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Recent Advances in Acyl Suzuki Cross-Coupling

Department of Chemistry, Rutgers University, 73 Warren Street, Newark, NJ 07102, USA
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Catalysts 2019, 9(1), 53; https://doi.org/10.3390/catal9010053
Received: 17 December 2018 / Accepted: 28 December 2018 / Published: 8 January 2019
(This article belongs to the Section Catalysis in Organic and Polymer Chemistry)
Acyl Suzuki cross-coupling involves the coupling of an organoboron reagent with an acyl electrophile (acyl halide, anhydride, ester, amide). This review provides a timely overview of the very important advances that have recently taken place in the acylative Suzuki cross-coupling. Particular emphasis is directed toward the type of acyl electrophiles, catalyst systems and new cross-coupling partners. This review will be of value to synthetic chemists involved in this rapidly developing field of Suzuki cross-coupling as well as those interested in using acylative Suzuki cross-coupling for the synthesis of ketones as a catalytic alternative to stoichiometric nucleophilic additions or Friedel-Crafts reactions. View Full-Text
Keywords: Suzuki cross-coupling; acyl cross-coupling; acylation; ketones; acylative cross-coupling; palladium; nickel; phosphine; N-heterocyclic carbene; Suzuki-Miyaura Suzuki cross-coupling; acyl cross-coupling; acylation; ketones; acylative cross-coupling; palladium; nickel; phosphine; N-heterocyclic carbene; Suzuki-Miyaura
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MDPI and ACS Style

Buchspies, J.; Szostak, M. Recent Advances in Acyl Suzuki Cross-Coupling. Catalysts 2019, 9, 53.

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