Curcumin Incorporation into Zn3Al Layered Double Hydroxides—Preparation, Characterization and Curcumin Release
Abstract
:1. Introduction
2. Materials and Methods
3. Results
3.1. Characterization of the Curcumin Containing Zn3Al-LDHs
3.1.1. Chemical Composition
3.1.2. XRD Characterization of CR Functionalized Zn3Al-LDH Samples
3.1.3. ATR-FTIR Characterization
3.1.4. DR-UV–Vis Characterization
3.2. Curcumin Release Studies
4. Discussion
5. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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Sample | Zn (wt. %) | Al (wt. %) | CO3 (wt. %) 1 | CR (wt. %) 2 | H2O (wt. %) 3 | Molar Ratio | |
---|---|---|---|---|---|---|---|
Zn/Al | CR/Al | ||||||
Zn3Al-LDH | 46.2 | 6.4 | 7.1 | 0 | 8.5 | 2.97 | 0 |
PZn3Al-CR(Aq) | 49.9 | 7.2 | 2.8 | 12.1 | 8.9 | 2.86 | 1/8.5 |
PZn3Al-CR(Et) | 48.1 | 6.8 | 1.7 | 9.3 | 8.8 | 2.90 | 1/10 |
RZn3Al-CR(Aq) | 51.1 | 7.2 | 1.2 | 10.0 | 5.6 | 2.91 | 1/9.9 |
RZn3Al-CR(Et) | 60.3 | 8.4 | 0.2 | 11.5 | 2.9 | 2.97 | 1/9.9 |
Samples | LDH Phase | ZnO Phase | ||||||||
---|---|---|---|---|---|---|---|---|---|---|
a (Å) | c (Å) | I003/I110 | D110 (nm) | D003 (nm) | a (Å) | c (Å) | Vol (Å3) | D (nm) | ZnO (%) | |
Zn3Al-LDH | 3.075(2) | 22.9026 | 7.66 | 35.6 | 23.4 | |||||
RZn3Al-LDH 1 | 3.07(2) | 22.84(7) | 5.10 | 16.6 | 8.9 | 3.243(2) | 5.183(6) | 47.21 | 13.2 | 42 |
PZn3Al-CR(Aq) | 3.061(5) | 22.56(4) | 7.71 | 24.4 | 20.2 | 3.251(6) | 5.21(1) | 47.69 | 12.0 | 45 |
PZn3Al-CR(Et) | 3.071(6) | 22.99(7) | 3.37 | 21.9 | 11.9 | 3.262(4) | 5.20(1) | 47.92 | 11.6 | 22 |
25.476(11) | 1.34 | 3.9 | ||||||||
RZn3Al-CR(Aq) | 3.071(4) | 22.62(5) | 5.88 | 26.7 | 16.5 | 3.263(9) | 5.21(3) | 48.04 | 11.3 | 41 |
RZn3Al-CR(Et) | 3.234(2) | 5.238(3) | 47.44 | 5.3 | 100 |
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Pavel, O.D.; Şerban, A.; Zăvoianu, R.; Bacalum, E.; Bîrjega, R. Curcumin Incorporation into Zn3Al Layered Double Hydroxides—Preparation, Characterization and Curcumin Release. Crystals 2020, 10, 244. https://doi.org/10.3390/cryst10040244
Pavel OD, Şerban A, Zăvoianu R, Bacalum E, Bîrjega R. Curcumin Incorporation into Zn3Al Layered Double Hydroxides—Preparation, Characterization and Curcumin Release. Crystals. 2020; 10(4):244. https://doi.org/10.3390/cryst10040244
Chicago/Turabian StylePavel, Octavian D., Ariana Şerban, Rodica Zăvoianu, Elena Bacalum, and Ruxandra Bîrjega. 2020. "Curcumin Incorporation into Zn3Al Layered Double Hydroxides—Preparation, Characterization and Curcumin Release" Crystals 10, no. 4: 244. https://doi.org/10.3390/cryst10040244