Tunable Properties via Composition Modulations of Poly(vinyl alcohol)/Xanthan Gum/Oxalic Acid Hydrogels
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Methods
2.3. Preparation of PVA/XG Hydrogels
3. Results and Discussions
3.1. Structural Characterization
3.2. Morphological Investigation
3.3. Porosity
3.4. Swelling Behavior and Kinetic Studies of PVA/XG Hydrogels
3.5. Mechanical Properties
3.6. Antibacterial Activity of PVA/XG Hydrogels
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Samples | PVA (g) | Xanthan Gum (g) | Oxalic Acid (g) | Distilled Water (mL)/(%) |
---|---|---|---|---|
PVA/XG-100/0 | 0.5 | 0 | 0.08 | 7.25/8 |
PVA/XG-90/10 | 0.45 | 0.05 | 0.08 | 7.25/8 |
PVA/XG-80/20 | 0.4 | 0.1 | 0.08 | 7.25/8 |
PVA/XG-70/30 | 0.35 | 0.15 | 0.08 | 7.25/8 |
PVA/XG-60/40 | 0.3 | 0.2 | 0.08 | 7.25/8 |
PVA/XG-50/50 | 0.25 | 0.25 | 0.08 | 7.25/8 |
Samples | Porosity (%) | Average Pore Diameters (mm) | Seq a (%) | Schott’s Second Order Kinetics | ||
---|---|---|---|---|---|---|
S∞ b (g/g) | Ksc (g/min *g) | R2d | ||||
PVA/XG-100/0 | 70 | 0.028 ± 0.007 | 1105.17 ± 55.25 | 10.81 | 0.02 | 0.9998 |
PVA/XG-90/10 | 69 | 0.029 ± 0.017 | 1242.44 ± 62.12 | 12.43 | 0.07 | 0.9999 |
PVA/XG-80/20 | 70 | 0.030 ± 0.009 | 1308.10 ± 65.40 | 13.05 | 0.1 | 0.9999 |
PVA/XG-70/30 | 70 | 0.040 ± 0.015 | 1421.28 ± 71.06 | 14.12 | 0.09 | 0.9999 |
PVA/XG-60/40 | 67 | 0.060 ± 0.011 | 1354.16 ± 67.70 | 13.53 | 0.04 | 0.9999 |
PVA/XG-50/50 | 86 | 0.064 ± 0.024 | 1390.50 ± 64.52 | 13.90 | 0.11 | 0.9999 |
Samples | Weight (g) | Staphylococcus aureus ATCC 25923 | Escherichia coli ATCC 25922 | ||||||
---|---|---|---|---|---|---|---|---|---|
DM | CTM | DM | CTM | ||||||
M(+) CFU/mL | 24 h CFU/mL | 48 h CFU/mL | M(+) CFU/mL | 24 h CFU/mL | 48 h CFU/mL | ||||
PVA/XG-100/0 | 0.05 | + | 1.5 × 108 | 0 | 0 | + | 1.5 × 108 | 0 | 0 |
PVA/XG-90/10 | 0.05 | + | 1.5 × 108 | 0 | 0 | + | 1.5 × 108 | 0 | 0 |
PVA/XG-80/20 | 0.05 | + | 1.5 × 108 | 0 | 0 | + | 1.5 × 108 | 0 | 0 |
PVA/XG-70/30 | 0.05 | + | 1.5 × 108 | 0 | 0 | + | 1.5 × 108 | 0 | 0 |
PVA/XG-60/40 | 0.05 | + | 1.5 × 108 | 0 | 0 | + | 1.5 × 108 | 0 | 0 |
PVA/XG-50/50 | 0.05 | + | 1.5 × 108 | 0 | 0 | + | 1.5 × 108 | 0 | 0 |
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Enache, A.A.; Serbezeanu, D.; Vlad-Bubulac, T.; Ipate, A.-M.; Suflet, D.M.; Drobotă, M.; Barbălată-Mândru, M.; Udrea, R.M.; Rîmbu, C.M. Tunable Properties via Composition Modulations of Poly(vinyl alcohol)/Xanthan Gum/Oxalic Acid Hydrogels. Materials 2022, 15, 2657. https://doi.org/10.3390/ma15072657
Enache AA, Serbezeanu D, Vlad-Bubulac T, Ipate A-M, Suflet DM, Drobotă M, Barbălată-Mândru M, Udrea RM, Rîmbu CM. Tunable Properties via Composition Modulations of Poly(vinyl alcohol)/Xanthan Gum/Oxalic Acid Hydrogels. Materials. 2022; 15(7):2657. https://doi.org/10.3390/ma15072657
Chicago/Turabian StyleEnache, Alin Alexandru, Diana Serbezeanu, Tăchiță Vlad-Bubulac, Alina-Mirela Ipate, Dana Mihaela Suflet, Mioara Drobotă, Mihaela Barbălată-Mândru, Radu Mihail Udrea, and Cristina Mihaela Rîmbu. 2022. "Tunable Properties via Composition Modulations of Poly(vinyl alcohol)/Xanthan Gum/Oxalic Acid Hydrogels" Materials 15, no. 7: 2657. https://doi.org/10.3390/ma15072657