Surface-Modified Sewage Sludge-Derived Carbonaceous Catalyst as a Persulfate Activator for Phenol Degradation
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials and Reagents
2.2. Preparation and Characterization of the Sludge-Derived Carbonaceous Catalysts (SCs)
2.3. Batch Experiments and Analytical Methods
3. Results and Discussion
3.1. Characterization of SCs
3.1.1. Composition Analysis
3.1.2. Nitrogen Adsorption-Desorption Isotherms and Pore Size Distributions
3.1.3. Scanning Electron Microscopy (SEM) Analysis
3.1.4. Fourier Transform Infrared (FTIR) Spectroscopy Analysis
3.2. Performance of SCs on Phenol Degradation
3.3. Effect of Reaction Parameters on Phenol Degradation
3.3.1. Effect of SS-600-HCl Dosage
3.3.2. Effect of Sodium Persulfate (PS) Dosage
3.3.3. Effect of Initial pH
3.3.4. Effect of Temperature
3.4. Mechanism Analysis of Phenol Degradation by SS-600-HCl/PS
3.5. Stability and Reuse of SS-600-HCl Catalyst
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Sample | C (%) | H (%) | N (%) | S (%) | Ash (%) |
---|---|---|---|---|---|
SS | 24.71 | 4.01 | 4.15 | 0.354 | 53.00 |
SS-600 | 16.97 | 0.522 | 1.54 | 0.679 | 13.60 |
SS-600-HCl | 30.07 | 0.904 | 2.97 | 1.23 | 9.40 |
Sample | SBET (m2/g) | Total Pore Volume (Vp) (cm3/g) | Pore Size (L0) (nm) |
---|---|---|---|
SS-600 | 147 | 0.19 | 5.21 |
SS-600-HCl | 197 | 0.29 | 5.89 |
t (°C) | kobs (min−1) | R2 |
---|---|---|
25 | 0.01421 | 0.99819 |
35 | 0.02358 | 0.99884 |
45 | 0.03527 | 0.99776 |
Sample | SBET (m2/g) | Vt (cm3/g) | L0 (nm) |
---|---|---|---|
Fresh SS-600-HCl | 197 | 0.29 | 5.89 |
Three times used SS-600-HCl | 3 | 0.005 | 5.71 |
Regenerated SS-600-HCl | 9 | 0.043 | 19.09 |
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Han, M.; Zhang, J.; Chu, W.; Zhou, G.; Chen, J. Surface-Modified Sewage Sludge-Derived Carbonaceous Catalyst as a Persulfate Activator for Phenol Degradation. Int. J. Environ. Res. Public Health 2020, 17, 3286. https://doi.org/10.3390/ijerph17093286
Han M, Zhang J, Chu W, Zhou G, Chen J. Surface-Modified Sewage Sludge-Derived Carbonaceous Catalyst as a Persulfate Activator for Phenol Degradation. International Journal of Environmental Research and Public Health. 2020; 17(9):3286. https://doi.org/10.3390/ijerph17093286
Chicago/Turabian StyleHan, Meiling, Jin Zhang, Wen Chu, Gongfu Zhou, and Jiahao Chen. 2020. "Surface-Modified Sewage Sludge-Derived Carbonaceous Catalyst as a Persulfate Activator for Phenol Degradation" International Journal of Environmental Research and Public Health 17, no. 9: 3286. https://doi.org/10.3390/ijerph17093286