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Materials 2010, 3(1), 150-157;

Syntheses and a Solid State Structure of a Dinuclear Molybdenum(V) Complex with Pyridine

Department of Chemistry and Chemical Technology, University of Ljubljana, Aškerčeva 5, 1000 Ljubljana, Slovenia
Department of Chemistry, Syracuse University, Syracuse, New York, NY 13244, USA
Author to whom correspondence should be addressed.
Received: 4 December 2009 / Revised: 29 December 2009 / Accepted: 4 January 2010 / Published: 4 January 2010
(This article belongs to the Special Issue Polyoxometalate Compounds)
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A mononuclear complex [MoOCl4(H2O)] readily forms a metal−metal bonded {Mo2O4}2+ core. A high content of pyridine in the reaction mixture prevents further aggregation of dinuclear cores into larger clusters and a neutral, dinuclear complex with the [Mo2O4Cl2(Py)4] composition is isolated as a product. Solid state structures of two compounds containing this complex, [Mo2O4Cl2(Py)4]·2.25Py (1) and [Mo2O4Cl2(Py)4]·1.5PyHCl (2), were investigated by X-ray crystallography. View Full-Text
Keywords: polyoxomolybdates; metal−metal bonded {Mo2O4}2+ core; molybdenum(V) polyoxomolybdates; metal−metal bonded {Mo2O4}2+ core; molybdenum(V)

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Modec, B.; Zubieta, J. Syntheses and a Solid State Structure of a Dinuclear Molybdenum(V) Complex with Pyridine. Materials 2010, 3, 150-157.

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