Magnetic Beads of Zero Valent Iron Doped Polyethersolfun Developed for Removal of Arsenic from Apatite-Soil Treated Water
Abstract
:1. Introduction
2. Materials and Methods
2.1. Chemical and Reagents
2.2. Preparation of Apatite-Soil
2.3. Treatment of Apatite-Soil Experiment
2.4. Beads Charactrization
2.5. Synthesis of PES/ZVI Microbeaads
2.6. Adsorption/Removal Procedure
3. Results and Discussions
3.1. Characterization
3.1.1. FTIR
3.1.2. TGA
3.1.3. SEM Microscopy
3.1.4. VSM
3.2. Effect of Parameters on Removal Efficiency
3.2.1. Type of Adsorbent
3.2.2. Solution pH and Proposed Mechanism
3.2.3. Adsorbent Dosage
3.2.4. Contact Time
3.3. Kinetic Study
3.4. Equilibrium Adsorption and Isotherm Models
3.5. Temperature and Thermodynamic Studies
3.6. Real Samples
3.7. Regeneration Anc Recycle
3.8. Iron Leaching Test
3.9. Comparison
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Sample | Original Concentration of Arsenic (mg·L−1) | Concentration of Arsenic in Apatite Treated Water at Different pHs (after Treatment) | ||
---|---|---|---|---|
pH = 3 | pH = 6 | pH = 10 | ||
G2 | 103.7 | 101.2 | 76.2 | 47.2 |
T1 | 147.3 | 142 | 118 | 63 |
GTSP | 170.59 | 163 | 129 | 77 |
T15-20 | 156.67 | 147.11 | 124.8 | 82 |
Q3 | 87.7 | 86.9 | 62.4 | 32.7 |
Q8 | 72.32 | 72.14 | 53.7 | 29.11 |
Q12 | 146.2 | 139 | 123 | 67 |
Q16 | 134.5 | 130.4 | 99.4 | 60.5 |
Models | Parameters | Arsenic |
---|---|---|
Pseudo first order | Qe (mg·g−1) | 18.916 |
K1 (min−1) | 0.0018 | |
R2 | 0.0583 | |
Pseudo second order | Qe (mg·g−1) | 55.556 |
K2 (g·mg−1·min−1) | 0.000324 | |
R2 | 0.981 |
Metal | Langmuir Model | Freundlich Model | ||||
---|---|---|---|---|---|---|
Qm (mg·g−1) | KL (L·mg−1) | R2 | 1/n | KF (mg·L−1)−1/n | R2 | |
Arsenic | 41.32 | 2.07 | 0.998 | 3.81 | 7.14 | 0.845 |
Adsorbate | T(K) | Qe (mg·g−1) | ΔG (kJ/mol) | ΔH (kJ/mol·K) | ΔS (kJ/mol·K) |
---|---|---|---|---|---|
arsenic | 20 | 34.45 | −0.76 | 28.31 | 0.097 |
25 | 35.77 | −1.45 | |||
45 | 38.03 | −3.31 |
Samples | Native Arsenic (ppb) | C0 (after Acidic Treatment) | Ce (after Removal) | R% |
---|---|---|---|---|
G2 | 103.7 | 101.2 | 19 | 81.22 |
GTSP | 147.3 | 142 | 28 | 80.28 |
T1 | 170.59 | 163 | 45 | 72.39 |
T15-20 | 156.67 | 147.11 | 39 | 73.48 |
Q3 | 87.7 | 86.9 | 11.8 | 86.42 |
Q8 | 72.32 | 72.4 | 8.1 | 88.81 |
Q12 | 146.2 | 139 | 33 | 76.25 |
Q16 | 134.5 | 130.4 | 29.4 | 77.45 |
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Noorbakhsh, R.; Koohi, M.K.; Hassan, J.; Rahmani, A.; Rashidi Nodeh, H.; Rezania, S. Magnetic Beads of Zero Valent Iron Doped Polyethersolfun Developed for Removal of Arsenic from Apatite-Soil Treated Water. Int. J. Environ. Res. Public Health 2022, 19, 12697. https://doi.org/10.3390/ijerph191912697
Noorbakhsh R, Koohi MK, Hassan J, Rahmani A, Rashidi Nodeh H, Rezania S. Magnetic Beads of Zero Valent Iron Doped Polyethersolfun Developed for Removal of Arsenic from Apatite-Soil Treated Water. International Journal of Environmental Research and Public Health. 2022; 19(19):12697. https://doi.org/10.3390/ijerph191912697
Chicago/Turabian StyleNoorbakhsh, Roya, Mohammad Kazem Koohi, Jalal Hassan, Anosheh Rahmani, Hamid Rashidi Nodeh, and Shahabaldin Rezania. 2022. "Magnetic Beads of Zero Valent Iron Doped Polyethersolfun Developed for Removal of Arsenic from Apatite-Soil Treated Water" International Journal of Environmental Research and Public Health 19, no. 19: 12697. https://doi.org/10.3390/ijerph191912697