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1-(Triethoxysilyl)buta-1,3-dienes—New Building Blocks for Stereoselective Synthesis of Unsymmetrical (E,E)-1,4-Disubstituted 1,3-dienes

Center for Advanced Technologies, Adam Mickiewicz University, Umultowska 89c, Poznan 61-614, Poland
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Academic Editor: Łukasz John
Materials 2015, 8(11), 7250-7256; https://doi.org/10.3390/ma8115378
Received: 8 August 2015 / Accepted: 14 October 2015 / Published: 28 October 2015
(This article belongs to the Special Issue Organometallic Compounds 2015)
A convenient methodology for the highly stereoselective synthesis of unsymmetrical (1E,3E)-1,4-disubstituted 1,3-dienes based on palladium-catalyzed Hiyama cross-coupling reaction of 1-(triethoxysilyl)-substituted buta-1,3-dienes with aryl iodides is reported. View Full-Text
Keywords: buta-1,3-dienes; organosilicon dienes; C–C bond formation; Hiyama cross-coupling; palladium catalyst buta-1,3-dienes; organosilicon dienes; C–C bond formation; Hiyama cross-coupling; palladium catalyst
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Szudkowska-Frątczak, J.; Taczała, M.; Pawluć, P. 1-(Triethoxysilyl)buta-1,3-dienes—New Building Blocks for Stereoselective Synthesis of Unsymmetrical (E,E)-1,4-Disubstituted 1,3-dienes. Materials 2015, 8, 7250-7256.

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