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Catalyst Deactivation and Regeneration Processes in Biogas Tri-Reforming Process. The Effect of Hydrogen Sulfide Addition

Faculty of Engineering, University of the Basque Country (UPV-EHU), 48013 Bilbao, Spain
Edp Naturgas Energía, c/General Concha, 20, 48010 Bilbao, Spain
Author to whom correspondence should be addressed.
Catalysts 2018, 8(1), 12;
Received: 22 September 2017 / Revised: 3 January 2018 / Accepted: 4 January 2018 / Published: 9 January 2018
This work studies Ni-based catalyst deactivation and regeneration processes in the presence of H2S under a biogas tri-reforming process for hydrogen production, which is an energy vector of great interest. 25 ppm of hydrogen sulfide were continuously added to the system in order to provoke an observable catalyst deactivation, and once fully deactivated two different regeneration processes were studied: a self-regeneration and a regeneration by low temperature oxidation. For that purpose, several Ni-based catalysts and a bimetallic Rh-Ni catalyst supported on alumina modified with CeO2 and ZrO2 were used as well as a commercial Katalco 57-5 for comparison purposes. Ni/Ce-Al2O3 and Ni/Ce-Zr-Al2O3 catalysts almost recovered their initial activity. For these catalysts, after the regeneration under oxidative conditions at low temperature, the CO2 conversions achieved—79.5% and 86.9%, respectively—were significantly higher than the ones obtained before sulfur poisoning—66.7% and 45.2%, respectively. This effect could be attributed to the support modification with CeO2 and the higher selectivity achieved for the Reverse Water-Gas-Shift (rWGS) reaction after catalysts deactivation. As expected, the bimetallic Rh-Ni/Ce-Al2O3 catalyst showed higher resistance to deactivation and its sulfur poisoning seems to be reversible. In the case of the commercial and Ni/Zr-Al2O3 catalysts, they did not recover their activity. View Full-Text
Keywords: hydrogen; reforming; deactivation; regeneration; biogas hydrogen; reforming; deactivation; regeneration; biogas
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Izquierdo, U.; García-García, I.; Gutierrez, Á.M.; Arraibi, J.R.; Barrio, V.L.; Cambra, J.F.; Arias, P.L. Catalyst Deactivation and Regeneration Processes in Biogas Tri-Reforming Process. The Effect of Hydrogen Sulfide Addition. Catalysts 2018, 8, 12.

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