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Catalysts 2019, 9(1), 53; https://doi.org/10.3390/catal9010053

Recent Advances in Acyl Suzuki Cross-Coupling

Department of Chemistry, Rutgers University, 73 Warren Street, Newark, NJ 07102, USA
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Author to whom correspondence should be addressed.
Received: 17 December 2018 / Accepted: 28 December 2018 / Published: 8 January 2019
(This article belongs to the Section Catalysis in Organic and Polymer Chemistry)

Abstract

Acyl Suzuki cross-coupling involves the coupling of an organoboron reagent with an acyl electrophile (acyl halide, anhydride, ester, amide). This review provides a timely overview of the very important advances that have recently taken place in the acylative Suzuki cross-coupling. Particular emphasis is directed toward the type of acyl electrophiles, catalyst systems and new cross-coupling partners. This review will be of value to synthetic chemists involved in this rapidly developing field of Suzuki cross-coupling as well as those interested in using acylative Suzuki cross-coupling for the synthesis of ketones as a catalytic alternative to stoichiometric nucleophilic additions or Friedel-Crafts reactions. View Full-Text
Keywords: Suzuki cross-coupling; acyl cross-coupling; acylation; ketones; acylative cross-coupling; palladium; nickel; phosphine; N-heterocyclic carbene; Suzuki-Miyaura Suzuki cross-coupling; acyl cross-coupling; acylation; ketones; acylative cross-coupling; palladium; nickel; phosphine; N-heterocyclic carbene; Suzuki-Miyaura
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).
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Buchspies, J.; Szostak, M. Recent Advances in Acyl Suzuki Cross-Coupling. Catalysts 2019, 9, 53.

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