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Energies 2010, 3(8), 1499-1528;

Principles and Materials Aspects of Direct Alkaline Alcohol Fuel Cells

School of Chemical Engineering and Advanced Materials, Merz Court, Newcastle University, Newcastle upon Tyne, NE1 7RU, UK
Max Planck Institute for Dynamics of Complex Technical Systems, Sandtorstrasse 1, 39106 Magdeburg, Germany
Portable Energy Systems, Chair for Process Systems Engineering, Otto von Guericke University, Universitaetsplatz 2, 39106 Magdeburg, Germany
Author to whom correspondence should be addressed.
Received: 21 July 2010 / Revised: 6 August 2010 / Accepted: 16 August 2010 / Published: 24 August 2010
(This article belongs to the Special Issue Fuel Cells)
PDF [424 KB, uploaded 17 March 2015]


Direct alkaline alcohol fuel cells (DAAFCs) have attracted increasing interest over the past decade because of their favourable reaction kinetics in alkaline media, higher energy densities achievable and the easy handling of the liquid fuels. In this review, principles and mechanisms of DAAFCs in alcohol oxidation and oxygen reduction are discussed. Despite the high energy densities available during the oxidation of polycarbon alcohols they are difficult to oxidise. Apart from methanol, the complete oxidation of other polycarbon alcohols to CO2 has not been achieved with current catalysts. Different types of catalysts, from conventional precious metal catalyst of Pt and Pt alloys to other lower cost Pd, Au and Ag metal catalysts are compared. Non precious metal catalysts, and lanthanum, strontium oxides and perovskite-type oxides are also discussed. Membranes like the ones used as polymer electrolytes and developed for DAAFCs are reviewed. Unlike conventional proton exchange membrane fuel cells, anion exchange membranes are used in present DAAFCs. Fuel cell performance with DAAFCs using different alcohols, catalysts and membranes, as well as operating parameters are summarised. In order to improve the power output of the DAAFCs, further developments in catalysts, membrane materials and fuel cell systems are essential. View Full-Text
Keywords: alcohol oxidation; oxygen reduction; anion exchange membranes; fuel cells; catalysts; power output alcohol oxidation; oxygen reduction; anion exchange membranes; fuel cells; catalysts; power output

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Yu, E.H.; Krewer, U.; Scott, K. Principles and Materials Aspects of Direct Alkaline Alcohol Fuel Cells. Energies 2010, 3, 1499-1528.

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