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Article

Environmental Analysis of the Use of Liquefied Natural Gas in Maritime Transport within the Port Environment

by
Tomas Gil-Lopez
and
Amparo Verdu-Vazquez
*
Building Technology Department, Universidad Politécnica de Madrid, 28040 Madrid, Spain
*
Author to whom correspondence should be addressed.
Sustainability 2021, 13(21), 11989; https://doi.org/10.3390/su132111989
Submission received: 15 September 2021 / Revised: 18 October 2021 / Accepted: 24 October 2021 / Published: 29 October 2021

Abstract

:
Sustainable transport is gaining increasing importance in the political agenda. All modes of transport are obliged to reduce their emissions by both national and international governmental bodies, this requirement being even more necessary in the case of ports due to their traffic density and proximity to the city. The objective of this research is to estimate the atmospheric emissions generated during the operational phases, which are carried out close to Spanish ports. Due to its geographical position, Spain benefits from the routes of the Atlantic corridor and Mediterranean corridor belonging to the principal European transport network. The method uses detailed information about ship movements and ship categories (ship type, engine type, fuel type, etc.). From an environmental point of view, the results show that engines powered by Liquefied Natural Gas, compared to traditional fuels, save between 28% in the case of freight ships and 31% for passenger ships in the emission of CO2 into the atmosphere (52 tons per journey). On the other hand, the saving in NOx emissions is reduced by 87%. In addition, SOx emissions are completely eliminated and PM emissions are reduced to negligible values.

1. Introduction

The transport sector was responsible for approximately 59% of total end-use sector liquid fuel consumption in 2018 [1]. Specifically, the marine industry consumes over 11% of transport fuels [2,3,4]. There are various research projects proving that maritime transport generates a large amount of pollutants, which are released into the atmosphere [5,6,7,8]. Although maritime transport is not the main factor increasing climate change caused by Greenhouse Gas (GHG) emissions, the maritime transport sector should assess the options for achieving a reduction in anthropogenic GHG emissions so as to highlight it as an environmentally sound mode of transportation [9,10,11,12,13].
Many of the different emission types produced by ships are directly related to their fuel consumption. None more so than air emissions, which are generated during the combustion process [14]. Although the main engines (MEs) used for ship propulsion at sea create the most emissions, emissions from the smaller auxiliary engines (AEs), used for generating electricity on board, cannot be overlooked. Such emissions are produced when ships are stationary (with MEs shut down) and at berth in ports close to population centers. Once in port, the power requirement is generally lower but can still vary depending on the type of ship activity, for example, hoteling, loading operations. Since most marine emission studies have focused upon ME operation, there is currently a widespread lack of knowledge regarding AE operations and the associated emissions [15].
The main and auxiliary engines account for most of the emissions from vessels [16]. The evolution of global CO2 emissions from commercial shipping using traditional fuels has seen an increase from 360 million tons in 1990 (1.72% of the total) to 938 million tons in 2012 (2.61% of the total and 22.32% of transport emissions) [17]. Emission scenario calculations up to the year 2050 reveal that a significant increase is to be expected in the future if ship emissions remain unabated, with CO2 reduction appearing to be the most challenging [12,18]. CO2 emissions from international shipping are based on the bunker fuels sold. While it may be said that this is not the amount of CO2 being emitted in Spanish ports, no exact figures have been available until now. For SO2 and NOx emissions from marine fuels, the same is true: no specific data for Spain were available.
Ship emission externalities refer mainly to acidification and eutrophication, and their impact on global warming and human health. It is worth highlighting the health problems caused by the high concentration of CO2 in port workers, both in open and closed spaces, since the air conditioning systems take polluted air from the outside to be used as fresh air, reducing the predicted percentage of dissatisfied (PPD) [19,20].
In order to regulate the level of pollutants, international regulations are increasingly strict, limiting NOx and SOx emissions and particulates from ships [21,22]. International maritime regulation is carried out through conventions from the International Maritime Organization (IMO), through the IGF [23] and IGC [24] codes, ISPS [25] and IBC [26] conventions, as well as the standards of the International Organization for Standardization [27]. In line with the MARPOL international convention, Sulfur Emission Control Areas (SECAs) [28] have been created. The limit of 0.1% sulfur content in marine fuels is applicable from 1 January 2015 [14,29,30,31]. According to Annex VI of Marpol [32,33], the regulations will be applicable not only to new builds but also to existing ships [34].
There are three options to ensure that maritime transport complies with the SECA emission restrictions: the use of low-sulfur fuels, the installation of catalytic converters (SCR) or scrubbers to cleanse exhaust gases in existing engines, and the use of alternative fuels such as biofuels, natural gas, methanol, hydrogen and so forth [35,36]. Each technology has advantages and disadvantages [37,38,39,40,41]. The first option, using low-sulfur fuels, has the advantage of being viable for both new vessels and the adaptation of old ones, and it requires less engine maintenance. The second option, mainly for ships that are in use today, is the installation of scrubbers. This technology is also viable for both new vessels and for adapting old ones. However, the drawbacks, other than the price that it entails (it may amount to 3 million euros, depending on the type of vessel), are being forced to moor the ship in the shipyard for the time it takes to install it, the high demand for space, increased weight of the vessel and production of hazardous liquid waste [42,43,44,45,46]. Furthermore, the reduction of NOx is insignificant [47]. The third option is to use alternative fuels. Currently, mainly two types of fuel are used in shipping: HFO (Heavy Fuel Oil) and MDO (Marine Diesel Oil), the use of MGO (Marine Gas Oil) being limited to the engine start phase and port stays. In the open sea, in general, HFO is used, which causes more pollution than MDO, whilst local and coastal navigation generally uses MDO, which is more expensive than HFO. Liquefied Natural Gas (LNG) emerges as an alternative to HFO and MDO [48,49].
The European Union has clearly opted for LNG as a short and medium-term solution for maritime transport [22,50]. The price of LNG is closer to that of HFO but it produces less pollutant emissions than MDO. The ecological interest in LNG is evident in view of the comparison of the ecological footprint with that of MDO and, above all, with that of HFO [51]. LNG is becoming increasingly popular as a marine fuel as emission regulations become more stringent [52].
One factor that is delaying the development of LNG consumption by ships is the lack of supply infrastructure in all ports [47,53,54], in addition to other factors such as transportation of large quantities of LNG under IMDG Code. However, gas supply companies are already making significant investments in order to adapt the port terminals of the most developed countries [55]. Currently, Spain moves 45,000 LNG tankers per year and has 10,900 km of pipelines [56].
The current notion of the port tends to support the integration of the port and the city [57,58,59]. Due to the fact that many major ports are also major cities, the harbor and near-harbor emissions of seagoing ships that influence local air quality may directly affect a large population [60,61,62]. While the long-range transmission of air pollutants is important, pollution is generally more harmful—relative to the emitted amounts—when it is emitted near vulnerable receptors.
Some years ago, numerous results indicated that air pollution levels in port areas were comparable with those of land. However, the current situation is worse because emissions from ships have significantly increased due to the rise in international maritime trade in recent years [16,30,63,64,65,66,67]. Emissions from liquefied natural gas (LNG) vehicles play an increasingly important role in urban air quality, due to fuel transition from gasoline/diesel to alternative fuels [68].
Due to its geographical position, Spain will benefit from the scheduled Atlantic and Mediterranean Core Network Corridors (Figure 1) belonging to the future Trans European Transport Network [58,59,60,61,62,63,64,65,66,67,69]. Some Spanish ports are suffering serious air pollution [56]. The case of Spain is of particular interest mainly due to the fact that the dense ship traffic within Spanish ports and its associated exhaust emission pollutants have a direct impaction highly populated cities (the same as in many other countries). As such, quantifying the effect of exhaust emissions from ships will become extremely important.
Limited knowledge is available concerning the exhaust emissions from ship engines in Spanish ports and the effects of these emissions on air quality in nearby urban regions. This issue is of growing significance because of the increased regulation of land based emissions, the limited regulation of shipping emissions and planned increases in shipping activity [10].
The aim of this study is to produce a model capable of providing a comprehensive analysis of ship engine exhaust emissions in a region, which features numerous ports. The method uses detailed information concerning ship movements and ship categories (ship type, fuel type, etc.) together with the associated fuel consumption figures and emission factors. The present methodology will facilitate assessment of whether ship emissions have significant health or other environmental impacts and whether the introduction of ship emission control measures is justified. Knowledge of the proportion of emissions from the various operating modes and machinery types will also facilitate analysis. The study seeks to inform future policy making with regard to regional transportation systems, allow assessment of the effectiveness of emission mitigation measures, and enable accurate modelling of the contribution of ship emissions to the impact of climate change.

2. Materials and Methods

As mentioned above, this research focuses on the port environment. Consequently, the phases of navigation analyzed are the Approach (sailing on approach to port), Maneuver (sailing from the port to the loading bay) and Hoteling (performing loading/unloading and maintenance operations). For each of these phases, the intention is to obtain the specific consumption for both propulsion engines and auxiliary engines and the pollutant emissions released by each into the atmosphere, placing particular emphasis on CO2, due to its relationship with the greenhouse effect.
In order to achieve this, the average installed power of ship engines was obtained according to the vessel type.
In parallel to the above, the time required for the maneuvers in the port environment was calculated as well as the percentage of power used by ship engines in performing them.
Based on the previous results, the fuel consumption is calculated. Two cases of ship propulsion have been studied, in accordance with the engine fuel used:
  • Case 1: Main engines are fueled by HFO and auxiliary engines by MDO.
For the case of the propulsion system of a ship powered by fuel, a set-up powered directly by a reciprocating engine was chosen.
  • Case 2: Main and auxiliary motors are powered by LNG.
In the case of the propulsion system of a ship powered by LNG, a Dual-Fuel set-up was chosen since this is a modern technology, operating only in gas mode (injecting 1% of diesel).
Using the fuel consumption figures obtained in the two cases above, the pollutant emissions are obtained for each type of vessel.

2.1. Type of Vessels Analyzed

In carrying out this research, the classification of ships performed by TRENDS and EUROSTAT depending on the cargo they carry has been taken into account [70].
Mainly freight ships have been selected since about 90% of the volume of the world’s goods trade is transported by sea [71]. Among the freight ships, the following types have been chosen:
  • Tanker (liquids and gases)
  • Bulk Carrier (solids)
  • General Cargo (representing a wide variety, from reefers to specialized vessels and special transport)
  • Container Ship (containers)
  • RO-RO (roll-on, roll-off of wheeled cargo).
Regarding the transport of people, the Passenger Ship has been chosen as the most representative vessel.

2.2. Installed Engine Capacity

The data used in this research concerning the power of the main and auxiliary engines, engine speed and the type of vessel, have been provided by the Spanish Port Authorities [72]. This is a public entity, under the authority of the Spanish Ministry of Public Works, with overall responsibility for the entire state-owned port system. It is in charge of implementing the Spanish Government’s port policy and coordinating and controlling the efficiency of the port system, made up of 28 Port Authorities [72], which administer the 46 ports of public interest. Consequently, the information that it possesses is sufficiently reliable given that it includes the port approach maneuvers performed by ships at the main Spanish ports. The average power installed on-board is shown in Table 1.

2.3. Time Spent in the Port Environment

The duration of the Approach, Maneuver and Hoteling phases is variable since it depends on the size of the ship and the port considered. From the data provided by the Spanish port authorities, we calculated a mean value of approximately two hours for the Approach phase and one hour for the Maneuver phase, regardless of the type of vessel.
The average time spent in the docks varies depending on the type of vessel. During this phase, the auxiliary engines must generate electricity for consumption in the vessel. The results shown in Table 2, were obtained from the mean values provided by the California Air Resources Board [73].

2.4. Power Used by Engines Depending on the Operational Phase

The power required by the engine will vary depending on the phase that the vessel is in. The percentage of rated power required by the engine in each of the operational phases analyzed in this research is shown in Table 3. The values in the table were obtained from Enertrans [74].

2.5. Fuel Consumption of the Engines

Fuel consumption varies mainly depending on the type of engine, its speed and the operational phase that the boat is in. This value has been declining over time due to improved engine performance.
The average calorific value taken into account in this research is: 40,600 kJ/kg for Heavy Fuel Oil, 42,700 kJ/kg for Marine Diesel Oil and 49,200 kJ/kg for LNG [66,71].

2.5.1. Main Engine

The consumption values used in this research are shown in Table 4 [74]. The following are specific consumption values; obtained for propulsion engines by ship type and phase, on a Fuel Oil consumption basis.
These values are slightly lower than those obtained for propulsion engines by ship type and phase in previous years [32,73]. The reason is the improvement of energy efficiency in engines.

2.5.2. Auxiliary Engines

The estimated consumption for auxiliary engines has been obtained from engines manufactured by Wärtsilä [75] and MAN [76], in various models. The average consumption for auxiliary engines in 2014 could be estimated at 180 g/kWh (fuel oil), 170 g/kWh (diesel) and 126 g/kWh (LNG) [38,77].
When these values are compared with previous research, an improvement is also seen in the energy efficiency of the engines [32,74].

2.6. Pollutant Emissions of Engines

In order to calculate the emissions from ship engines we used the following expression, Equation (1) [33]:
E = P × LF × A × EF.
The emission factor is in terms of emissions per unit of energy from the engine. It is multiplied by the power needed to move the ship in a particular activity.
In a detailed inventory, emissions for each mode (approach, maneuver, and hoteling) during a call should be calculated using ship type, actual speed, engine power, load factor, time in that mode and emission factors for propulsion and auxiliary engines.
The pollutants analyzed in this research are: nitrogen oxides (NOx), sulfur oxides (SOx), carbon dioxide (CO2) and particulate matter (PM). The emission factors considered in this work depending on the type of fuel are shown in Table 5 [78].

3. Results and Discussion

3.1. Power Demand Depending on the Operating Phase

Applying the percentage to the engine power, the actual power it uses is obtained (Figure 2).
Jointly analyzing the three operational phases carried out in the port environment (Approach, Maneuver and Hoteling), the results show a higher power demand by the passenger ship compared with other vessels (53% higher). This is mainly due to the greater use of auxiliary engines in the port environment together with the associated increased power demand.
Another fact worth noting is the little power demanded in the hoteling phase for freight transport ships compared with passenger transport ships (85% increase). The fundamental reason is that the latter must be able to address the needs of passengers in port and, to a lesser extent, those of the crew. This demand is considerably reduced in a freight ship since only the crew’s needs must be met.

3.2. Fuel Consumption

According to the previous data (percentage of power used and specific engine power consumption), the fuel consumption obtained is shown in Figure 3.
In all of the vessel types analyzed, the highest consumption occurs in the hoteling phase (between 62% and 75% of the total). The higher values for passenger ships are due to the higher power demand of its engines along with the longer duration of the hoteling phase when compared to freight ships.
If the two cases analyzed are compared, savings in fuel consumption vary between 23% and 26%, depending on the type of vessel. In all vessels, the biggest saving is in the hoteling phase, in other words, where the auxiliary engines demand greater power.

3.3. Pollutant Emissions Depending on Fuel Type

Of the four elements analyzed (NOx, SOx, CO2 and PM), a decision was made to study CO2 emissions separately, since the quantities of this pollutant are far superior to the rest. Figure 4 shows the NOx, SOx and PM emissions for the two cases analyzed.
Overall, in view of the results obtained, it can be stated that the reduction of emissions in case 2, compared to case 1, is significant.
Particularly noteworthy is the virtual disappearance of SOx and PM observed in case 2. This is due to the use of LNG as fuel compared to traditional ones (HFO and MDO). Such a drastic reduction in sulfur emissions makes it easier for vessels with LNG engines to operate within ECAs and SECAs.
With regard to NOx, in case 2 this is reduced by between 86.99% and 87.07%, depending on the type of vessel analyzed. This implies a considerable reduction of the tax levied by the governments of countries that penalize the emission of nitrogen oxides and the possibility to operate in ECAs.
Figure 5 shows the CO2 emissions for the two cases analyzed.
The reduction of CO2 emissions in case 2 as compared to case 1, ranges between 28.38% and 28.85% for the case of freight ships and reaches 31.42% for passenger ships. Therefore, the use of alternative fuels, such as LNG as in this case, can break the current trend of a gradual increase in emissions of this pollutant in maritime transport (almost doubled in the last twenty years) [79,80].
This reduction in CO2 emissions improves the energy efficiency index (EEDI) of ships. This is important since the IMO and EU agreed to establish monitoring systems for CO2 emissions on ships of more than 5,000GT starting in 2018. Vessels with a low EEDI are now subject to strong penalties, through tax payments, in addition to not being able to navigate in certain areas.
It is important to stress the magnitude of the CO2 emission values obtained due to their direct impact on people’s health. These are CO2 emissions which are discharged directly into the harbor, in other words, very close to the city. A change of fuel from HFO and MDO to LNG in the propulsion engines of the passenger ship analyzed (case 2 compared to case 1) reduces CO2 emissions in the port environment by 52 tons per journey.
This amount of pollutant is similar to that emitted annually by nine houses with an area of 100 m2 each (assuming that the boiler for heating and hot water is powered by natural gas) [81,82] or that emitted annually by the ventilation of a car park with 3000 spaces (assuming a level of CO2 concentration in line with the current regulations lower than 50 parts per million-and a journey inside of 120 km per vehicle per year) [19].
By ship type, passenger ships are the main contributors: they represent more than 50% of the atmospheric emissions (52% for CO2; 52% for SO2, 56% for NOx and 51% for PM). It is also worth highlighting the emissions from container ships, which represent more than 26% of the total. On the other hand, tanker and bulk carrier vessels represent about 17% of all emissions [3].

4. Conclusions

Maritime transport generates a large amount of pollutant emissions worldwide. Of these, those emitted in the port environment, although not representing the largest amount, are those that have a greater impact on the health of the population. Furthermore, current port design tends to incorporate this facility in the city; making more comprehensive monitoring of these emissions necessary.
Due to its geographical position, Spain will benefit from the scheduled Atlantic and Mediterranean Core Network Corridors belonging to the future Trans European Transport Network. In this context, this paper presents the contribution of Spain to ship exhaust emissions. The case of Spain is of particular interest mainly because the dense ship traffic within the Spanish ports directly imposes the impact of its exhaust emission pollutants upon highly populated cities.
In this research, various types of vessels powered by traditional fuels (HFO and MDO) were analyzed alongside the use of liquefied natural gas (LNG) during the operational phases taking place near the port (Approach, Maneuver and Hoteling).
A model has been developed for the calculation of ship engine exhaust emissions in Spanish ports using data to describe ship movements and operating modes. The method utilizes detailed information on ship movements and ship categories (ship type, fuel type, etc.) in conjunction with corresponding fuel consumption figures and emission factors.
Jointly analyzing the three operational phases carried out in the port environment, the results show a higher power demand by the passenger ship compared to other vessels (53% higher). Another fact worth noting is the little power demanded in the hoteling phase for freight transport ships compared with passenger transport ships (85% increase).
In all of the vessel types analyzed, the highest consumption occurs in the hoteling phase (between 62% and 75% of the total). If the two cases analyzed are compared, savings in fuel consumption vary between 23% and 26%, depending on the type of vessel.
The savings achieved in the emission of CO2 into the atmosphere vary between 28% for the case of freight ships and 31% for passenger ships. Specifically, this represents 52 tons per journey. This amount of pollutant is similar to that emitted annually by nine houses with an area of 100 m2 each (assuming that the boiler for heating and hot water is powered by natural gas) or that emitted annually by the ventilation of a car park with 3000 spaces (assuming a level of CO2 concentration in line with the current regulations).
On the other hand, the saving in NOx emissions is reduced by 87%. In addition, SOx emissions are completely eliminated and PM emissions are reduced to negligible values.
By ship type, passenger ships are the main contributors: they represent more than 50% of the atmospheric emissions (52% for CO2; 52% for SO2, 56% for NOx and 51% for PM). It is also worth highlighting the emissions from container ships, which represent more than 26% of the total. On the other hand, tanker and bulk carrier vessels represent about 17% of all emissions.
This research has tried to serve as a basis for the future policy making with regard to regional transportation systems, to allow assessment of the effectiveness of emission mitigation measures, and to enable accurate modelling of the contribution of ship emissions to the impact of climate change.

Author Contributions

Conceptualization, T.G.-L.; Writing—original draft, T.G.-L. and A.V.-V.; Methodology, T.G.-L.; Investigation, T.G.-L. and A.V.-V.; Validation, T.G.-L.; Formal analysis, T.G.-L. and A.V.-V.; Data curation, T.G.-L. and A.V.-V.; Writing—review & editing, T.G.-L. and A.V.-V.; Supervision, T.G.-L. and A.V.-V. All authors have read and agreed to the published version of the manuscript.

Funding

This research received no external funding.

Institutional Review Board Statement

Not applicable.

Informed Consent Statement

Not applicable.

Data Availability Statement

Not applicable.

Acknowledgments

Thanks to the Spanish port authorities for providing us with the data to carry out this research. The data for the different vessel operations has been obtained after consulting the port authorities of the ports analyzed.

Conflicts of Interest

The authors declare no conflict of interest.

Abbreviations

AActivity (hours [h])
AEAuxiliary Engine(s)
EEmissions (grams [g])
ECAEmission Control Area
EEDIEnergy Efficiency Design Index
EFEmission Factor (grams per kilowatt-hour [g/kWh])
CO2Carbon dioxide
GTGross tonnage
HFOHeavy Fuel Oil
IGCInternational code for the construction and equipment of ships carrying liquefied gases in bulk
IGFInternational code for gas and low-flashpoint fuels
IMOInternational Maritime Organization
LFLoad Factor (percentage of vessel’s total power [%])
LNGLiquefied Natural Gas
MDOMarine Diesel Oil
MEMain Engine(s)
MGOMarine Gas Oil
NOxNitrogen Oxides
PMaximum Continuous Rating Power (kilowatts [kW])
PMParticulate Matter
Ro-RoRoll on–Roll off ship
SCRSelective Catalytic Reduction
SECASulfur Emission Control Area
SOxSulfur Oxides

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Figure 1. Core Network Corridors.
Figure 1. Core Network Corridors.
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Figure 2. Power demand by vessel type depending on the operating phase.
Figure 2. Power demand by vessel type depending on the operating phase.
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Figure 3. Fuel consumption for the two cases analyzed.
Figure 3. Fuel consumption for the two cases analyzed.
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Figure 4. Pollutant emissions of NOx, SOx and PM for the two cases analyzed.
Figure 4. Pollutant emissions of NOx, SOx and PM for the two cases analyzed.
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Figure 5. Pollutant emissions of CO2 for the two cases analyzed.
Figure 5. Pollutant emissions of CO2 for the two cases analyzed.
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Table 1. Average power of the main and auxiliary engines.
Table 1. Average power of the main and auxiliary engines.
Engine Power (kW)
Type of ShipMain Engines (ME)Aux Engines (AE)
Tankers94111987
Bulk carrier79651450
General cargo93351780
Container ship30,8856800
RO-RO10,8102850
Passenger ship39,500
Table 2. Average time spent during Hoteling.
Table 2. Average time spent during Hoteling.
Type of ShipTime (h)
Tanker34
Bulk carrier56
General Cargo49
Container ship39
RO-RO 31
Passenger ship 14
Table 3. Percentage of total power used in vessel operations.
Table 3. Percentage of total power used in vessel operations.
Power Used in Vessel Operations (%)
ApproachManeuverHoteling
Type of ShipMEAEMEAEMEAE
Tanker45%30%20%50%0%40%
Bulk carrier45%30%20%50%0%40%
General cargo35%30%20%50%0%40%
Container ship30%30%15%50%0%40%
RO-RO30%30%15%50%0%40%
Passenger ship33% *40% *46% *
* The values were obtained from the California Air Resources Board [73].
Table 4. Specific consumption, 2016.
Table 4. Specific consumption, 2016.
Specific Consumption (g/kWh)
Type of shipApproach/Maneuver
Tanker220
Bulk carrier215
General cargo214
Container ship211
RO-RO222
Passenger ship217 *
* This consumption has also been considered in the operational phase of remaining in dock (Hoteling).
Table 5. Emission factors depending on the type of fuel.
Table 5. Emission factors depending on the type of fuel.
Emission Factors (g/kWh)
FuelNOxSOxCO2PM
HFO (3.5%)17106002.2
MDO (1%)1545500.5
LNG204000
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Gil-Lopez, T.; Verdu-Vazquez, A. Environmental Analysis of the Use of Liquefied Natural Gas in Maritime Transport within the Port Environment. Sustainability 2021, 13, 11989. https://doi.org/10.3390/su132111989

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Gil-Lopez T, Verdu-Vazquez A. Environmental Analysis of the Use of Liquefied Natural Gas in Maritime Transport within the Port Environment. Sustainability. 2021; 13(21):11989. https://doi.org/10.3390/su132111989

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Gil-Lopez, Tomas, and Amparo Verdu-Vazquez. 2021. "Environmental Analysis of the Use of Liquefied Natural Gas in Maritime Transport within the Port Environment" Sustainability 13, no. 21: 11989. https://doi.org/10.3390/su132111989

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