Hydrogen-Bonding Motifs in Piperazinediium Salts
Abstract
:1. Introduction
2. Results and Discussion
2.1. p-Toluenesulfonate Structures
1 | 2 | ||||||
---|---|---|---|---|---|---|---|
Interaction | D···A (Å) | H···A (Å) | D–H···A (°) | Interaction | D···A (Å) | H···A (Å) | D–H···A (°) |
N1···O1 | 2.9126(16) | 2.10 | 146.3 | N1···O2#3 | 2.790(5) | 2.00 | 143.0 |
N1···O5#1 | 2.8089(17) | 1.89 | 174.1 | N1···O1#4 | 3.076(6) | 2.41 | 129.0 |
N2···O2#2 | 2.7223(17) | 1.84 | 159.5 | N1···O1 | 2.798(5) | 1.92 | 158.0 |
N2···O4 | 2.7542(15) | 1.86 | 163.0 | N1···O2#4 | 3.063(5) | 2.50 | 120.0 |
N1···O2 | 3.0536(15) | 2.50 | 114.9 | N2···O6#5 | 2.772(5) | 1.98 | 142.9 |
N1···O6 | 2.8620(16) | 2.30 | 114.9 | N2···O4 | 3.080(5) | 2.42 | 128.8 |
– | – | – | – | N2···O4#6 | 2.784(5) | 1.91 | 157.3 |
– | – | – | – | N2···O6 | 3.149(6) | 2.57 | 121.0 |
2.2. Chloroacetate Structures
3 | 4 | ||||||
---|---|---|---|---|---|---|---|
Interaction | D···A (Å) | H···A (Å) | D-H···A (°) | Interaction | D···A (Å) | H···A (Å) | D-H···A (°) |
N1···O2 | 2.7517(17) | 1.85 | 165.6 | N1···O1 | 2.741(2) | 1.76 | 172.4 |
N1···O1#1 | 2.6915(16) | 1.78 | 169.2 | N1···O2#2 | 2.741(2) | 1.76 | 171.7 |
– | – | – | – | N2···O3 | 2.727(2) | 1.75 | 169.8 |
– | – | – | – | N2···O4#2 | 2.713(2) | 1.73 | 174.8 |
3. Experimental Section
3.1. Synthesis
3.2. X-Ray Crystallography
Compound | 1 AT10 | 2 CC10 | 3 AT14 | 4 CC14 |
---|---|---|---|---|
Formula | (H2Pip)(TsO)2 | (H2MePip)(TsO)2·½H2O | (H2Pip)(OAcCl)2 | (H2MePip)(OAcCl)2 |
Empirical Formula | C18H26N2O6S2 | C19H29N2O6.5S2 | C8H16Cl2N2O4 | C9H18Cl2N2O4 |
Formula Mass | 430.53 | 453.56 | 275.13 | 289.15 |
Crystal System | Triclinic | Monoclinic | Triclinic | Monoclinic |
Space Group | P-1 | Pc | P-1 | P21/c |
a/Å | 5.9020(12) | 14.584(3) | 5.6260(11) | 5.7050(11) |
b/Å | 13.059(3) | 9.863(2) | 7.2100(14) | 29.975(6) |
c/Å | 13.581(3 | 7.6460(15) | 7.5280(15) | 7.5280(15) |
α/° | 73.55(3) | 90 | 77.60(3) | 90 |
β/° | 86.00(3) | 100.89(3) | 80.83(3) | 97.26(3) |
γ/° | 84.09(3) | 90 | 85.29(3) | 90 |
V/Å3 | 997.7(3) | 1080.0(4) | 294.07(10) | 1277.0(4) |
μ/mm−1 | 0.305 | 0.284 | 0.553 | 0.514 |
Refs. Collected | 36824 | 11230 | 11028 | 23550 |
Theta Range | 1.56–31.54 | 2.71–31.50 | 2.80–31.49 | 1.36–31.51 |
Unique Refs. (Rint) | 5606 (0.0660) | 5649 (0.0779) | 1660 (0.0706) | 3548 (0.0460) |
Obs. Refs. (I > 2σI) | 5391 | 5038 | 1557 | 3414 |
R1 (I > 2σI/all data) | 0.0386/0.0399 | 0.0786/0.0834 | 0.0361/0.0379 | 0.0473/0.0486 |
wR2 (I > 2σI/all data) | 0.1027/0.1040 | 0.2118/0.2184 | 0.0940/0.0950 | 0.1130/0.1137 |
GooF | 1.077 | 1.081 | 1.120 | 1.122 |
4. Conclusions
Acknowledgments
Conflicts of Interest
References
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Hawes, C.S.; Chen, C.; Tran, A.; Turner, D.R. Hydrogen-Bonding Motifs in Piperazinediium Salts. Crystals 2014, 4, 53-63. https://doi.org/10.3390/cryst4010053
Hawes CS, Chen C, Tran A, Turner DR. Hydrogen-Bonding Motifs in Piperazinediium Salts. Crystals. 2014; 4(1):53-63. https://doi.org/10.3390/cryst4010053
Chicago/Turabian StyleHawes, Chris S., Cherry Chen, Andrew Tran, and David R. Turner. 2014. "Hydrogen-Bonding Motifs in Piperazinediium Salts" Crystals 4, no. 1: 53-63. https://doi.org/10.3390/cryst4010053
APA StyleHawes, C. S., Chen, C., Tran, A., & Turner, D. R. (2014). Hydrogen-Bonding Motifs in Piperazinediium Salts. Crystals, 4(1), 53-63. https://doi.org/10.3390/cryst4010053