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Article

Life-Cycle Assessment (LCA) of Different Pretreatment and Product Separation Technologies for Butanol Bioprocessing from Oil Palm Frond

1
Department of Agricultural and Biosystems Engineering, Iowa State University, Elings Hall, Ames, IA 50011, USA
2
Faculty of Industrial Sciences and Technology, University Malaysia Pahang, Lebuhraya Tun Razak, Kuantan 26300, Malaysia
*
Author to whom correspondence should be addressed.
Energies 2020, 13(1), 155; https://doi.org/10.3390/en13010155
Received: 27 November 2019 / Revised: 18 December 2019 / Accepted: 25 December 2019 / Published: 28 December 2019
(This article belongs to the Special Issue Sustainability of Biorenewable Systems and Processes)
Environmental impact assessment is a crucial aspect of biofuels production to ensure that the process generates emissions within the designated limits. In typical cellulosic biofuel production process, the pretreatment and downstream processing stages were reported to require a high amount of chemicals and energy, thus generating high emissions. Cellulosic butanol production while using low moisture anhydrous ammonia (LMAA) pretreatment was expected to have a low chemical, water, and energy footprint, especially when the process was combined with more efficient downstream processing technologies. In this study, the quantification of environmental impact potentials from cellulosic butanol production plants was conducted with modeled different pretreatment and product separation approaches. The results have shown that LMAA pretreatment possessed a potential for commercialization by having low energy requirements when compared to the other modeled pretreatments. With high safety measures that reduce the possibility of anhydrous ammonia leaking to the air, LMAA pretreatment resulted in GWP of 5.72 kg CO2 eq./L butanol, ecotoxicity potential of 2.84 × 10−6 CTU eco/L butanol, and eutrophication potential of 0.011 kg N eq./L butanol. The lowest energy requirement in biobutanol production (19.43 MJ/L), as well as better life-cycle energy metrics performances (NEV of 24.69 MJ/L and NER of 2.27) and environmental impacts potentials (GWP of 3.92 kg N eq./L butanol and ecotoxicity potential of 2.14 × 10−4 CTU eco/L butanol), were recorded when the LMAA pretreatment was combined with the membrane pervaporation process in the product separation stage. View Full-Text
Keywords: environmental impacts; emissions; global warming potential; LMAA pretreatment; cellulosic butanol environmental impacts; emissions; global warming potential; LMAA pretreatment; cellulosic butanol
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MDPI and ACS Style

Mahmud, N.; Rosentrater, K.A. Life-Cycle Assessment (LCA) of Different Pretreatment and Product Separation Technologies for Butanol Bioprocessing from Oil Palm Frond. Energies 2020, 13, 155. https://doi.org/10.3390/en13010155

AMA Style

Mahmud N, Rosentrater KA. Life-Cycle Assessment (LCA) of Different Pretreatment and Product Separation Technologies for Butanol Bioprocessing from Oil Palm Frond. Energies. 2020; 13(1):155. https://doi.org/10.3390/en13010155

Chicago/Turabian Style

Mahmud, Nazira, and Kurt A. Rosentrater 2020. "Life-Cycle Assessment (LCA) of Different Pretreatment and Product Separation Technologies for Butanol Bioprocessing from Oil Palm Frond" Energies 13, no. 1: 155. https://doi.org/10.3390/en13010155

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