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Materials 2014, 7(2), 805-875;

Fabrications and Applications of Stimulus-Responsive Polymer Films and Patterns on Surfaces: A Review

Department of Materials Science and Engineering, National Taiwan University of Science and Technology, 43, Section 4, Keelung Road, Taipei 106, Taiwan
Department of Chemical Engineering, Feng Chia University, 100 Wenhwa Road, Seatwen, Taichung 40724, Taiwan
Author to whom correspondence should be addressed.
Received: 26 November 2013 / Revised: 10 January 2014 / Accepted: 16 January 2014 / Published: 28 January 2014
(This article belongs to the Section Advanced Composites)
Full-Text   |   PDF [3321 KB, uploaded 28 January 2014]


In the past two decades, we have witnessed significant progress in developing high performance stimuli-responsive polymeric materials. This review focuses on recent developments in the preparation and application of patterned stimuli-responsive polymers, including thermoresponsive layers, pH/ionic-responsive hydrogels, photo-responsive film, magnetically-responsive composites, electroactive composites, and solvent-responsive composites. Many important new applications for stimuli-responsive polymers lie in the field of nano- and micro-fabrication, where stimuli-responsive polymers are being established as important manipulation tools. Some techniques have been developed to selectively position organic molecules and then to obtain well-defined patterned substrates at the micrometer or submicrometer scale. Methods for patterning of stimuli-responsive hydrogels, including photolithography, electron beam lithography, scanning probe writing, and printing techniques (microcontact printing, ink-jet printing) were surveyed. We also surveyed the applications of nanostructured stimuli-responsive hydrogels, such as biotechnology (biological interfaces and purification of biomacromoles), switchable wettability, sensors (optical sensors, biosensors, chemical sensors), and actuators. View Full-Text
Keywords: thermoresponsive; pH-responsive; photo-responsive; polymer; magnetically-responsive thermoresponsive; pH-responsive; photo-responsive; polymer; magnetically-responsive
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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Chen, J.-K.; Chang, C.-J. Fabrications and Applications of Stimulus-Responsive Polymer Films and Patterns on Surfaces: A Review. Materials 2014, 7, 805-875.

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