 1 | O | dimer | [162] |
175 | Benzyl/CH2(2-furyl) | S4 + 1 | O | dimer | [158] |
176 | (CH2)2Ph/CH2(2-furyl) | S4 + 1 | O | dimer | [163] |
177 | (CH2)2Ph/CH2CH2(thiophen-2-yl) | S4 + 1 | O | dimer | [163] |
178 | CH2(3-py)/CH2(ferrocenyl) | S4 + 1 | O | dimer | [109] |
1793 | CH2(3-py)/CH2(1-naphthyl) | NS4 | Q | dimer | [39] |
1804 | NRR’ = R2 5 | 2 × S5 + S6 | S | trimer | [145] |
181 | Me/CH2(4-py) | NS4 | Z | polymer | [72] |
182 | CH2(3-py)/CH2(1,3-benzodioxo-5-yl) | NS4 | P | polymer | [72] |
183 | CH2(4-py)/CH2(2-furyl) | N2S4 | R | layer | [72] |
184 | (CH2)2Ph/CH2(3-py) | NS5 | AA | polymer | [72] |
185 | (CH2)2Ph/CH143(1H-pyrrol-2-yl) | S6 | V | polymer | [152] |
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Tiekink, E.R.T. Exploring the Topological Landscape Exhibited by Binary Zinc-triad 1,1-dithiolates. Crystals 2018, 8, 292. https://doi.org/10.3390/cryst8070292
Tiekink ERT. Exploring the Topological Landscape Exhibited by Binary Zinc-triad 1,1-dithiolates. Crystals. 2018; 8(7):292. https://doi.org/10.3390/cryst8070292
Chicago/Turabian StyleTiekink, Edward R.T. 2018. "Exploring the Topological Landscape Exhibited by Binary Zinc-triad 1,1-dithiolates" Crystals 8, no. 7: 292. https://doi.org/10.3390/cryst8070292